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CAS No.: | 623-72-3 |
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Name: | Propanoic acid, 3-hydroxy-, ethyl ester |
Article Data: | 34 |
Molecular Structure: | |
Formula: | C5H10O3 |
Molecular Weight: | 118.133 |
Synonyms: | Ethyl 3-hydroxypropanoate;Propanoic acid, 3-hydroxy-, ethyl ester; |
Density: | 1.054g/cm3 |
Boiling Point: | 187.499oC at 760 mmHg |
Flash Point: | 79.075oC |
PSA: | 46.53000 |
LogP: | -0.06810 |
Conditions | Yield |
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With oxygen; tetraethylammonium perchlorate In N,N-dimethyl-formamide at 20℃; electroreduction at -1.1 V; | A 70% B 20 % Chromat. |
With oxygen In N,N-dimethyl-formamide at 20℃; Product distribution; electrolysis of the oxygen saturated solution at -1,1 V; 0.1 M TEAP; further esters; | A 70% B 20 % Chromat. |
Conditions | Yield |
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With sulfuric acid at 78 - 80℃; under 760.051 Torr; for 10h; Time; | 67.24% |
With copper(II) sulfate | |
amberlyst-15 at 20℃; for 19h; Product distribution / selectivity; | 17 - 68 %Chromat. |
Nafion NR-50 at 20℃; for 21h; Product distribution / selectivity; | 71 %Chromat. |
Conditions | Yield |
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With Amberlyst 15 | 66% |
Conditions | Yield |
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With hydrogenchloride; thionyl chloride In water at 0 - 20℃; for 6h; Reflux; | 50% |
ethyl 3-(benzyloxy)propanoate
ethyl 3-hydroxypropanoate
Conditions | Yield |
---|---|
With palladium 10% on activated carbon; hydrogen In ethanol at 20℃; | 41% |
diazoacetic acid ethyl ester
methanol
A
methyl methoxyacetate
B
ethyl 2-methoxyacetate
C
ethyl 3-hydroxypropanoate
D
Ethoxyessigsaeure-methylester
Conditions | Yield |
---|---|
Irradiation; | A 3% B 40% C 8% D 20% |
β-Propiolactone
diethoxydibutyltin
A
ethyl 3-hydroxypropanoate
B
3-Hydroxy-propionic acid 2-ethoxycarbonyl-ethyl ester
Conditions | Yield |
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In chloroform Heating; | A 12% B 3.6% |
Conditions | Yield |
---|---|
With silver(l) oxide |
Conditions | Yield |
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(i) AgOCN, toluene, (ii) /BRN= 1718733/, H2SO4; Multistep reaction; |