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95-80-7

Basic Information
CAS No.: 95-80-7
Name: 2,4-Diaminotoluene
Article Data: 133
Molecular Structure:
Molecular Structure of 95-80-7 (2,4-Diaminotoluene)
Formula: C7H10N2
Molecular Weight: 122.17
Synonyms: Toluene-2,4-diamine(7CI,8CI);1,3-Diamino-4-methylbenzene;2,4-Diamino-1-methylbenzene;2,4-Tolylenediamine;3-Amino-4-methylaniline;4-Methyl-1,3-benzenediamine;4-Methyl-1,3-phenylenediamine;4-Methyl-m-phenylenediamine;Brown for Fur T;C.I. Oxidation Base 35;EucanineGB;Fouramine J;Fourrine 94;Fourrine M;Nako TMT;Pelagol Grey J;Pelagol J;Pontamine Developer TN;Renal MD;TDA;TDA (diamine);Zoba GKE;m-Toluenediamine;m-Tolylenediamine;Toluene-2,4-diamine;
EINECS: 202-453-1
Density: 1.107 g/cm3
Melting Point: 97-99 °C(lit.)
Boiling Point: 292 °C at 760 mmHg
Flash Point: 149.5 °C
Solubility: 50 g/l (25 °C) in water
Appearance: brown crystalline powder, crystals or flakes
Hazard Symbols: ToxicT, DangerousN
Risk Codes: 45-21-25-36-43-51/53
Safety: 53-45-61
Transport Information: UN 1709 6.1/PG 3
PSA: 52.04000
LogP: 2.32180
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Chemistry

Molecular structure of Toluene-2,4-diamine (CAS NO.95-80-7) is:

Product Name: Toluene-2,4-diamine
CAS Registry Number: 95-80-7
IUPAC Name: 4-methylbenzene-1,3-diamine
Molecular Weight: 122.1677 [g/mol]
Molecular Formula: C7H10N2
XLogP3: 0.1
H-Bond Donor: 2
H-Bond Acceptor: 2 
EINECS: 202-453-1
Melting Point: 97-99 °C(lit.)
Water Solubility: 50 g/l (25 °C) 
Surface Tension: 52.3 dyne/cm
Density: 1.107 g/cm3
Flash Point: 149.5 °C
Enthalpy of Vaporization: 53.15 kJ/mol
Boiling Point: 292 °C at 760 mmHg
Vapour Pressure: 0.00188 mmHg at 25°C
Product Categories: Intermediates of Dyes and Pigments;Aromatic Hydrocarbons (substituted) & Derivatives

Uses

 Toluene-2,4-diamine (CAS NO.95-80-7) is used in producing TDI, vulcanization dye, alkaline dyes and dispersal dyes, pharmaceutical intermediates and other organic synthesis intermediates.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LDLo subcutaneous 200mg/kg (200mg/kg)   U.S. Public Health Service, Public Health Bulletin. Vol. 271, Pg. 56, 1941.
mouse LD50 intraperitoneal 480mg/kg (480mg/kg)   Journal of Environmental Pathology and Toxicology. Vol. 3(1-2), Pg. 149, 1979.
rabbit LDLo subcutaneous 400mg/kg (400mg/kg) BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Zeitschrift fuer Experimentelle Pathologie und Therapie. Vol. 17, Pg. 59, 1915.
rat LD50 intraperitoneal 325mg/kg (325mg/kg)   Journal of Environmental Pathology and Toxicology. Vol. 3(1-2), Pg. 149, 1979.
rat LDLo subcutaneous 350mg/kg (350mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

CARDIAC: PULSE RATE

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION
Zeitschrift fuer Experimentelle Pathologie und Therapie. Vol. 17, Pg. 59, 1915.

Safety Profile

Hazard Codes: ToxicT, DangerousN
Risk Statements: 45-21-25-36-43-51/53 
R45:May cause cancer. 
R21:Harmful in contact with skin. 
R25 :Toxic if swallowed. 
R36:Irritating to eyes. 
R43:May cause sensitization by skin contact. 
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 53-45-61
RIDADR: UN 1709 6.1/PG 3
WGK Germany: 3
RTECS: XS9625000
F: 8-10-23
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29215119

Specification

 Toluene-2,4-diamine , its cas register number is 95-80-7. It also can be called [4,4'-Bi-3H-pyrazole]-3,3'-dione, 2,2',4,4'-tetrahydro-5,5'-dimethyl-2,2'-diphenyl- ; 2,4-Diaminotoluene ; 2,4-TDA ; 3,3'-Dimethyl-1,1'-diphenyl-4,4'-bi-5-pyrazolone ; 4-Methyl-m-phenylenediamine .It is a brown crystalline powder, crystals or flakes. It soluble in water, alcohol and ether.