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| CAS No.: | 128-50-7 |
|---|---|
| Name: | NOPOL |
| Article Data: | 26 |
| Molecular Structure: | |
|
|
|
| Formula: | C11H18 O |
| Molecular Weight: | 166.263 |
| Synonyms: | 2-Norpinene-2-ethanol,6,6-dimethyl- (6CI,7CI,8CI); 10-(Hydroxymethyl)-2-pinene;2-(6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol;6,6-Dimethyl-2-norpinene-2-ethanol;6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol; Homomyrtenol; NSC 1284; NSC404962; Nopol; Nopol (terpene) |
| Density: | 0.978g/cm3 |
| Boiling Point: | 235°Cat760mmHg |
| Flash Point: | 98.9°C |
| Hazard Symbols: |
|
| Risk Codes: | 22 |
| Safety: | Moderately toxic by ingestion and intramuscular routes. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes. |
| PSA: | 20.23000 |
| LogP: | 2.36120 |
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| Conditions | Yield |
|---|---|
| With iron(III) phosphate In acetonitrile at 80℃; for 4h; Prins condensation; | 100% |
| With mesoporous SnSBA-15(5) In toluene at 89.84℃; for 6h; Prins reaction; | 96.7% |
| at 150℃; | 61% |
- 128-50-7
nopol
| Conditions | Yield |
|---|---|
| With hydrogen; benzyl bromide; Pd<*>MCM-48 In methanol under 760.051 Torr; | 95% |
| With Na2K-SG(I) In tetrahydrofuran at 20℃; Inert atmosphere; |
- 77661-66-6
2-<2-(methoxymethoxy)ethyl>-6,6-dimethylbicyclo<3.1.1>hept-2-ene
- 128-50-7
nopol
| Conditions | Yield |
|---|---|
| zirconium(IV) chloride In isopropyl alcohol for 4h; Heating; | 93% |
- 128-50-7
nopol
| Conditions | Yield |
|---|---|
| With zirconium(IV) chloride In acetonitrile at 20℃; for 0.333333h; | 87% |
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride | 86% |
| (saponification); |
- 69978-56-9
[2-(6,6-Dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-ethoxy]-trimethyl-silane
- 128-50-7
nopol
| Conditions | Yield |
|---|---|
| With tris paraperiodate In benzene for 0.166667h; Heating; | 85% |
- 693272-53-6
4-{[2-(6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-ethoxy]-phenyl-methyl}-biphenyl
- 128-50-7
nopol
| Conditions | Yield |
|---|---|
| With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane at 20℃; for 7h; | 83% |
- 693272-54-7
4-{[2-(6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-ethoxy]-diphenyl-methyl}-biphenyl
- 128-50-7
nopol
| Conditions | Yield |
|---|---|
| With trifluoroacetic acid In dichloromethane at 20℃; for 3h; | 82% |
- 128-50-7
nopol
| Conditions | Yield |
|---|---|
| With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane; water at 20℃; for 1.5h; | 78% |
| Conditions | Yield |
|---|---|
| With Cr and Fe containing metal organic framework MIL-101; air In acetonitrile at 80℃; for 30h; Catalytic behavior; Reagent/catalyst; | A 63.75% B 21.25% |
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Chemistry
IUPAC Name: 2-(7,7-Dimethyl-4-bicyclo[3.1.1]hept-3-enyl)ethanol
Synonyms: NOPOL ; 2-(6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol ; 6,6-Dimethyl-2-(2-hydroxyethyl)-2-norpinene ; 6,6-Dimethyl-2-norpinene-2-ethano ; 6,6-Dimethylbicyclo-(3.1.1)-2-heptene-2-ethanol ; 6,6-Dimethyl-bicyclo[3.1.1]hept-2-ene-2-ethano ; Bicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-dimethyl- ; Homomyretenol
CAS NO: 128-50-7
Molecular Formula of 6,6-Dimethyl-2-norpinene-2-ethano (CAS NO.128-50-7) : C11H18O
Molecular Weight of 6,6-Dimethyl-2-norpinene-2-ethano (CAS NO.128-50-7) :166.26
Molecular Structure of 6,6-Dimethyl-2-norpinene-2-ethano (CAS NO.128-50-7) : 
EINECS: 204-890-3
Mol File: 128-50-7.mol
Index of Refraction: 1.501
Surface Tension: 32.1 dyne/cm
Density: 0.978 g/cm3
Flash Point: 98.9 °C
Enthalpy of Vaporization: 54.83 kJ/mol
Boiling Point: 235 °C at 760 mmHg
Vapour Pressure: 0.00937 mmHg at 25°C
Toxicity Data With Reference
| 1. | skn-rbt 500 mg/24H MOD | FCTXAV Food and Cosmetics Toxicology. 17 (1979),879. | ||
| 2. | orl-rat LD50:890 mg/kg | FCTXAV Food and Cosmetics Toxicology. 17 (1979),879. | ||
| 3. | ims-mus LD50:500 mg/kg | JSICAZ Journal of Scientific and Industrial Research, Section C: Biological Sciences. 21 (1962),342. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Hazard Codes 
Xn
Risk Statements 22
R22: 6,6-Dimethyl-2-norpinene-2-ethano (CAS NO.128-50-7) is harmful if swallowed.