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7758-99-8

Basic Information
CAS No.: 7758-99-8
Name: Sulfuric acidcopper(2+) salt (1:1), hydrate (1:5)
Article Data: 457
Cas Database
Molecular Structure:
Molecular Structure of 7758-99-8 (Sulfuric acidcopper(2+) salt (1:1), hydrate (1:5))
Formula: CuSO4.5(H2O)
Molecular Weight: 159.61
Synonyms: Sulfuricacid copper(2+) salt (1:1), pentahydrate (8CI,9CI);Copper sulfate (CuSO4)pentahydrate;Copper sulfate pentahydrate;Copper(2+) sulfate pentahydrate;Copper(II) sulfate pentahydrate;Cupric sulfate pentahydrate;Copper(Ⅱ)sulfate;copper sulphate;
EINECS: 231-847-6
Density: 2.284 g/cm3
Melting Point: 110 °C (dec.)(lit.)
Boiling Point: 330oC at 760 mmHg
Flash Point: N/A
Solubility: 320 g/L (20 °C) in water
Appearance: Blue crystalline granules or powder
Hazard Symbols: HarmfulXn, DangerousN, IrritantXi
Risk Codes: 22-36/38-50/53-52/53-36-36/37/38-20/21/22
Safety: 22-60-61-26-36
Transport Information: UN 3288 6.1/PG 3
PSA: 134.79000
LogP: -0.58120
Synthetic route

copper(I) oxide

77-78-1

dimethyl sulfate

7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
at 160℃; for 0.166667h; Inert atmosphere;94%
22205-45-4

copper(I) sulfide

A

copper(I) oxide

B

7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
With oxygen In neat (no solvent) byproducts: SO2; at 500°C, O2-N2-mixtures with up to 60% O2;;A 50%
B n/a
With O2 In neat (no solvent) byproducts: SO2; at 500°C, O2-N2-mixtures with up to 60% O2;;A 50%
B n/a
With oxygen byproducts: SO2; over 500°C;

copper (II) carbonate hydroxide

7664-93-9

sulfuric acid

7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
In water

Cu(2+)*2Cu(1+)*2SO3(2-)=Cu(CuSO3)2

A

7758-99-8

copper(II) sulfate

B

copper(II) oxide

Conditions
ConditionsYield
In neat (no solvent) byproducts: SO3(2-); thermal decompn., corundum crucible, 226°C, 260-375°C;

copper(II) sulfide

7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
In water

copper(II) sulfide

7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
In neat (no solvent) rapid oxidation to CuSO4;;
In neat (no solvent) oxidation;;
In neat (no solvent) rapid oxidation to CuSO4;;
In neat (no solvent) oxidation;;
7757-82-6

sodium sulfate

A

7758-99-8

copper(II) sulfate

B

1310-73-2

sodium hydroxide

Conditions
ConditionsYield
In not given Electrolysis; arrangement with diaphragms; Cu anode; liquid film between 2 porous walls of separation between anode and cathode region, regenaration by circulation;;

iron sulfide

copper(II) oxide

A

iron(III) oxide

B

7758-99-8

copper(II) sulfate

iron(III) sulfate

22205-45-4

copper(I) sulfide

iron sulfide

7647-14-5

sodium chloride

copper(II) oxide

A

iron(III) oxide

B

7758-99-8

copper(II) sulfate

C

copper dichloride

Conditions
ConditionsYield
With sulfur dioxide; oxygen byproducts: Na2SO4;
With sulfur dioxide; oxygen byproducts: Na2SO4;
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Consensus Reports

Copper and its compounds are on the Community Right-To-Know List.

Standards and Recommendations

ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3

Specification

The Copper sulfate pentahydrate, with the CAS registry number 7758-99-8, is also known as Copper (II) sulfate.It belongs to the product categories of Metabolites;Metal and Ceramic Science;Molluscicides;Pesticides;Pesticides &;Salts;Ultra-High Purity Materials. This chemical's molecular formula is CuSO4.5(H2O) and molecular weight is 249.68. What's more,Its systematic name is Copper sulfate pentahydrate.

