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CAS No.: | 7758-99-8 |
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Name: | Copper sulfate pentahydrate |
Article Data: | 457 |
Cas Database | |
Molecular Structure: | |
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Formula: | CuSO4.5(H2O) |
Molecular Weight: | 159.61 |
Synonyms: | Sulfuricacid copper(2+) salt (1:1), pentahydrate (8CI,9CI);Copper sulfate (CuSO4)pentahydrate;Copper sulfate pentahydrate;Copper(2+) sulfate pentahydrate;Copper(II) sulfate pentahydrate;Cupric sulfate pentahydrate;Copper(Ⅱ)sulfate;copper sulphate; |
EINECS: | 231-847-6 |
Density: | 2.284 g/cm3 |
Melting Point: | 110 °C (dec.)(lit.) |
Boiling Point: | 330oC at 760 mmHg |
Solubility: | 320 g/L (20 °C) in water |
Appearance: | Blue crystalline granules or powder |
Hazard Symbols: |
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Risk Codes: | 22-36/38-50/53-52/53-36-36/37/38-20/21/22 |
Safety: | 22-60-61-26-36 |
Transport Information: | UN 3288 6.1/PG 3 |
PSA: | 134.79000 |
LogP: | -0.58120 |
Conditions | Yield |
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at 160℃; for 0.166667h; Inert atmosphere; | 94% |
Conditions | Yield |
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With oxygen In neat (no solvent) byproducts: SO2; at 500°C, O2-N2-mixtures with up to 60% O2;; | A 50% B n/a |
With O2 In neat (no solvent) byproducts: SO2; at 500°C, O2-N2-mixtures with up to 60% O2;; | A 50% B n/a |
With oxygen byproducts: SO2; over 500°C; |
Conditions | Yield |
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In water |
Conditions | Yield |
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In neat (no solvent) byproducts: SO3(2-); thermal decompn., corundum crucible, 226°C, 260-375°C; |
Conditions | Yield |
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In water |
Conditions | Yield |
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In neat (no solvent) rapid oxidation to CuSO4;; | |
In neat (no solvent) oxidation;; | |
In neat (no solvent) rapid oxidation to CuSO4;; | |
In neat (no solvent) oxidation;; |
Conditions | Yield |
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In not given Electrolysis; arrangement with diaphragms; Cu anode; liquid film between 2 porous walls of separation between anode and cathode region, regenaration by circulation;; |
A
copper
B
copper(II) sulfate
Conditions | Yield |
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In sulfuric acid diln. of H2SO4; | |
In sulfuric acid aq. H2SO4; diln. of H2SO4; |
Conditions | Yield |
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With sulfur dioxide; oxygen byproducts: Na2SO4; | |
With sulfur dioxide; oxygen byproducts: Na2SO4; |
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Copper and its compounds are on the Community Right-To-Know List.
ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3
The Copper sulfate pentahydrate, with the CAS registry number 7758-99-8, is also known as Copper (II) sulfate.It belongs to the product categories of Metabolites;Metal and Ceramic Science;Molluscicides;Pesticides;Pesticides &;Salts;Ultra-High Purity Materials. This chemical's molecular formula is CuSO4.5(H2O) and molecular weight is 249.68. What's more,Its systematic name is Copper sulfate pentahydrate.
Physical properties about Copper sulfate pentahydrate are: (1)mp: 110 °C (dec.)(lit.); (2)density: 2.284; (3)vapor pressure: 7.3 mm Hg ( 25 °C); (4)storage temp: Store at RT; (5)solubility: 320 g/L (20°C); (6)Water Solubility: 320 g/L (20 oC); (7)Merck: 14,2653.
Copper sulfate pentahydrate can be dehydrated by heating. Serves as a weak oxidizing agent. Causes hydroxylamine to ignite. Gains water readily. The hydrated salt is vigorously reduced by hydroxylamine [Mellor 8:292(1946-1947)]. Both forms are incompatible with finely powdered metals. Both are incompatible with magnesium, corrode steel and iron, may react with alkalis, phosphates, acetylene gas, hydrazine, or nitromethane, and may react with beta-naphthol, propylene glycol, sulphathiazole and triethanolamine if the pH exceeds 7 . Both act as acidic salts, corrode metals and irritate tissues.
