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Basic Information
CAS No.: 75-88-7
Name: 2-Chloro-1,1,1-trifluoroethane
Article Data: 68
Molecular Structure:
Molecular Structure of 75-88-7 (2-Chloro-1,1,1-trifluoroethane)
Formula: C2H2 Cl F3
Molecular Weight: 118.486
Synonyms: (Chloromethyl)trifluoromethane;1,1,1-Trifluoro-2-chloroethane; 1,1,1-Trifluorochloroethane;1,1,1-Trifluoroethyl chloride; 1-Chloro-2,2,2-trifluoroethane;2,2,2-Trifluoro-1-chloroethane; 2,2,2-Trifluorochloroethane;2,2,2-Trifluoroethyl chloride; 2-Chloro-1,1,1-trifluoroethane; F 133a; FC 133a;Forane 133a; Freon 133a; Genetron 133a; HCFC 133a; R 133a
Density: 1.389
Melting Point: -105°C
Boiling Point: 7°C
Hazard Symbols: Xi
Risk Codes: R59
Safety: A poison by inhalation. Experimental reproductive effects. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits toxic fumes of F−.
PSA: 0.00000
LogP: 1.78750
Related products
Synthetic route
79-01-6

Trichloroethylene

75-88-7

1,1,1-trifluoro-2-chloroethane

Conditions
ConditionsYield
With hydrogen fluoride; antimony pentafluoride at 100℃; for 1h; Temperature; Autoclave;97%
With hydrogen fluoride; tantalum pentafluoride at 0 - 140℃; under 25858.1 Torr; for 10.5h; Product distribution / selectivity; Neat (no solvent);90%
With hydrogen fluoride; tantalum pentafluoride at 100 - 140℃; under 25858.1 Torr; for 6h;80%
79-34-5

1,1,2,2-tetrachloroethane

75-88-7

1,1,1-trifluoro-2-chloroethane

Conditions
ConditionsYield
With hydrogen fluoride; antimonypentachloride at 80 - 90℃; Autoclave;92.3%
With hydrogen fluoride; antimonypentachloride; chlorine at 120℃;
1649-08-7

1,2-dichloro-1,1-difluoroethane

75-88-7

1,1,1-trifluoro-2-chloroethane

Conditions
ConditionsYield
With 1,1,2-trichloro-1-fluoroethane; hydrogen fluoride; tantalum pentachloride at 0 - 140℃; for 2h; Product distribution / selectivity; Neat (no solvent);87.5%
With hydrogen fluoride; tantalum pentachloride at 0 - 140℃; for 2.5h; Product distribution / selectivity; Neat (no solvent);22%
With antimony dichloride trifluoride; hydrogen fluoride at 144℃; under 33097.9 Torr;
75-89-8

2,2,2-trifluoroethanol

421-83-0

trifluoromethane sulfonyl chloride

A

75-88-7

1,1,1-trifluoro-2-chloroethane

B

333-36-8

1,1,1-trifluoro-2-(2,2,2-trifluoroethoxy)ethane

C

6226-25-1

2,2,2-trifluoroethyl trifluoromethanesulphonate

Conditions
ConditionsYield
With potassium carbonate; tetra-n-propylammonium bromide In water at 10.2 - 23.3℃; for 4 - 7h; Product distribution / selectivity;A 0.2 %Chromat.
B 0.13 - 0.28 %Chromat.
C 82%
...Expand
354-58-5

1,1,1-Trichloro-2,2,2-trifluoroethane

75-88-7

1,1,1-trifluoro-2-chloroethane

Conditions
ConditionsYield
With ammonium persulfate; ammonium formate In N,N-dimethyl-formamide at 30 - 40℃;77%
811-95-0

1,1,2-trichloro-1-fluoroethane

A

75-88-7

1,1,1-trifluoro-2-chloroethane

B

1649-08-7

1,2-dichloro-1,1-difluoroethane

Conditions
ConditionsYield
With hydrogen fluoride; tantalum pentachloride at 110℃; for 1.5h;A 22%
B 74%
306-83-2

1,1,1-trifluoro-2,2-dichloroethane

A

75-88-7

1,1,1-trifluoro-2-chloroethane

B

359-10-4

1-Chloro-2,2-difluoroethene

Conditions
ConditionsYield
With water; zinc unter Zusatz eines Netzmittels;
359-10-4

