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628-35-3

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Product FOB Price Min.Order Supply Ability Supplier
1,2-Ethanediol,1-formate
Cas No: 628-35-3
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
Factory Supply 2-hydroxyethyl formate
Cas No: 628-35-3
No Data 1 1 Ality Chemical Corporation Contact Supplier
2-Hydroxyethyl formate
Cas No: 628-35-3
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
TopCAS 628-35-3 with best quality
Cas No: 628-35-3
USD $ 146.0-176.0 / Gram 10 Gram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
1,2-Ethanediol,1-formate
Cas No: 628-35-3
No Data No Data 10000 Metric Ton/Month Henan Wentao Chemical Product Co., Ltd. Contact Supplier
1,2-Ethanediol,1-formate
Cas No: 628-35-3
No Data 1 Kilogram 1 Metric Ton/Day Shandong Hanjiang Chemical Co., Ltd. Contact Supplier
1,2-Ethanediol,1-formate cas:628-35-3
Cas No: 628-35-3
USD $ 100.0-150.0 / Kilogram 1 Kilogram 1000 Metric Ton/Day Wuhan Monad Medicine Tech Co.,LTD Contact Supplier
2-Hydroxyethyl formate
Cas No: 628-35-3
USD $ 100.0-100.0 / Kilogram 1 Kilogram 10000 Kilogram/Day Metric Ton/Day Zibo Hangyu Import&Export Co., Ltd Contact Supplier
1,2-Ethanediol,1-formate
Cas No: 628-35-3
No Data No Data No Data HANGZHOU CLAP TECHNOLOGY CO,.LTD Contact Supplier
2-Hydroxyethyl formate
Cas No: 628-35-3
No Data No Data No Data GIHI CHEMICALS CO.,LIMITED Contact Supplier

628-35-3 Usage

InChI:InChI=1/C3H6O3/c4-1-2-6-3-5/h3-4H,1-2H2

628-35-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Hydroxyethyl formate

1.2 Other means of identification

Product number -
Other names methanol,methyl formate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:628-35-3 SDS

628-35-3Synthetic route

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

A

1,3-Dioxolan-2-hydroperoxid
5771-94-8

1,3-Dioxolan-2-hydroperoxid

B

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

Conditions
ConditionsYield
With oxygen; cobalt(II) decanoate at 40℃;A 80%
B n/a
With dibenzo-18-crown-6; oxygen; cobalt(II) decanoate at 40℃; Product distribution; further reagents and its concentrations, percent of conversion, rate of oxidation;
With dibenzo-18-crown-6; oxygen; cobalt(II) decanoate at 40℃;
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

2-methylquinoline
91-63-4

2-methylquinoline

A

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

B

4-(1,3-dioxacyclopent-2-yl)-2-methylquinoline
89587-03-1

4-(1,3-dioxacyclopent-2-yl)-2-methylquinoline

C

4-(1,3-dioxacyclopent-4-yl)-2-methylquinoline
89587-04-2

4-(1,3-dioxacyclopent-4-yl)-2-methylquinoline

Conditions
ConditionsYield
With Cumene hydroperoxide; sulfuric acid; iron(II) sulfate at 5 - 10℃; for 0.5h; pH 8;A n/a
B 78%
C 10.5%
With Cumene hydroperoxide; sulfuric acid; iron(II) sulfate pH 1;A n/a
B 58%
C 31.5%
With Cumene hydroperoxide; sulfuric acid; iron(II) sulfate at 5 - 10℃; for 0.5h; Product distribution; Mechanism; pH 8;
oxirane
75-21-8

oxirane

A

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

B

ethylene glycol
107-21-1

ethylene glycol

Conditions
ConditionsYield
With 1-methyl-pyrrolidin-2-one; N-methylcyclohexylamine; carbon dioxide; hydrogen; tris(triphenylphosphine)ruthenium(II) chloride at 140℃; under 60800 Torr; for 15h;A 7%
B 76%
oxirane
75-21-8

oxirane

carbon dioxide
124-38-9

carbon dioxide

A

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

B

ethanol
64-17-5

ethanol

C

ethylene glycol
107-21-1

ethylene glycol

Conditions
ConditionsYield
With 1-Methylpyrrolidine; 1-methyl-pyrrolidin-2-one; hydrogen; tris(triphenylphosphine)ruthenium(II) chloride at 140℃; under 60800 Torr; for 15h; Product distribution; Kinetics; Mechanism; var. of catalyst, base, without base;A 5%
B 3%
C 75%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

