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CAS No.: | 1113-59-3 |
---|---|
Name: | Bromopyruvic acid |
Article Data: | 15 |
Molecular Structure: | |
Formula: | C3H3BrO3 |
Molecular Weight: | 166.959 |
Synonyms: | Pyruvicacid, bromo- (6CI,7CI,8CI);3-Bromo-2-oxopropanoic acid;3-Bromopyruvate;3-Bromopyruvic acid;NSC 11731;NSC 62343;b-Bromopyruvic acid; |
EINECS: | 214-206-5 |
Density: | 2.011 g/cm3 |
Melting Point: | 77-82 °C |
Boiling Point: | 223.4 °C at 760 mmHg |
Flash Point: | 88.9 °C |
Solubility: | Soluble in water, dimethyl sulfoxide, ethyl acetate and water. |
Appearance: | white to pale yellow crystalline powder |
Hazard Symbols: | C |
Risk Codes: | 34-20/21/22 |
Safety: | 26-36/37/39-45-27 |
Transport Information: | UN 3261 8/PG 2 |
PSA: | 54.37000 |
LogP: | 0.03500 |
Conditions | Yield |
---|---|
With sulfuric acid; bromine for 1h; | 90% |
With bromine at 50℃; | 85% |
With bromine | |
With bromine at 40 - 50℃; |
Conditions | Yield |
---|---|
With diethyl ether; hydrogen bromide |
acetylacetone
A
bromopyruvic acid
B
dibromo-pyruvic acid
C
tribromo-pyruvic acid
D
acetic acid
E
2-oxo-propionic acid
Conditions | Yield |
---|---|
With potassium bromate; manganese(III) sulfate; sulfuric acid In water at 35℃; Mechanism; Belousov-Zhabotinsky reaction: dependence of oscillatory reaction on concentration of reactants; oscillatory characteristics; |
water
bromine
2-oxo-propionic acid
A
bromopyruvic acid
B
dibromo-pyruvic acid
C
tribromo-pyruvic acid
Conditions | Yield |
---|---|
With bromine In sulfuric acid at 25℃; Kinetics; Further Variations:; Temperatures; Bromination; |
Conditions | Yield |
---|---|
With bromine In water |
1H-pyrrolo[2,3-b]pyridin-3-carbothioc acid amide
bromopyruvic acid
2-(1H-pyrrolo[2,3-b]pyridin-3-yl)-thiazole-4-carboxylic acid
Conditions | Yield |
---|---|
In ethanol at 20℃; for 18h; Heating / reflux; | 100% |
1H-pyrrolo[2,3-b]pyridin-3-carbothioc acid amide
bromopyruvic acid
Conditions | Yield |
---|---|
In ethanol at 20℃; for 18h; Reflux; | 100% |
bromopyruvic acid
2-(N-t-butoxycarbonylamino)thioacetamide
2-((tert-butoxycarbonylamino)methyl)thiazole-4-carboxylic acid
Conditions | Yield |
---|---|
With calcium carbonate In ethanol Inert atmosphere; | 99% |
With calcium carbonate In methanol at 20℃; for 87h; Hantzsch Thiazole Synthesis; | 98% |
With calcium carbonate In ethanol for 5h; Ambient temperature; | 74% |
bromopyruvic acid
orthoformic acid triethyl ester
3-bromo-2,2-diethoxypropionic acid
Conditions | Yield |
---|---|
With sulfuric acid for 24h; Ambient temperature; | 99% |
With sulfuric acid at 20℃; | 90% |
With sulfuric acid at 20℃; for 24h; | |
With sulfuric acid at 20℃; for 24h; Inert atmosphere; |