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109-90-0

Basic Information
CAS No.: 109-90-0
Name: Ethyl isocyanate
Article Data: 87
Molecular Structure:
Molecular Structure of 109-90-0 (Ethyl isocyanate)
Formula: C3H5NO
Molecular Weight: 71.0788
Synonyms: Isocyanicacid, ethyl ester (6CI,8CI);Isocyanatoethane;NSC 89687;
EINECS: 203-717-9
Density: 0.87 g/cm3
Melting Point: <-50
Boiling Point: 60 °C at 760 mmHg
Flash Point: 23 °C
Solubility: insoluble in water
Appearance: Colorless liquid
Hazard Symbols: FlammableF, ToxicT
Risk Codes: 11-20/21-25-36/37/38-42
Safety: 16-26-36/37/39-45
Transport Information: UN 2481 3/PG 1
PSA: 29.43000
LogP: 0.34210
Synthetic route
32315-10-9

bis(trichloromethyl) carbonate

75-04-7

ethylamine

109-90-0

ethyl isocyanate

Conditions
ConditionsYield
With triethylamine In dichloromethane100%
75-44-5

phosgene

75-04-7

ethylamine

109-90-0

ethyl isocyanate

Conditions
ConditionsYield
In toluene at 320 - 340℃; under 37.5038 Torr; Temperature;97.6%
542-85-8

Ethyl isothiocyanate

109-90-0

ethyl isocyanate

Conditions
ConditionsYield
With air; palladium dichloride In 1,4-dioxane Heating;89%
6135-31-5

methyl N-ethylcarbamate

109-90-0

ethyl isocyanate

Conditions
ConditionsYield
With Phenyltrichlorosilane at 100 - 155℃; for 0.5h;87.3%
41891-13-8

ethyl carbamoyl chloride

111-27-3

hexan-1-ol

A

67821-25-4

N-ethyl-carbamic acid hexyl ester

B

109-90-0

ethyl isocyanate

Conditions
ConditionsYield
In 1,2-dichloro-benzeneA n/a
B 81%
41891-13-8

ethyl carbamoyl chloride

109-90-0

ethyl isocyanate

Conditions
ConditionsYield
In chlorobenzene77%
With N,N-dimethyl-aniline
With triethylamine at 40℃; for 0.333333h; Yield given;
With triethylamine In Dimethyldisulphide at 0 - 5℃; pH=8 - 8.5;
621-04-5

1-ethyl-3-phenylurea

A

(Dichloro-phenyl-silanyl)-phenyl-amine

B

109-90-0

ethyl isocyanate

Conditions
ConditionsYield
With Phenyltrichlorosilane at 160 - 205℃; for 1h;A n/a
B 72.5%
19265-06-6

ethyl (chloroformyl)methyl carbamate

109-90-0

ethyl isocyanate

Conditions
ConditionsYield
With aluminium trichloride at 193 - 220℃; for 0.5h;64.3%
61031-53-6

3-ethyl-4-hydroxy-5,5-dimethyl-4-phenyl-oxazolidin-2-one

A

769-60-8

2-methyl-1-phenylprop-2-en-1-one

B

7473-98-5

2-hydroxy-2-methylpropiophenone

C

3155-01-9

3-hydroxy-3-phenyl-butan-2-one

D

109-90-0

ethyl isocyanate

Conditions
ConditionsYield
In benzene at 550℃;A 41%
B 14%
C 45%
D 44%

N-nitro-N'-ethyl-urea

109-90-0

ethyl isocyanate

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    MSDS/COA Download

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    ChemicalName:EthylisocyanateSynonyms:Isocyanicacid,ethylester MolecularFormula:CH3CH2NCOMolecularWeight:71.1 BoilingPoint:60°C,densi…Appearance:Colorless to light yellow liquid Storage:Keep container closed when not in use. Store in

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    CAS no. : 109-90-0 English name: baton rouge isocyanate English synonyms: C2H5NCO; Baton rouge 爄 socyanate; Baton rouge ISOCYANATE; Isocyanatoethane; Isocyanato - Ethan; Isocyanatoethene; Isocyanato - Ethane; Isocyanated ethyle '; Ethane, i

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Chemistry

1.IUPAC Name:  Isocyanatoethane
2.Synonyms:Ethyl isocyanate ; Isocyanic acid ethyl ester ; 1-Isocyanatoethane ; C2H5NCO ; Ethane,isocyanato- ; Isocyanated’ethyle ; Isocyanato-ethan ; Isocyanatoethane 
3.The Molecular formula of  Ethyl isocyanate (109-90-0) : C3H5NO
4.The Molecular Weight of  Ethyl isocyanate (109-90-0) : 71.08 g/mol
5.The Molecular Structure of  Ethyl isocyanate (109-90-0) : 
6.Density: 0.898 g/mL at 25 °C(lit.)
7.Boiling point:  60 °C(lit.)
8.Flash point:  20 °F
9.Solubility in water: Insoluble
10.Refractive index (nD): 1.381(lit.)
11.Appearance:  colorless liquid
12.Storage temp: 2-8°C
13.vapor pressure: 209 mmHg at 25°C

Uses

  Ethyl isocyanate (109-90-0) is used to make pharmaceuticals and pesticides.

Toxicity Data With Reference

1.    

mmo-sat 50 µg/plate ABCHA6 44,3017,80

2.    

ivn-mus LD50:56 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#02910 .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intravenous route. Mutation data reported. A flammable liquid. When heated to decomposition it emits toxic fumes of NOx. See also CYANATES.
 Hazard Codes  F,T
F: Highly Flammable
T:  Toxic
Risk Statements:  11-20/21-25-36/37/38-42
R11:  Highly Flammable
R20/21:  Harmful by inhalation and if swallowed
R36/37/38:  Irritating to eyes, respiratory system and skin
R42:  May cause sensitization by inhalation
Safety Statements  16-26-36/37/39-45
S16:  Keep away from sources of ignition - No smoking
S26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
 WGK Germany:  3

Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid, Poison; DOT Class: 6.1; Label: Poison; DOT Class: 6.1; Label: Poison, Flammable Liquid; DOT Class: 3; Label: Flammable Liquid, Poison

Specification

 Ethyl isocyanate (109-90-0) may react with water to produce a corrosive liquid and carbon dioxide gas.