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79-34-5

Basic Information
CAS No.: 79-34-5
Name: 1,1,2,2-Tetrach loroethane
Article Data: 110
Molecular Structure:
Molecular Structure of 79-34-5 (1,1,2,2-Tetrach loroethane)
Formula: C2H2Cl4
Molecular Weight: 167.85
Synonyms: 1,1,2,2-TCE;1,1,2,2-Tetrachlorethane;Acetylene tetrachloride;Bonoform;Cellon;F 130;F 130 (halocarbon);NSC 60912;Tetrachloroethane;s-Tetrachloroethane;sym-Tetrachloroethane;1,1,2,2- Tetrachloroethane;
EINECS: 201-197-8
Density: 1.556 g/cm3
Melting Point: - 43 °C
Boiling Point: 142 °C at 760 mmHg
Flash Point: 42.6 °C
Solubility: 0.3 g/100 mL (25 ºC)
Appearance: colourless to light yellow liquid
Hazard Symbols: VeryT+,DangerousN
Risk Codes: 26/27-51/53-59-39/23/24/25-23/24/25-11
Safety: 38-45-61-36/37
Transport Information: UN 1702 6.1/PG 2
PSA: 0.00000
LogP: 2.59380
Synthetic route
156-60-5

trans-1,2-dichloroethylene

79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
With 2,3-dimethylbutane In benzene at 20℃; Irradiation;94%
With chlorine at 80 - 95℃; unter Ausschluss von Sauerstoff;
76107-35-2

C11H16Cl10NO3P

A

76078-37-0

bis(2,2,2-trichloroethyl) piperidinophosphonate

B

79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
at 180℃; under 0.03 Torr;A 89%
B 93%
76078-34-7

C10H14Cl10NO4P

A

76078-38-1

bis(2,2,2-trichloroethyl) morpholinophosphonate

B

79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
at 180℃; under 0.03 Torr;A 87%
B 93%
473-29-0

N,N-Dichlorobenzenesulfonamide

540-59-0

1,2-Dichloroethylene

A

98-10-2

benzenesulfonamide

B

113791-97-2

N-(2,2-dichloroethylidene)benzenesulfonamide

C

79054-58-3

N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide

D

79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
at 47 - 55℃; for 10h; Irradiation; Further byproducts given. Yields of byproduct given;A n/a
B n/a
C 80.7%
D n/a
18142-52-4

(2-Chlor-vinyl)-dimethyl-chlorsilan

A

540-59-0

1,2-Dichloroethylene

B

75-78-5

dimethylsilicon dichloride

C

176102-95-7

Chloro-dimethyl-(1,2,2-trichloro-ethyl)-silane

D

79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
With chlorine for 5h; Further byproducts given;A 5%
B 6%
C 70%
D 2%
473-29-0

N,N-Dichlorobenzenesulfonamide

540-59-0

1,2-Dichloroethylene

A

127-18-4

1,1,2,2-tetrachloroethylene

B

79-01-6

Trichloroethylene

C

55596-11-7

N-(2,2,2-trichloroethylidene)benzenesulfonamide

D

113791-97-2

N-(2,2-dichloroethylidene)benzenesulfonamide

E

79054-58-3

N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide

F

79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator;A n/a
B n/a
C n/a
D n/a
E 54.1%
F n/a
540-59-0

1,2-Dichloroethylene

17260-65-0

N,N-dichloro-4-chlorobenzenesulfonamide

A

113791-98-3

N-(2,2-dichloroethylidene)-p-chlorobenzenesulfonamide

B

79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
for 4h; Irradiation;A 50%
B n/a
473-29-0

N,N-Dichlorobenzenesulfonamide

540-59-0

1,2-Dichloroethylene

A

113791-97-2

N-(2,2-dichloroethylidene)benzenesulfonamide

B

79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
for 4h; Irradiation;A 45%
B n/a
35802-68-7

β-chlorovinyltrimethylsilane

A

75-77-4

chloro-trimethyl-silane

B

540-59-0

1,2-Dichloroethylene

C

Trimethyl-(1,2,2-trichloro-ethyl)-silane

D

79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
With chlorine for 5h; Further byproducts given;A 10%
B 7%
C 45%
D 3%
35802-68-7

β-chlorovinyltrimethylsilane

A

540-59-0

1,2-Dichloroethylene

B

18163-49-0

Trimethyl-(pentachlorethyl)-silan

C

Trimethyl-(1,2,2-trichloro-ethyl)-silane

D

79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
With chlorine for 5h; Further byproducts given;A 7%
B 14%
C 45%
D 3%
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  • 1,1,2,2-Tetrachloroethane