1-Chloro-2,2-difluoroethene

75-88-7

1,1,1-trifluoro-2-chloroethane

Conditions
ConditionsYield
With aluminum(III) fluoride; hydrogen fluoride at 300℃;
With hydrogen fluoride; boron trifluoride at 25℃;
79-01-6

Trichloroethylene

A

75-88-7

1,1,1-trifluoro-2-chloroethane

B

354-15-4

1,2,2-trichloro-1,2-difluoroethane

C

76-13-1

1,1,2-Trichloro-1,2,2-trifluoroethane

D

76-12-0

CFC-112a

Conditions
ConditionsYield
With cobalt (III) fluoride at 120℃; Further byproducts given;
...Expand
79-11-8

chloroacetic acid

A

75-88-7

1,1,1-trifluoro-2-chloroethane

B

38217-12-8

bis-(2-chloro-1,1-difluoro-ethyl) ether

Conditions
ConditionsYield
With sulfur tetrafluoride at 65℃; for 3h;
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Chemistry

Molecular Structure of 1,1,1-Trifluoro-2-chloroethane (CAS NO.75-88-7):

EINECS: 200-912-0
IUPAC Name: 2-Chloro-1,1,1-trifluoroethane 
Molecular Formula: C2H2ClF3
Molecular Weight: 118.485490 g/mol
XLogP3-AA: 1.9
H-Bond Donor: 0
H-Bond Acceptor: 3
Canonical SMILES: C(C(F)(F)F)Cl
InChI: InChI=1S/C2H2ClF3/c3-1-2(4,5)6/h1H2
InChIKey: CYXIKYKBLDZZNW-UHFFFAOYSA-N
Index of Refraction: 1.298
Molar Refractivity: 16.62 cm3
Molar Volume: 89.3 cm3
Surface Tension: 14.3 dyne/cm
Density: 1.326 g/cm3
Enthalpy of Vaporization: 24.48 kJ/mol
Boiling Point: 6.9 °C at 760 mmHg
Vapour Pressure: 1430 mmHg at 25 °C
Melting Point: -105 °C
Water Solubility: 365.4 mg/L at 25 °C
BRN: 1733200

Toxicity Data With Reference

1.    

orl-rat TDLo:78 g/kg/1Y-I:CAR,REP

     TXAPA9    Toxicology and Applied Pharmacology. 72 (1984),15.
2.    

ihl-mus LC50:15 pph/1H

     BJANAD    British Journal of Anesthesia. 37 (1965),716.

Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Limited Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 41 ,1986,p. 253.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory.

Safety Profile

Safety Information of 1,1,1-Trifluoro-2-chloroethane (CAS NO.75-88-7):
Hazard Codes: Xi Irritant
Hazard Note: Irritant
Risk Statements: 59
R59:Dangerous to the ozone layer
Safety Statements: 9-23-59
S9:Keep container in a well-ventilated place
S23:Do not breathe vapour
S59:Refer to manufacturer / supplier for information on recovery / recycling
RIDADR: 1983
TSCA: T
HazardClass: 2.2
A poison by inhalation. Experimental reproductive effects. Questionable carcinogen with experimental carcinogenic data. When heated to decomposition it emits toxic fumes of F−.

Specification

  1,1,1-Trifluoro-2-chloroethane with CAS Registry Number of 75-88-7 is a colorless, odorless gas. It is also known as 1,1,1-Trifluoroethyl chloride ; 1-Chloro-2,2,2-trifluoroethane ; 2,2,2-Trifluorochloroethane ; 2-Chloro-1,1,1-trifluoroethane ; 4-01-00-00128 (Beilstein Handbook Reference) ; CCRIS 154 ; CFC 133a ; FC 133a ; Forane 133a ; Freon 133a ; Genetron 133a ; HCFC 133a ; HCFC-133a ; HSDB 6949 ; R 133a ; Chloro-1,1,1-trifluoroethane ; Ethane, 2-chloro-1,1,1-trifluoro- ; 1-Chloro-2,2,2-trifluoroethane or Refrigerant gas R 133a [UN1983] [Non-flammable gas] ; Chlorotrifluoroethane ; HCFC-133a ; UN1983 . It can react violently with strong reducing agents and undergo oxidation with strong oxidizing agents and under extremes of temperature.