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Basic Information
| CAS No.: | 628-35-3 |
|---|---|
| Name: | 2-hydroxyethyl formate |
| Molecular Structure: | |
|
|
|
| Formula: | C3H6 O3 |
| Molecular Weight: | 90.0788 |
| Synonyms: | 1,2-Ethanediol,monoformate (9CI);Ethylene glycol, formate (6CI,7CI);Ethylene glycol,monoformate (8CI);2-Hydroxyethyl formate;Glycol monoformate;NSC 3770; |
| EINECS: | 211-038-4 |
| Density: | 1.136g/cm3 |
| Boiling Point: | 175.1°C at 760 mmHg |
| Flash Point: | 77.8°C |
| PSA: | 46.53000 |
| LogP: | -0.21240 |
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Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| With oxygen; cobalt(II) decanoate at 40℃; | A 80% B n/a |
| With dibenzo-18-crown-6; oxygen; cobalt(II) decanoate at 40℃; Product distribution; further reagents and its concentrations, percent of conversion, rate of oxidation; | |
| With dibenzo-18-crown-6; oxygen; cobalt(II) decanoate at 40℃; |
- 646-06-0
1,3-DIOXOLANE
- 91-63-4
2-methylquinoline
A
- 628-35-3
ethylene glycol monoformate
B
- 89587-03-1
4-(1,3-dioxacyclopent-2-yl)-2-methylquinoline
C
- 89587-04-2
4-(1,3-dioxacyclopent-4-yl)-2-methylquinoline
Conditions
| Conditions | Yield |
|---|---|
| With Cumene hydroperoxide; sulfuric acid; iron(II) sulfate at 5 - 10℃; for 0.5h; pH 8; | A n/a B 78% C 10.5% |
| With Cumene hydroperoxide; sulfuric acid; iron(II) sulfate pH 1; | A n/a B 58% C 31.5% |
| With Cumene hydroperoxide; sulfuric acid; iron(II) sulfate at 5 - 10℃; for 0.5h; Product distribution; Mechanism; pH 8; |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With 1-methyl-pyrrolidin-2-one; N-methylcyclohexylamine; carbon dioxide; hydrogen; tris(triphenylphosphine)ruthenium(II) chloride at 140℃; under 60800 Torr; for 15h; | A 7% B 76% |
- 75-21-8
oxirane
- 124-38-9
carbon dioxide
A
- 628-35-3
ethylene glycol monoformate
B
- 64-17-5
ethanol
C
- 107-21-1
ethylene glycol
Conditions
| Conditions | Yield |
|---|---|
| With 1-Methylpyrrolidine; 1-methyl-pyrrolidin-2-one; hydrogen; tris(triphenylphosphine)ruthenium(II) chloride at 140℃; under 60800 Torr; for 15h; Product distribution; Kinetics; Mechanism; var. of catalyst, base, without base; | A 5% B 3% C 75% |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With oxygen; CoCl2 In 1,2-dimethoxyethane at 60℃; for 24h; | A 10% B 61% |
Conditions
| Conditions | Yield |
|---|---|
| With 1-Methylpyrrolidine; 1-methyl-pyrrolidin-2-one; hydrogen; dodecacarbonyl-triangulo-triruthenium at 140℃; under 60800 Torr; for 15h; | A 15% B 60% |
...Expand
- 646-06-0
1,3-DIOXOLANE
- 50-00-0
formaldehyd
A
- 5694-68-8
2-hydroxymethyl-1,3-dioxolane
B
- 628-35-3
ethylene glycol monoformate
C
- 31144-13-5
formic acid 3-hydroxypropyl ester
D
- 39239-93-5
2-(hydroxymethyl)-1,3-dioxane
E
- 107-21-1
ethylene glycol
F
- 141-46-8
Glycolaldehyde
Conditions
| Conditions | Yield |
|---|---|
| With tert-Butyl peroxybenzoate at 100 - 130℃; for 4h; Product distribution; Mechanism; further products (2-hydroxymethoxymethyl-1,3-dioxolane and CH2O homologues) isolated; also reaction with paraformaldehyde, and other initiators investigated; | A 15.8 % Chromat. B 3.2 % Chromat. C 1.66 % Chromat. D 5.8 % Chromat. E 12.1 % Chromat. F 5.1 % Chromat. |
...Expand
- 646-06-0
1,3-DIOXOLANE
A
- 96-49-1
[1,3]-dioxolan-2-one
B
- 50-00-0
formaldehyd
C
- 64-18-6
formic acid
D
- 628-35-3
ethylene glycol monoformate
E
- 107-21-1
ethylene glycol
Conditions
| Conditions | Yield |
|---|---|
| With oxygen at 70℃; for 16.5h; Product distribution; Mechanism; other substituted 1,3-dioxolanes; rate of consumption of oxygen, relative rate of formation of glycol; |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With Cumene hydroperoxide at 130℃; | |
| With Cumene hydroperoxide at 90℃; |
- 75-18-3
dimethylsulfide
- 101325-78-4
1,3-dioxolane hydrotrioxide
A
- 628-35-3
ethylene glycol monoformate
B
- 67-68-5
dimethyl sulfoxide
Conditions
| Conditions | Yield |
|---|---|
| 1.) -60 to -50 deg C, 15 min, 2.) -30 deg C, 5-6 h; |
...Expand