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  • 1,1,2,2-Tetrachloroethane CAS 79-34-5 good factory price

  • Casno:

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  • 1,1,2,2-Tetrachloroethane,

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  • 1,1,2,2-Tetrachloroethane

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    79-34-5

    1,1,2,2-Tetrachloroethane

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    Tetrachloroethane CAS No. : 79-34-5Molecular formula: C2H2Cl4Structural formula: Molecular weight: 167.85Appearance: Colorless liquidAssay: 99% Pa…

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  • 1,1,2,2-Tetrachloroethane

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    1,1,2,2-Tetrachloroethane

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  • 1,1,2,2-Tetrachloroethane

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    79-34-5

    1,1,2,2-Tetrachloroethane

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  • 1,1,2,2-Tetrachloroethane

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    1,1,2,2-Tetrachloroethane

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  • 1,1,2,2-Tetrachloroethane

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    1,1,2,2-Tetrachloroethane

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  • Tetrachloroethane

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    79-34-5

    Tetrachloroethane

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    please contact us to confirm the required quantity and quote, we will provide you with COA,NMR,HPLC and other relevant informationAppearance:Colorless liquid Storage:Store in a cool place. Keep container tightly closed in a dry and well-ventilated pl

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  • 1,1,2,2-tetrachloroethane

  • Casno:

    79-34-5

    1,1,2,2-tetrachloroethane

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    ≥99%, stockAppearance:colourless to light yellow liquid with a chloroform-like Storage:Refrigerator Package:1kg/bottle;50kg/100kg/drum Application:OLED Transportation:by air, by sea

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  • 1,1,2,2-Tetrachloroethane

  • Casno:

    79-34-5

    1,1,2,2-Tetrachloroethane

    Min.Order: 1 Gram

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Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 354.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Limited Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 20 ,1979,p. 477.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; NCI Carcinogenesis Bioassay (gavage); Clear Evidence: mouse NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-27 ,1978. ; Some Evidence: rat NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-27 ,1978. . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Community Right-To-Know List.

Standards and Recommendations

OSHA PEL: TWA 1 ppm (skin)
ACGIH TLV: TWA 1 ppm (skin); Animal Carcinogen
DFG MAK: 1 ppm (7 mg/m3); Confirmed Animal Carcinogen with Unknown Relevance to Humans
NIOSH REL: (1,1,2,2-Tetrachlorethane) Reduce to lowest level

Analytical Methods

For occupational chemical analysis use NIOSH: 1,1,2,2-Tetrachloroethane, 1019.

Specification

The 1,1,2,2-Tetrachloroethane , with the CAS register number 79-34-5, could also be called as (CHCl2)2;1,1,2,2,-tetrachlor-ethane ; 1,1,2,2-Czterochloroetan ; 1,1,2,2-czterochloroetan(polish) ; 1,1,2,2-tce ; 1,1,2,2-Tetrachloorethaan ; 1,1,2,2-Tetrachloraethan ; 1,1,2,2-Tetrachlorethan .

The physical properties of this chemcial are as followings: (1)ACD/LogP:  2.17 ; (2)ACD/LogD (pH 5.5):  2.17  ; (3)ACD/LogD (pH 7.4):  2.17  ; (4)ACD/BCF (pH 5.5):  26.37  ; (5)ACD/BCF (pH 7.4):  26.37  ; (6)ACD/KOC (pH 5.5):  362.07  ; (7)ACD/KOC (pH 7.4):  362.07  ; (8)#Freely Rotating Bonds:  1; (9)Index of Refraction:  1.479  ; (10)Molar Refractivity:  30.62 cm ; (11)Molar Volume:  107.8 cm ; (12)Polarizability:  12.14 ×10-24 cm ; (13)Surface Tension:  33.9 dyne/cm  ; (14)Density:  1.556 g/cm3  ; (15)Flash Point:  42.6 °C  ; (16)Enthalpy of Vaporization:  37.64 kJ/mol  ; (17)Boiling Point:  142 °C at 760 mmHg  ; (18)Vapour Pressure:  7.14 mmHg at 25°C.

This is a kind of colorless liquid and is complete soluble in Methanol, ethanol, ethyl ether, chloroform, benzene, carbon tetrachloride, carbon bisulfide, petroleum ether, DMF and other oils but insoluble in water. And it could volatilize with steam. Besides, it is incompatible with strong oxidizing agents, strong bases and can react violently with sodium, potassium, nitrates, 2,4-dinitrophenyl disulphide. As for its usage, it could be used as solvent and analytical reagent and it could also be as the metal detergent, pesticide, and other phytocide.

