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CAS No.: | 1011-12-7 |
---|---|
Name: | 2-cyclohexylidenecyclohexanone |
Article Data: | 63 |
Molecular Structure: | |
Formula: | C12H18 O |
Molecular Weight: | 178.274 |
Synonyms: | 1-Cyclohexylidene-2-cyclohexanone;2-Cyclohexylidenecyclohexanone; Bicyclohexyliden-2-one; Dianon; NSC 61652 |
Density: | 1.034g/cm3 |
Melting Point: | 57 °C |
Boiling Point: | 295°C at 760 mmHg |
Flash Point: | 122.4°C |
PSA: | 17.07000 |
LogP: | 3.39020 |
Conditions | Yield |
---|---|
With 2-(trimethylsilyl)prop-2-enylzinc chloride; bis(acetylacetonate)nickel(II) In diethyl ether 1.) -15 deg C, 0.5 h, 2.) r.t., 18 h; | 100% |
With titanium(IV) tetraethanolate | 94% |
With [Mg0833Al0.167(OH)2](C(00)O3)84*0.64H2O In acetonitrile at 239.84℃; Reagent/catalyst; Aldol Condensation; Inert atmosphere; | 13.4% |
(+/-)-2-pentanol
cyclohexanone
A
2-cyclohexylidenecyclohexanone
C
cyclohexanol
Conditions | Yield |
---|---|
With magnesium oxide for 6h; Reactivity; Temperature; Reagent/catalyst; Time; Meerwein-Ponndorf-Verley reduction; Inert atmosphere; Heating; | A n/a B n/a C 79% |
cyclohexanone
4-aza-9-diazo-9H-fluorene
A
2-cyclohexylidenecyclohexanone
B
2'-oxospiro<4-azafluorene-9',1-cyclopropane>
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate at 0℃; for 3h; Product distribution; or cyclopentanone; | A 0.4 g B 73% |
With boron trifluoride diethyl etherate at 0℃; for 3h; | A 0.4 g B 73% |
cyclohexanone
(dichloroalumino)(trichlorotitanio)methane
2-cyclohexylidenecyclohexanone
Conditions | Yield |
---|---|
In toluene at 25℃; for 3h; | 60% |
cyclohexanone
cyclohexylamine
A
2-cyclohexylidenecyclohexanone
B
cyclohexanone-2-propionitrile
Conditions | Yield |
---|---|
With acetic acid; acrylonitrile; hydroquinone for 16h; Heating; | A 15% B 42% |
cyclohexanone
acrylonitrile
A
2-cyclohexylidenecyclohexanone
B
cyclohexanone-2-propionitrile
Conditions | Yield |
---|---|
With cyclohexylamine; acetic acid; hydroquinone for 16h; Heating; | A 15% B 42% |
cyclohexanone
A
2-(1-cyclohexenyl)cyclohexanone
B
2-cyclohexylidenecyclohexanone
C
2-cyclohexylidene-6-(1-cyclohexen-1-yl)cyclohexan-1-one
D
2(R*),6(S*)-di(1-cyclohexen-1-yl)cyclohexanone
Conditions | Yield |
---|---|
With potassium hydroxide In toluene at 190℃; for 6.5h; Further byproducts given; | A n/a B n/a C n/a D 33% |
cyclohexanone
1,1,1,3,3,3-hexamethyl-disilazane
A
2-cyclohexylidenecyclohexanone
B
1-(Trimethylsilyloxy)cyclohexene
C
N-Cyclohexenylcyclohexanimine
Conditions | Yield |
---|---|
dicobalt octacarbonyl at 110℃; for 6h; | A n/a B n/a C 32% |
cyclohexanone
acetonitrile
A
2-cyclohexylidenecyclohexanone
B
2-cyclohexylideneacetonitrile
Conditions | Yield |
---|---|
With [Mg0751Al0.249(OH)2](C(01)O3)25*0.71H2O at 239.84℃; Inert atmosphere; | A 11.2% B 8.4% |
cyclohexanone
tert-butyldimethylsilyl chloride
A
2-cyclohexylidenecyclohexanone
B
tert-butyl(cyclohex-1-en-1-yloxy)dimethylsilane
Conditions | Yield |
---|---|
Stage #1: cyclohexanone; tert-butyldimethylsilyl chloride With triethylamine for 1h; Inert atmosphere; Stage #2: With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 3h; Inert atmosphere; | A n/a B 11% |