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CAS No.: | 7791-07-3 |
---|---|
Name: | SODIUM PERCHLORATE MONOHYDRATE |
Article Data: | 8 |
Molecular Structure: | |
Formula: | NaClO4.H2O |
Molecular Weight: | 140.456 |
Synonyms: | Sodiumperchlorate (NaClO4) monohydrate;Sodium perchlorate monohydrate; |
EINECS: | 231-511-9 |
Density: | 2,02 g/cm3 |
Melting Point: | 130 °C |
Solubility: | Soluble in water. |
Appearance: | white adhering crystals |
Hazard Symbols: | O,Xi,Xn |
Risk Codes: | 9-22-36/37/38-8 |
Safety: | 17-26-27-36/37/39-22-13 |
Transport Information: | UN 1502 |
PSA: | 83.50000 |
LogP: | 0.15000 |
perchloric acid
water
sodium hydrogencarbonate
sodium perchlorate monohydrate
Conditions | Yield |
---|---|
In perchloric acid by a react. of HClO4 with NaHCO3; evapn. to incipient crystn.; |
sodium perchlorate monohydrate
Conditions | Yield |
---|---|
In water crystn. below 52.75°C; | |
In water crystn. below 52.75°C; |
Conditions | Yield |
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In not given neutralization, concg. to satn. concn., hot filtration, cooling the filtrate at stirring; recrystn. from water twice; | |
In perchloric acid dissoln. of carbonate in HClO4 (72 %), repeated recrystn. (H2O); | |
In not given neutralization, concg. to satn. concn., hot filtration, cooling the filtrate at stirring; recrystn. from water twice, washing by dry ether, drying in vac. for 10 h at ambient temp.; | |
In not given neutralization, concg. to satn. concn., hot filtration, cooling the filtrate at stirring; recrystn. from water twice; | |
In not given neutralization, concg. to satn. concn., hot filtration, cooling the filtrate at stirring; recrystn. from water twice, washing by dry ether, drying in vac. for 10 h at ambient temp.; |
Conditions | Yield |
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With aq. HClO4 dry box.; |
sodium perchlorate monohydrate
{(NH3)5IrOCHN(CH3)2}(3+)*3ClO4(1-)={(NH3)5IrOCHN(CH3)2}(ClO4)3
{(NH3)5IrOOCH}(2+)*2ClO4(1-)={(NH3)5IrOOCH}(ClO4)2
Conditions | Yield |
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With sodium hydroxide In water Kinetics; stirred for 10 min at ambient temp., NaClO4*H2O was added in H2O; cooled, filtered, elem. anal.; | 100% |
sodium perchlorate monohydrate
[Pd(η3-1,1,2-Me3C3H2)(2-isopropylthiomethylpyridine)](ClO4)
Conditions | Yield |
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In methanol; dichloromethane stirred at room temp. under N2 for 1 h; evapd. in vacuo, residue dissolved in CH2Cl2, treated with activated charcoal, filtered through celite, filtrate was concd., treated with Et2O, ppt. was collected; elem. anal.; | 99% |
Conditions | Yield |
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In water at 20℃; for 2h; Sealed tube; | 99% |
sodium perchlorate monohydrate
Conditions | Yield |
---|---|
In not given to Pt-salt NaClO4*H2O added; filtered, washed (H2O), dried in vac., elem. anal.; | 98% |
Conditions | Yield |
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In acetonitrile equimol., a soln. of salt added to a soln. of S compd., stirred overnight at room temp.; solvent evapd., residue washed (cold diethyl ether), dried (vac.); elem.anal.; | 98% |
Conditions | Yield |
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Stage #1: C21H24N3Pd(1+)*ClO4(1-); triphenylphosphine In dichloromethane for 0.166667h; Inert atmosphere; Schlenk technique; Stage #2: sodium perchlorate monohydrate In dichloromethane at 20℃; for 1h; Inert atmosphere; Schlenk technique; | 98% |
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DOT Classification: 5.1; Label: Oxidizer
The Sodium perchlorate monohydrate, also known as CCRIS 8893, is an inorganic substance with the formula NaClO4•H2O. It belongs to the product categories of Oxidation; Perchlorates Metal and Ceramic Science; Salts; Sodium Salts; Synthetic Reagents; ACS Grade Synthetic Reagents; Essential Chemicals; Perchlorates; Routine Reagents; HPLC; HPLC Buffer; HPLC Buffer - SolidChromatography/CE Reagents; HPLC Buffers; Solid. Its EINECS registry number is 231-511-9. With the CAS registry number 7791-07-3, its IUPAC name is sodium perchlorate hydrate. Sodium perchlorate monohydrate is used for the manufacture of perchlorate and other perchlorate, and also for the gunpowder industry.
Physical properties of Sodium perchlorate monohydrate: (1)H-Bond Donor: 1; (2)H-Bond Acceptor: 5; (3)Rotatable Bond Count: 0; (4)Exact Mass: 139.948846; (5)MonoIsotopic Mass: 139.948846; (6)Topological Polar Surface Area: 75.3; (7)Heavy Atom Count: 7; (8)Formal Charge: 0; (9)Complexity: 118; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 3.
Preparation of Sodium perchlorate monohydrate: this chemical can be prepared by Na2CO3 and HClO4. Then the anhydrous sodium perchlorate was crystallized out. It can gradually absorb moisture in the air. At last, you will get Sodium perchlorate monohydrate.
When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.
You can still convert the following datas into molecular structure:
(1)Canonical SMILES: O.[O-]Cl(=O)(=O)=O.[Na+]
(2)InChI: InChI=1S/ClHO4.Na.H2O/c2-1(3,4)5;;/h(H,2,3,4,5);;1H2/q;+1;/p-1
(3)InChIKey: IXGNPUSUVRTQGW-UHFFFAOYSA-M
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intraperitoneal | 1150mg/kg (1150mg/kg) | Journal of Agricultural and Food Chemistry. Vol. 14, Pg. 512, 1966. |