A

[1,3]-dioxolan-2-one
96-49-1

[1,3]-dioxolan-2-one

B

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

Conditions
ConditionsYield
With oxygen; CoCl2 In 1,2-dimethoxyethane at 60℃; for 24h;A 10%
B 61%
oxirane
75-21-8

oxirane

carbon dioxide
124-38-9

carbon dioxide

A

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

B

ethylene glycol
107-21-1

ethylene glycol

Conditions
ConditionsYield
With 1-Methylpyrrolidine; 1-methyl-pyrrolidin-2-one; hydrogen; dodecacarbonyl-triangulo-triruthenium at 140℃; under 60800 Torr; for 15h;A 15%
B 60%
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

formaldehyd
50-00-0

formaldehyd

A

2-hydroxymethyl-1,3-dioxolane
5694-68-8

2-hydroxymethyl-1,3-dioxolane

B

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

C

formic acid 3-hydroxypropyl ester
31144-13-5

formic acid 3-hydroxypropyl ester

D

2-(hydroxymethyl)-1,3-dioxane
39239-93-5

2-(hydroxymethyl)-1,3-dioxane

E

ethylene glycol
107-21-1

ethylene glycol

F

Glycolaldehyde
141-46-8

Glycolaldehyde

Conditions
ConditionsYield
With tert-Butyl peroxybenzoate at 100 - 130℃; for 4h; Product distribution; Mechanism; further products (2-hydroxymethoxymethyl-1,3-dioxolane and CH2O homologues) isolated; also reaction with paraformaldehyde, and other initiators investigated;A 15.8 % Chromat.
B 3.2 % Chromat.
C 1.66 % Chromat.
D 5.8 % Chromat.
E 12.1 % Chromat.
F 5.1 % Chromat.
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

A

[1,3]-dioxolan-2-one
96-49-1

[1,3]-dioxolan-2-one

B

formaldehyd
50-00-0

formaldehyd

C

formic acid
64-18-6

formic acid

D

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

E

ethylene glycol
107-21-1

ethylene glycol

Conditions
ConditionsYield
With oxygen at 70℃; for 16.5h; Product distribution; Mechanism; other substituted 1,3-dioxolanes; rate of consumption of oxygen, relative rate of formation of glycol;
1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

A

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

B

formic acid ethyl ester
109-94-4

formic acid ethyl ester

Conditions
ConditionsYield
With Cumene hydroperoxide at 130℃;
With Cumene hydroperoxide at 90℃;
dimethylsulfide
75-18-3

dimethylsulfide

1,3-dioxolane hydrotrioxide
101325-78-4

1,3-dioxolane hydrotrioxide

A

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

B

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

Conditions
ConditionsYield
1.) -60 to -50 deg C, 15 min, 2.) -30 deg C, 5-6 h;
2-hydroxy-1,3-dioxolane
4401-60-9

2-hydroxy-1,3-dioxolane

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

Conditions
ConditionsYield
In water at 5 - 10℃; pH < 7; Yield given;
carbon monoxide
201230-82-2

carbon monoxide

A

propan-1-ol
71-23-8

propan-1-ol

B

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

C

ethanol
64-17-5

ethanol

D

ethylene glycol
107-21-1

ethylene glycol

Conditions
ConditionsYield
With 2-hydroxypyridin; hydrogen; acetylacetonatodicarbonylrhodium(l) In various solvent(s) at 230℃; under 1499480 Torr; for 4.5h; Further byproducts given. Title compound not separated from byproducts;A 121 mmol
B 118 mmol
C 191 mmol
D 1000 mmol
1,3-dioxolane hydrotrioxide
101325-78-4

