CAS No.102-82-9,Tributylamine Suppliers

Products Categories

Pharmaceutical (31)
Organic Chemicals (16)
Others (5)
Adhesive and Sealant (3)
Synthetic Flavours & Fragrances (2)
Materials (2)
Agrochemicals (1)
Reagent (1)

Basic Information

Molecular Structure:
CAS No.:	102-82-9
Name:	Tributylamine
Article Data:	141

Formula:	C₁₂H₂₇N
Molecular Weight:	185.353
Synonyms:	Tributylamine(7CI,8CI);N,N-Dibutyl-1-butanamine;Tri-n-butylamine;Tris-n-butylamine;Tributylamine;
EINECS:	203-058-7
Density:	0.792 g/cm³
Melting Point:	-70 °C(lit.)
Boiling Point:	215.3 °C at 760 mmHg
Flash Point:	63.3 °C
Solubility:	0.386 g/L (25 °C) in water
Appearance:	pale yellow liquid with an amine odour
Hazard Symbols:	T,N
Risk Codes:	22-23/24-38-51/53-23/24/25
Safety:	26-36/37-45-61-36/37/39-28A
Transport Information:	UN 2542 6.1/PG 2
PSA:	3.24000
LogP:	3.68870

Synthetic route

: 111-92-2
dibutylamine

: 123-72-8
butyraldehyde

: 102-82-9
tributyl-amine

Conditions

Conditions	Yield
With polymethylhydrosiloxane; bis(1,5-cyclooctadiene)diiridium(I) dichloride In tetrahydrofuran at 50℃; for 5h;	99%
With NiO doped titania In butan-1-ol Reagent/catalyst; Irradiation;	93%
With hydrogen; nickel at 120 - 140℃;

: 71-36-3
butan-1-ol

: 102-82-9
tributyl-amine

Conditions

Conditions	Yield
With C42H44ClN4P2Ru(1+)*Cl(1-); potassium tert-butylate; ammonium formate at 100℃; for 72h;	95%
With 1-hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II); ammonium chloride; potassium hydroxide at 140℃; for 39h; Sealed tube; Inert atmosphere;	99 %Chromat.

: 7529-21-7
tributylamine N-oxide

: 102-82-9
tributyl-amine

Conditions

Conditions	Yield
With BER-CuSO4 In methanol for 3h; Ambient temperature;	93%
With Dimethylphenylsilane In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;	88%
With bis(tri-n-butyltin) In tetrahydrofuran at 50℃; for 1h;	84%
With BER-CuSO4 In methanol for 3h; Ambient temperature; other tertiary amine N-oxides and aromatic N-oxides, var. temp. and time;

: 109-74-0
propyl cyanide

: 111-87-5
octanol

: 71-36-3
butan-1-ol

A: 102-82-9
tributyl-amine

B: 41145-51-1
octyldibutylamine

Conditions

Conditions	Yield
With hydrogen; copper at 240℃; under 7600 Torr;	A n/a B 92%

...Expand

: 109-65-9
1-bromo-butane

: 102-82-9
tributyl-amine

Conditions

Conditions	Yield
With 5-methyl-1,3,4-thiadiazol-2-amine; potassium hydroxide In ethanol; water at 25℃; for 1h;	85%
With sodium hydroxide; urea at 120℃; under 3102.97 Torr; for 40h;	76.5%
With ammonia

: 110-68-9
N-n-butyl-N-methylamine

A: 102-82-9
tributyl-amine

B: 927-62-8
N,N-dimethylbutylamine

Conditions

Conditions	Yield
palladium at 160℃; for 5h;	A 8% B 85%

: 109-74-0
propyl cyanide

: 71-36-3
butan-1-ol

: 143-08-8
nonyl alcohol

A: 102-82-9
tributyl-amine

B: 93658-58-3
1-Dibutylamino-nonan

Conditions

Conditions	Yield
With hydrogen; copper at 240℃; under 7600 Torr;	A n/a B 85%

...Expand

: 109-74-0
propyl cyanide

A: 102-82-9
tributyl-amine

B: butyl-1-idene-di-n-butylamine

C: 111-92-2
dibutylamine

Conditions

Conditions	Yield
With hydrogen at 200℃;	A 13% B 2% C 85%

...Expand

: 109-74-0
propyl cyanide

: 112-30-1
1-Decanol

: 71-36-3
butan-1-ol

A: 102-82-9
tributyl-amine

B: N,N-dibutyldecan-1-amine

Conditions

Conditions	Yield
With hydrogen; copper at 240℃; under 7600 Torr;	A n/a B 84%

...Expand

: 111-92-2
dibutylamine

: 102-82-9
tributyl-amine

Conditions

Conditions	Yield
With chlorohydridocarbonylbis(tricyclohexylphosphine)ruthenium(II) In toluene at 120℃; for 24h; Catalytic behavior; Reagent/catalyst; Schlenk technique; Inert atmosphere;	82%
With aluminium trichloride
With palladium/alumina at 199.84℃; under 760.051 Torr; Kinetics;