Physical properties about Copper sulfate pentahydrate are: (1)mp: 110 °C (dec.)(lit.); (2)density: 2.284; (3)vapor pressure: 7.3 mm Hg ( 25 °C); (4)storage temp: Store at RT; (5)solubility: 320 g/L (20°C); (6)Water Solubility: 320 g/L (20 oC); (7)Merck: 14,2653.

Copper sulfate pentahydrate can be dehydrated by heating. Serves as a weak oxidizing agent. Causes hydroxylamine to ignite. Gains water readily. The hydrated salt is vigorously reduced by hydroxylamine [Mellor 8:292(1946-1947)]. Both forms are incompatible with finely powdered metals. Both are incompatible with magnesium, corrode steel and iron, may react with alkalis, phosphates, acetylene gas, hydrazine, or nitromethane, and may react with beta-naphthol, propylene glycol, sulphathiazole and triethanolamine if the pH exceeds 7 . Both act as acidic salts, corrode metals and irritate tissues.

The Copper sulfate pentahydrate is harmful by inhalation, in contact with skin and if swallowed. It is irritating to eyes, respiratory system and skin.The Copper sulfate pentahydrate is very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment, so it should be avoided release to the environment. Refer to special instructions safety data sheet .This material and/or its container must be disposed of as hazardous waste.When you use it,wear suitable protective clothing.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Do not breathe dust.

You can still convert the following datas into molecular structure:
(1)SMILES:O.O.O.O.O.[O-]S(=O)(=O)[O-].[Cu+2];
(2)Std. InChI:InChI=1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2;
(3)Std. InChIKey:JZCCFEFSEZPSOG-UHFFFAOYSA-L;

The toxicity data of Copper sulfate pentahydrate as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
bird - wild LDLo oral 300mg/kg (300mg/kg)   Australian Veterinary Journal. Vol. 16, Pg. 147, 1940.
bird - wild LDLo oral 300mg/kg (300mg/kg) BEHAVIORAL: COMA

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
Australian Veterinary Journal. Vol. 16, Pg. 147, 1940.
dog LDLo oral 60mg/kg (60mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
domestic animals - goat/sheep LDLo oral 5mg/kg (5mg/kg) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"

BLOOD: HEMORRHAGE

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
Journal of Comparative Pathology. Vol. 82, Pg. 47, 1972.
duck LDLo oral 600mg/kg (600mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: COMA
Australian Veterinary Journal. Vol. 16, Pg. 147, 1940.
guinea pig LDLo subcutaneous 62mg/kg (62mg/kg) BEHAVIORAL: COMA

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"

AUTONOMIC NERVOUS SYSTEM: OTHER (DIRECT) PARASYMPATHOMIMETIC
British Medical Journal. Vol. 2, Pg. 217, 1913.
human LDLo oral 1088mg/kg (1088mg/kg) BEHAVIORAL: COMA

BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA
Indian Practitioner. Vol. 18, Pg. 807, 1965.
human TDLo oral 272mg/kg (272mg/kg) KIDNEY, URETER, AND BLADDER: OTHER CHANGES

BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA
Indian Practitioner. Vol. 18, Pg. 807, 1965.
mammal (species unspecified) LD50 intraperitoneal 7500ug/kg (7.5mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS

GASTROINTESTINAL: NAUSEA OR VOMITING
Journal of Animal Science. Vol. 55, Pg. 337, 1982.
man LDLo unreported 221mg/kg (221mg/kg)   "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970.
man TDLo oral 429mg/kg (429mg/kg) VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION

BEHAVIORAL: SLEEP
Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 41, Pg. 193, 1999.
mouse LD50 intraperitoneal 33mg/kg (33mg/kg)   Biochemical Pharmacology. Vol. 14, Pg. 289, 1965.
pigeon LDLo oral 1gm/kg (1000mg/kg)   Australian Veterinary Journal. Vol. 16, Pg. 147, 1940.
pigeon LDLo oral 1gm/kg (1000mg/kg) BEHAVIORAL: COMA

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
Australian Veterinary Journal. Vol. 16, Pg. 147, 1940.
rat LD50 intraperitoneal 18700ug/kg (18.7mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 53(4), Pg. 78, 1988.
rat LD50 oral 300mg/kg (300mg/kg)   "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 2, Pg. 182, 1977.
rat LD50 skin > 2gm/kg (2000mg/kg)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 18, Pg. S161, 1993.

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