1,3-dioxolane hydrotrioxide

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

Conditions
ConditionsYield
at -30℃;
at -30℃; Rate constant;
1,3-dioxolane hydrotrioxide
101325-78-4

1,3-dioxolane hydrotrioxide

triphenylphosphine
603-35-0

triphenylphosphine

A

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

B

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

Conditions
ConditionsYield
In diethyl ether 1.) -60 to -50 deg C, 15 min, 2.) -30 deg C, 5-6 h;
(1,3-dioxolan-2-yl)-ethoxy-1,3-dioxolan-2-yl peroxide
114915-54-7

(1,3-dioxolan-2-yl)-ethoxy-1,3-dioxolan-2-yl peroxide

A

[1,3]-dioxolan-2-one
96-49-1

[1,3]-dioxolan-2-one

B

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

C

ethanol
64-17-5

ethanol

D

ethyl (2-hydroxyethyl) carbonate
35466-85-4

ethyl (2-hydroxyethyl) carbonate

E

formic acid ethyl ester
109-94-4

formic acid ethyl ester

Conditions
ConditionsYield
at 120℃; Kinetics; Thermodynamic data; activation energy measured;
diethylene glycol
111-46-6

diethylene glycol

A

glycolic Acid
79-14-1

glycolic Acid

B

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

C

2-(2-hydroxyethoxy)acetaldehyde
17976-70-4

2-(2-hydroxyethoxy)acetaldehyde

D

ethylene glycol
107-21-1

ethylene glycol

E

Glycolaldehyde
141-46-8

Glycolaldehyde

F

diethylene glycol monoformate

diethylene glycol monoformate

Conditions
ConditionsYield
With air at 120℃; Rate constant; Product distribution; Mechanism; further temperatures;
1,4-dioxane
123-91-1

1,4-dioxane

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

Conditions
ConditionsYield
With hydrogenchloride; sodium hypochlorite
diethylene glycol
111-46-6

diethylene glycol

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

Conditions
ConditionsYield
With hydrogenchloride; sodium hypochlorite
C11H11N2O4

C11H11N2O4

A

formaldehyd
50-00-0

formaldehyd

B

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

C

ethylene glycol diformate
629-15-2

ethylene glycol diformate

D

4-cyanonitrosobenzene
31125-07-2

4-cyanonitrosobenzene

E

1,4-dioxane-2-ol
22347-47-3

1,4-dioxane-2-ol

F

p-dioxanone
3041-16-5

p-dioxanone

Conditions
ConditionsYield
With dinitrogen monoxide In water Mechanism; Product distribution; Rate constant; Ambient temperature; Irradiation; other ethers;
2-(4-methoxybenzyl)-1,3-dioxolane
91970-78-4

2-(4-methoxybenzyl)-1,3-dioxolane

A

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

B

4-methoxybenzyl nitrate
79929-17-2

4-methoxybenzyl nitrate

C

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

D

2-[(4-Methoxy-phenyl)-nitrooxy-methyl]-[1,3]dioxolane

2-[(4-Methoxy-phenyl)-nitrooxy-methyl]-[1,3]dioxolane

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate; tetrabutylammonium nitrate In acetonitrile at 5℃; for 0.333333h; Irradiation;A 20 % Spectr.
B 18 % Spectr.
C 5 % Spectr.
D 30 % Spectr.
formic acid
64-18-6

formic acid

ethylene glycol
107-21-1

ethylene glycol

A

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

B

ethylene glycol diformate
629-15-2

ethylene glycol diformate

Conditions
ConditionsYield
With acid at 20℃; Esterification;
ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

A

ethylene glycol diformate
629-15-2

ethylene glycol diformate

B

ethylene glycol
107-21-1

ethylene glycol

Conditions
ConditionsYield
With 1-Methylpyrrolidine; ruthenium(II) bis(triphenylphosphine) dichloride at 140℃; for 15h;A 12%
B 12%
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