Raw Materials

112-72-1

7529-21-7

75-04-7

111-66-0

75-85-4

112-53-8

71-36-3

111-92-2

Downstream Products

109-73-9

51-28-5

942-92-7

Country:
Business Type:
All

Lab/Research institutions

Trading Company

Manufacturers

Other
Certificate:
Manufacturer

Enterprise Authentication

ISO

GMP

FDA

HALAL

Display:default sort
Suppiers of more reward points first

New supplier

Total:55 Page 1 of 2 1 2 Next>>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 102-82-9

Chemistry

Specification

The Tributylamine is an organic compound with the formula C₁₂H₂₇N. The IUPAC name of this chemical is N,N-dibutylbutan-1-amine. With the CAS registry number 102-82-9, it is also named as 1-butanamine, N,N-dibutyl-. The product's categories are Amines; C11 to C38; Nitrogen Compounds; Analytical Reagents for General Use; Puriss p.a. ACS; T-Z, Puriss p.a. ACS. Besides, it is pale yellow liquid with an amine odour, which should be stored in a cool and well-ventilated place. It is used as oil additives, solvents, pharmaceutical intermediates, pesticides, emulsifier, plasticizer, mineral flotation agent and surface active agent.

Physical properties about Tributylamine are:
(1)ACD/LogP: 4.85; (2)ACD/LogD (pH 5.5): 1.76; (3)ACD/LogD (pH 7.4): 2.37; (4)ACD/BCF (pH 5.5): 2.34; (5)ACD/BCF (pH 7.4): 9.55; (6)ACD/KOC (pH 5.5): 8.51; (7)ACD/KOC (pH 7.4): 34.7; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 9; (10)Polar Surface Area: 3.24 Å²; (11)Index of Refraction: 1.437; (12)Molar Refractivity: 61.36 cm3; (13)Molar Volume: 233.8 cm³; (14)Polarizability: 24.32×10^-24cm³; (15)Surface Tension: 27.4 dyne/cm; (16)Density: 0.792 g/cm³; (17)Flash Point: 63.3 °C; (18)Enthalpy of Vaporization: 45.16 kJ/mol; (19)Boiling Point: 215.3 °C at 760 mmHg; (20)Vapour Pressure: 0.149 mmHg at 25°C.

Preparation of Tributylamine:
This chemical can be prepared by butyl-methyl-amine. This reaction will need catalyst palladium black. The reaction time is 5 hours with reaction temperature of 160 °C. The yield is about 85%.

Uses of Tributylamine:
It can be used to produce methyl methyltributylammonium sulfate. The reaction time is 3 hours with reaction temperature of 80 °C. The yield is about 84.6%.

When you are using Tributylamine, please be cautious about it as the following:
It is harmful if swallowed and toxic by inhalation, in contact with skin and if swallowed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating skin and toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. When you are using it, wear suitable gloves and eye/face protection and avoid release to the environment. Refer to special instructions/safety data sheet. After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer). In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: N(CCCC)(CCCC)CCCC
(2)InChI: InChI=1/C12H27N/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
(3)InChIKey: IMFACGCPASFAPR-UHFFFAOYAY
(4)Std. InChI: InChI=1S/C12H27N/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
(5)Std. InChIKey: IMFACGCPASFAPR-UHFFFAOYSA-N

The toxicity data of Tributylamine is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
guinea pig	LD50	oral	350mg/kg (350mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 42(12), Pg. 36, 1977.
mammal (species unspecified)	LD50	intraperitoneal	107mg/kg (107mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: EXCITEMENT	Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 28(11), Pg. 50, 1984.
mammal (species unspecified)	LD50	oral	888mg/kg (888mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: EXCITEMENT	Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 28(11), Pg. 50, 1984.
mouse	LD50	oral	114mg/kg (114mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 42(12), Pg. 36, 1977.
rabbit	LD50	oral	615mg/kg (615mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 42(12), Pg. 36, 1977.
rabbit	LD50	skin	250uL/kg (0.25mL/kg)		Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.
rat	LCLo	inhalation	75ppm/4H (75ppm)		Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.
rat	LD50	oral	114mg/kg (114mg/kg)		Trudy Leningradskogo Sanitarno-Gigienicheskogo Meditsinskogo Instituta. Vol. 115, Pg. 57, 1977.
rat	LDLo	subcutaneous	380mg/kg (380mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: COMA LUNGS, THORAX, OR RESPIRATION: DYSPNEA	Journal of Pharmacology and Experimental Therapeutics. Vol. 20, Pg. 435, 1923.