10072-09-0

Basic information

• Product Name: ACETIC ACID PYRIDIN-3-YLMETHYL ESTER
• Synonyms: ACETIC ACID PYRIDIN-3-YLMETHYL ESTER;3-(acetoxymethyl)pyridine;pyridin-3-ylmethyl acetate
• CAS NO: 10072-09-0
• Molecular Formula: C₈H₉NO₂
• Molecular Weight: 151.16256
• Mol File: 10072-09-0.mol
• Article Data: 20

Chemical Properties

• Boiling Point: 230°Cat760mmHg
• Flash Point: 92.9°C
• Appearance: /
• Density: 1.115g/cm³
• Vapor Pressure: 0.0675mmHg at 25°C
• Refractive Index: 1.506
• Storage Temp.: 2-8°C
• CAS DataBase Reference: ACETIC ACID PYRIDIN-3-YLMETHYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: ACETIC ACID PYRIDIN-3-YLMETHYL ESTER(10072-09-0)
• EPA Substance Registry System: ACETIC ACID PYRIDIN-3-YLMETHYL ESTER(10072-09-0)

Safety Data

• Hazardous Substances Data: 10072-09-0(Hazardous Substances Data)

Usage

General Description

ACETIC ACID PYRIDIN-3-YLMETHYL ESTER is a chemical compound with the molecular formula C9H9NO2. It is an ester derived from acetic acid and 3-pyridinemethanol. ACETIC ACID PYRIDIN-3-YLMETHYL ESTER is a colorless liquid with a pungent odor and is widely used as a solvent and intermediate in the production of pharmaceuticals and agrochemicals. It is also utilized in the manufacture of dyes and perfumes. ACETIC ACID PYRIDIN-3-YLMETHYL ESTER is known for its irritant properties and should be handled with caution in industrial and laboratory settings.

InChI:InChI=1/C8H9NO2/c1-7(10)11-6-8-3-2-4-9-5-8/h2-5H,6H2,1H3

Upstream product

• 100-55-0 3-hydroxymethylpyridin 
• 127-09-3 sodium acetate 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 2466-76-4 N-Acetylimidazole 
• 1003-73-2 3-picoline-N-oxide 
• 2530-26-9 3-nitropyridine 
• 108-05-4 vinyl acetate 
• 123-54-6 acetylacetone 
• 75-36-5 acetyl chloride 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 59321-67-4 3-((trimethylsilyl)methyl)pyridine 

Downstream Products

• 58418-60-3 3-((benzyloxy)methyl)pyridine 
• 100-55-0 3-hydroxymethylpyridin 
• 114951-34-7 3-Acetoxymethylpyridine-N-oxide 
• 104642-47-9 C₉H₁₂O₃S*C₈H₁₀N₂O₂ 
• 36721-61-6 3-(hydroxymethyl)-1-methylpyridin-2(1H)-one 

Relevant articles and documents

Supramolecular Catalysis of Acyl Transfer within Zinc Porphyrin-Based Metal-Organic Cages

To illustrate the supramolecular catalysis process in molecular containers, two porphyrinatozinc(II)-faced cubic cages with different sizes were synthesized and used to catalyze acyl-transfer reactions between N-acetylimidazole (NAI) and various pyridylcarbinol (PC) regioisomers (2-PC, 3-PC, and 4-PC). A systemic investigation of the supramolecular catalysis occurring within these two hosts was performed, in combination with a host-guest binding study and density functional theory calculations. Compared to the reaction in a bulk solvent, the results that the reaction of 2-PC was found to be highly efficient with high rate enhancements (kcat/kuncat = 283 for Zn-1 and 442 for Zn-2), as well as the different efficiencies of the reactions with various ortho-substituted 2-PC substrates and NAI derivates should be attributed to the cages having preconcentrated and preoriented substrates. The same cage displayed different catalytic activities toward different PC regioisomers, which should be mainly attributed to different binding affinities between the respective reactant and product with the cages. Furthermore, control experiments were carried out to learn the effect of varying reactant concentrations and product inhibition. The results all suggested that, besides the confinement effect caused by the inner microenvironment, substrate transfer, including the encapsulation of the reactant and the release of products, should be considered to be a quite important factor in supramolecular catalysis within a molecular container.

A 3 - pyridine formaldehyde synthetic method

The present invention relates to machine the chemical field, in particular to a 3 - pyridine formaldehyde synthetic method, comprises the following steps: 1, to 3 - methyl pyridine as raw materials, under acidic conditions, through the oxidation reaction

Synthetic method of 3-pyridylaldehyde

The invention relates to the field of organic chemistry, in particular to a synthetic method of 3-pyridylaldehyde. The synthetic method comprises the following steps: 1, taking 3-methyl pyridine as a raw material and obtaining 3-pyridine nitrogen oxide through oxidation reaction under an acidic condition; 2, synthesizing the 3-pyridine nitrogen oxide into acetic acid-3-pyridine methyl ester through acetic anhydride rearrangement; 3, hydrolyzing the acetic acid-3-pyridine methyl ester to obtain 3-pyridine methanol; 4, performing oxidation reaction on the 3-pyridine methanol to obtain 3-pyridylaldehyde. After the synthetic method is adopted, the 3-methyl pyridine is used as the raw material, and the 3-pyridine methanol is obtained through N-oxidation, rearrangement and hydrolyzation and is further oxidized to obtain the 3-pyridylaldehyde. The synthetic method provided by the invention is high in total yield, low in raw material price, short in reaction time, mild in condition, and simple in process operation.