105368-79-4

Upstream product

• 108-24-7 acetic anhydride 
• 105265-85-8 methyl (4S,5S,6R)-4,5,6-tris(benzyloxy)-7-hydroxy-2-(methoxycarbonyl)heptanoate 
• 108713-89-9 (2R,3R,4R)-2,3,4-tris-benzyloxy-5,5-bis-ethylsulfanyl-pentan-1-ol 
• 108-59-8 malonic acid dimethyl ester 
• 94898-44-9 (2R,3S,4S)-1,1-bis(ethylsulfanyl)-5-(trityloxy)pentane-2,3,4-triol 
• 94898-45-0 (2R,3S,4S)-2,3,4-tris(benzyloxy)-1,1-bis(ethylsulfanyl)-5-(trityloxy)pentane 
• 94898-47-2 Toluene-4-sulfonic acid (2S,3S,4R)-2,3,4-tris-benzyloxy-5,5-bis-ethylsulfanyl-pentyl ester 
• 94898-48-3 Toluene-4-sulfonic acid (2S,3S,4R)-2,3,4-tris-benzyloxy-5-oxo-pentyl ester 
• 94898-49-4 2,3,4-tri-O-benzyl-5-deoxy-5-iodo-L-arabinose 
• 94898-46-1 2,3,4-tri-O-benzyl-L-arabinose diethyl dithioacetal 
• 100-39-0 benzyl bromide 
• 43179-48-2 L-arabinose di(ethylthio)acetal 
• 94921-22-9 (3S,4S,5S)-3,4,5-Tris-benzyloxy-2-hydroxy-cyclohexane-1,1-dicarboxylic acid dimethyl ester 
• 105265-83-6 (2R,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentanal 

Downstream Products

• 105368-81-8 (3R,4S,5S)-3,4,5-tris(benzyloxy)-1-cyclohexene-1-methanol 
• 105368-83-0 (1S,2S,3R,4S,5S)-2,3,4,5-tetraacetoxy-1-(acetoxymethyl)cyclohexane, pseudo-β-L-mannopyranose pentaacetate 
• 94898-39-2 (1S,2S,3R,4S,5S)-2-acetoxy-1-(acetoxymethyl)-3,4,5-tris(benzyloxy)cyclohexane 
• 94898-39-2 (1S,2S,3S,4S,5S)-4-acetoxy-5-acetoxymethyl-1,2,3-tribenzyloxycyclohexane 
• 94898-39-2 (1S,2S,3S,4R,5R)-4-acetoxy-5-acetoxymethyl-1,2,3-tribenzyloxycyclohexane 
• 94943-07-4 (1S,2S,3S,4S,5S)-5-(acetoxymethyl)cyclohexane-1,2,3,4-tetrayl tetraacetate 
• 94898-38-1 (3S,4S,5S)-3,4,5-tribenzyloxy-1-hydroxymethyl-1-cyclohexene 
• 81307-66-6 (1S,2S,3S,4S,5S)-pseudo-β-L-altrose 
• 81307-66-6 (1S,2S,3S,4R,5R)-pseudo-α-D-glucose 
• 94943-06-3 (1S,2S,3S,4R,5R)-1,2,3,4-tetraacetoxy-5-acetoxymethylcyclohexane 
• 125258-11-9 DL-(1,2,4/3,5)-1,2,3-tri-O-benzyl-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 94898-37-0 (3S,4S,5S)-3,4,5-Tris-benzyloxy-cyclohex-1-enecarboxylic acid methyl ester 
• 125258-11-9 (1S,2R,3S,4S,6S)-2,3,4-Tris-benzyloxy-6-hydroxymethyl-cyclohexanol 
• 105368-80-7 methyl (3R,4S,5S)-3,4,5-tris(benzyloxy)-1-cyclohexene-1-carboxylate 

Relevant academic research and scientific papers

A Novel Transformation of Four Aldoses to Some Optically Pure Pseudohexopyranoses and a Pseudopentofuranose, Carboxylic Analogues of Hexopyranoses and Pentofuranose. Synthesis of Derivatives of (1S,2S,3R,4S,5S)-, (1S,2S,3R,4R,5S)-, (1R,2R,3R,4R,5S)-, (1S,

Knoevenagel reactions with dimethyl malonate of the suitably protected acylic aldehydes 6, 20, 34, and 46, which were prepared from D-ribose, D-xylose, D-arabinose, and D-erythrose, respectively, proceeded smoothly to provide α,β-unsaturated diesters 7, 2

A NEW TRANSFORMATION OF ALDOSE DERIVED SYNTHONS TO PSEUDO-HEXOPYRANOSE OR PSEUDO-PENTOFURANOSE DERIVATIVES

The D-ribose or D-erythrose derived acyclic synthon, which possesses a 2-malonyl carbon chain at C-1 position, was cyclized stereoselectively to a six- or five-membered carbocycle.Those carbocycles were converted into pseudo-β-L-mannopyranose derivatives

SYNTHESIS OF OPTICALLY ACTIVE PSEUDO-α-D-GLUCOSE AND PSEUDO-β-L-ALTROSE

Optically active two pseudo-sugars, pseudo-α-D-glucose and pseudo-β-L-altrose have been synthesized by cyclization of 2,3,4-tri-O-benzyl-5-deoxy-5-iodo-L-arabinose with dimethyl malonate in the presence of sodium hydride as a key reaction.