As for its product categories, there are vairous, including Intermediates of Dyes and Pigments; refrigerants; Organics; Analytical Chemistry; Standard Solution of Volatile Organic Compounds for Water & Soil Analysis; Standard Solutions (VOC); Alpha Sort; Chemical Class; ChloroPesticides; FumigantsVolatiles/ Semivolatiles; Halogenated; Insecticides; TA - TE; T-ZAlphabetic.

Being a kind of very toxic chemical, it may at very low levels cause damage to health and it is dangerous when by inhalation or in contact with skin, and it has the danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. Besides, it is dangerous for the environment, for it may present an immediate or delayed danger to one or more components of the environment and it is toxic to the aquatic organisms and may cause long-term adverse effects in the aquatic environment. Besides, it is dangerous for the ozone layer. Except all these, it is a kind of highly flammable chemical, as it may catch fire in contact with air, only needing brief contact with an ignition source and it has a very low flash point or evolve highly flammable gases in contact with water.
 
Because of these dangerous possibilities, you should be very cautious while dealing with it. Wear suitable protective clothing and gloves. If in case of insufficient ventilation, wear suitable respiratory equipment and if in case of accident or if you feel unwell seek medical advice immediately (show the label where possible). Besides, Avoid releasing to the environment and refer to special instructions/safety data sheet. Yuo could obtain more safety information from WGK Germany  3. When store it, it should be kept in the ventilating dry and cool storeroom, and away from those oxygenant and other food additives.

When it comes to its preparation products, there are including chloroacetic acid, trichloroethylene, thiophosgene, hexachloroethane, 4-vinylbenzyl chloride, decabromodiphenyl oxide, pentachloroethane. And its raw materials are including ferric chloride, antimony(v) chloride.

Additionally, you could convert the following data information into the molecular structure:
SMILES:ClC(Cl)C(Cl)Cl
InChI:InChI=1/C2H2Cl4/c3-1(4)2(5)6/h1-2H
InChIKey:QPFMBZIOSGYJDE-UHFFFAOYAH

Below are the toxicity information of this chemical:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LCLo inhalation 19gm/m3/45M (19000mg/m3) SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE

BEHAVIORAL: GENERAL ANESTHETIC

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
Archiv fuer Hygiene und Bakteriologie. Vol. 116, Pg. 131, 1936.
dog LDLo intravenous 50mg/kg (50mg/kg)   Quarterly Journal of Pharmacy & Pharmacology. Vol. 7, Pg. 205, 1934.
dog LDLo oral 300mg/kg (300mg/kg) LIVER: "HEPATITIS (HEPATOCELLULAR NECROSIS), ZONAL"

BEHAVIORAL: SLEEP

LIVER: FATTY LIVER DEGERATION
American Journal of Hygiene. Vol. 16, Pg. 325, 1932.
guinea pig LDLo intraperitoneal 500mg/kg (500mg/kg) LIVER: FATTY LIVER DEGERATION American Industrial Hygiene Association Journal. Vol. 35, Pg. 21, 1974.
 
human TCLo inhalation 1000mg/m3/30M (1000mg/m3) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS"
Archiv fuer Hygiene und Bakteriologie. Vol. 116, Pg. 131, 1936.
human TDLo oral 30mg/kg (30mg/kg) BEHAVIORAL: GENERAL ANESTHETIC Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 1110, 1966.
mouse LC50 inhalation 4500mg/m3/2H (4500mg/m3)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 107, 1982.
mouse LD50 intraperitoneal 821mg/kg (821mg/kg)   Sangyo Igaku. Japanese Journal of Industrial Health. Vol. 8, Pg. 371, 1966.
mouse LD50 subcutaneous 1108mg/kg (1108mg/kg) BEHAVIORAL: SLEEP

BEHAVIORAL: ATAXIA
Journal of Pharmacology and Experimental Therapeutics. Vol. 123, Pg. 224, 1958.
 
rabbit LDLo subcutaneous 500mg/kg (500mg/kg)   Quarterly Journal of Pharmacy & Pharmacology. Vol. 7, Pg. 205, 1934.
rat LCLo inhalation 1000ppm/4H (1000ppm)   Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 343, 1949.
 
rat LD50 oral 200mg/kg (200mg/kg)   Industrial Health. Vol. 32, Pg. 145, 1994.