The Copper sulfate pentahydrate is harmful by inhalation, in contact with skin and if swallowed. It is irritating to eyes, respiratory system and skin.The Copper sulfate pentahydrate is very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment, so it should be avoided release to the environment. Refer to special instructions safety data sheet .This material and/or its container must be disposed of as hazardous waste.When you use it,wear suitable protective clothing.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Do not breathe dust.
You can still convert the following datas into molecular structure:
(1)SMILES:O.O.O.O.O.[O-]S(=O)(=O)[O-].[Cu+2];
(2)Std. InChI:InChI=1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2;
(3)Std. InChIKey:JZCCFEFSEZPSOG-UHFFFAOYSA-L;
The toxicity data of Copper sulfate pentahydrate as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
bird - wild | LDLo | oral | 300mg/kg (300mg/kg) | Australian Veterinary Journal. Vol. 16, Pg. 147, 1940. | |
bird - wild | LDLo | oral | 300mg/kg (300mg/kg) | BEHAVIORAL: COMA BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | Australian Veterinary Journal. Vol. 16, Pg. 147, 1940. |
dog | LDLo | oral | 60mg/kg (60mg/kg) | "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935. | |
domestic animals - goat/sheep | LDLo | oral | 5mg/kg (5mg/kg) | GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" BLOOD: HEMORRHAGE BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | Journal of Comparative Pathology. Vol. 82, Pg. 47, 1972. |
duck | LDLo | oral | 600mg/kg (600mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: COMA | Australian Veterinary Journal. Vol. 16, Pg. 147, 1940. |
guinea pig | LDLo | subcutaneous | 62mg/kg (62mg/kg) | BEHAVIORAL: COMA GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" AUTONOMIC NERVOUS SYSTEM: OTHER (DIRECT) PARASYMPATHOMIMETIC | British Medical Journal. Vol. 2, Pg. 217, 1913. |
human | LDLo | oral | 1088mg/kg (1088mg/kg) | BEHAVIORAL: COMA BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA | Indian Practitioner. Vol. 18, Pg. 807, 1965. |
human | TDLo | oral | 272mg/kg (272mg/kg) | KIDNEY, URETER, AND BLADDER: OTHER CHANGES BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA | Indian Practitioner. Vol. 18, Pg. 807, 1965. |
mammal (species unspecified) | LD50 | intraperitoneal | 7500ug/kg (7.5mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS GASTROINTESTINAL: NAUSEA OR VOMITING | Journal of Animal Science. Vol. 55, Pg. 337, 1982. |
man | LDLo | unreported | 221mg/kg (221mg/kg) | "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970. | |
man | TDLo | oral | 429mg/kg (429mg/kg) | VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION BEHAVIORAL: SLEEP | Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 41, Pg. 193, 1999. |
mouse | LD50 | intraperitoneal | 33mg/kg (33mg/kg) | Biochemical Pharmacology. Vol. 14, Pg. 289, 1965. | |
pigeon | LDLo | oral | 1gm/kg (1000mg/kg) | Australian Veterinary Journal. Vol. 16, Pg. 147, 1940. | |
pigeon | LDLo | oral | 1gm/kg (1000mg/kg) | BEHAVIORAL: COMA BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | Australian Veterinary Journal. Vol. 16, Pg. 147, 1940. |
rat | LD50 | intraperitoneal | 18700ug/kg (18.7mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 53(4), Pg. 78, 1988. | |
rat | LD50 | oral | 300mg/kg (300mg/kg) | "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 2, Pg. 182, 1977. | |
rat | LD50 | skin | > 2gm/kg (2000mg/kg) | Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 18, Pg. S161, 1993. |