CAS No.143-66-8,Sodium tetraphenylboron Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	143-66-8
Name:	Sodium tetraphenylboron
Article Data:	33

Formula:	C₂₄H₂₀BNa
Molecular Weight:	342.224
Synonyms:	Borate(1-),tetraphenyl-, sodium (8CI,9CI);Kalibor;Kalignost;Kariporu K;Sodiumtetrakis(phenyl) borate;Sodium tetraphenylborate(NaPh4B);Sodium tetraphenylborate(1-);Sodiumtetraphenylboride(1-);Tetraphenyl boron sodium salt;Tetraphenyl sodium borate;
EINECS:	205-605-5
Density:	1.15 g/cm3
Melting Point:	300 °C
Solubility:	Soluble in water
Appearance:	white powder
Hazard Symbols:	Xn,Xi
Risk Codes:	22-36/37/38
Safety:	26-36/37
PSA:	0.00000
LogP:	3.06400

Synthetic route

: phenylmagnesium bromide

: 143-66-8
sodium tetraphenyl borate

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate anschliessendes Behandeln mit H2O und NaCl;
With sodium tetrafluoroborate; diethyl ether anschliessendes Behandeln mit wss.NaCl;

: 960-71-4
triphenylborane

: 143-66-8
sodium tetraphenyl borate

Conditions

Conditions	Yield
With sodium tetraethylborate In xylene Heating;

: sodium perchlorate

: 3244-41-5
potassium tetraphenylborate

A: potassium perchlorate

B: 143-66-8
sodium tetraphenyl borate

Conditions

Conditions	Yield
In acetone filtration, evapn. of filtrate;
In acetone filtration, evapn. of filtrate;

...Expand

: 109-63-7
trifluoroborane diethyl ether

: 100-58-3
phenylmagnesium bromide

: 7647-14-5
sodium chloride

: 143-66-8
sodium tetraphenyl borate

Conditions

Conditions	Yield
extrn. with dry acetone;
In diethyl ether; water ether layer is evapd.; residue dissolved in water; satd. with NaCl;
extrn. with dry acetone;
In diethyl ether; water ether layer is evapd.; residue dissolved in water; satd. with NaCl;

...Expand

: 13755-29-8
sodium tetrafluoroborate

: 100-58-3
phenylmagnesium bromide

: 7647-14-5
sodium chloride

: 143-66-8
sodium tetraphenyl borate

Conditions

Conditions	Yield
In tetrahydrofuran; water THF layer is again treated with aq. NaCl;
In tetrahydrofuran C6H5Mg is reacted with Na; poured into satd. soln. of NaCl; extrn. with THF; removing solvent in vac., stirring with CHCl3;
In not given organic layer is evapd.; residue freeing from biphenyl by extrn. with CHCl3; recrystn. from ether;

...Expand

: 7637-07-2
boron trifluoride

: 497-19-8
sodium carbonate

: 100-58-3
phenylmagnesium bromide

: 143-66-8
sodium tetraphenyl borate

Conditions

Conditions	Yield
In diethyl ether; water distilling off the ether, adding H2O and calcd. amt. of Na2CO3;
In diethyl ether; water distilling off the ether, adding H2O and calcd. amt. of Na2CO3;

...Expand

: 7440-23-5
sodium

: 10294-34-5
boron trichloride

: 108-90-7
chlorobenzene

: 143-66-8
sodium tetraphenyl borate

Conditions

Conditions	Yield
With hydrogenchloride In xylene below 30°C; reaction mixture pured into ice, organic layer separated, washed with water, aqueous layers are neutralized with 6N HCl;

...Expand

: 124-41-4
sodium methylate

: 109-63-7
trifluoroborane diethyl ether

: 100-58-3
phenylmagnesium bromide

: 143-66-8
sodium tetraphenyl borate

Conditions

Conditions	Yield
With ammonium salt

...Expand

: 109-63-7
trifluoroborane diethyl ether

: 100-58-3
phenylmagnesium bromide

: 143-66-8
sodium tetraphenyl borate

Conditions

Conditions	Yield
With sodium carbonate; sodium chloride In diethyl ether water cooling, stirring, adding the BF3*(C2H5)2O soln. drop by drop, evapn. of solvent, taking up the residue with water; precipitation of Mg by adding of Na2CO3, saturation with NaCl, extrn. in Soxlet-equipment with ether;	55-60
With Na2CO3; NaCl In diethyl ether water cooling, stirring, adding the BF3*(C2H5)2O soln. drop by drop, evapn. of solvent, taking up the residue with water; precipitation of Mg by adding of Na2CO3, saturation with NaCl, extrn. in Soxlet-equipment with ether;	55-60

: 14637-34-4
ammonium tetraphenylborate

: 1310-73-2
sodium hydroxide

A: 7664-41-7
ammonia

B: 143-66-8
sodium tetraphenyl borate

Conditions

Conditions	Yield
In water little excess of NaOH, boiling;
In water little excess of NaOH, boiling;

...Expand

Raw Materials

960-71-4

Downstream Products

605-02-7

76-84-6

613-37-6

36330-85-5

7647-14-5

10345-87-6

836-30-6

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Chemistry

Empirical Formula: C₂₄H₂₀BNa
Molecular Weight: 342.2164
EINECS: 205-605-5
Melting point: 300 °C
Storage tempreture: 2-8 °C
Solubility: Soluble in water
Sensitive: Light sensitive
Appearance: White powder
Structure of Sodium tetraphenylboron (CAS NO.143-66-8):

IUPAC Name: Sodium tetraphenylboranuide
Canonical SMILES: [B-](C1=CC=CC=C1)(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.[Na+]
InChI: InChI=1S/C24H20B.Na/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;/q-1;+1
InChIKey: HFSRCEJMTLMDLI-UHFFFAOYSA-N
Product Category of Sodium tetraphenylboron (CAS NO.143-66-8): Boron compounds;Organometallics;Na (Sodium) Compounds (excluding simple sodium salts);Analytical Chemistry;Ion Association;Tetraphenylborates;Typical Metal Compounds

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD50	oral	288mg/kg (288mg/kg)	BEHAVIORAL: MUSCLE WEAKNESS	National Technical Information Service. Vol. OTS0555250,

Sodium tetraphenylboron (CAS NO.143-66-8) hasn't been listed as a carcinogen by NTP, IARC, ACGIH, or CA Prop 65. And the toxicological properties have not been fully investigated. You can see actual entry in RTECS for complete information.

Safety Profile

Hazard Codes: Harmful Xn, Irritant Xi
Risk Statements: 22-36/37/38
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37:Wear suitable protective clothing and gloves.
S36:Wear suitable protective clothing.

Specification

(R)-2-Amino-3-methoxypropanoic acid hydrochloride , its cas register number is Sodium tetraphenylborate ; Tetraphenylboron sodium ; and Tetraphenyl boron sodium salt . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product: Wash mouth out with water, and get medical aid immediately. Notes to physician: Treat supportively and symptomatically.
In addition, Sodium tetraphenylboron (CAS NO.143-66-8) is light sensitive. It is not compatible with strong oxidizing agents, and you must not take it with incompatible materials, light, excess heat. And also prevent it to broken down into hazardous decomposition products: Carbon monoxide, carbon dioxide, metallic oxides, boron oxides.