106418-67-1

Usage

Uses

Used in Organic Synthesis:
1-Bromo-4-decylbenzene is used as a key intermediate in organic synthesis for the production of a variety of compounds. Its unique structure allows for versatile chemical reactions, making it a valuable component in the synthesis of complex organic molecules.
Used in Pharmaceutical Production:
In the pharmaceutical industry, 1-Bromo-4-decylbenzene is utilized as an intermediate in the manufacturing process of various drugs. Its presence in the synthesis pathway contributes to the development of new medications with potential therapeutic benefits.
Used in Agrochemical Production:
Similarly, in the agrochemical sector, 1-Bromo-4-decylbenzene serves as an essential intermediate for the creation of different agrochemicals. Its role in the synthesis of these compounds aids in the development of products designed to enhance agricultural productivity and protect crops from pests and diseases.

InChI:InChI=1/C16H25Br/c1-2-3-4-5-6-7-8-9-10-15-11-13-16(17)14-12-15/h11-14H,2-10H2,1H3

Upstream product

• 106-37-6 1.4-dibromobenzene 
• 17049-50-2 n-decyl magnesium bromide 
• 134443-99-5 1-(4-bromophenyl)decan-1-one 
• 104-72-3 decylbenzene 
• 112-13-0 n-decanoyl chloride 
• 108-90-7 chlorobenzene 
• 7758-89-6 copper(I) chloride 
• 112-29-8 1-bromo dodecane 
• 30089-00-0 9-octyl-9-bora-bicyclo[3.3.1]nonane 
• 1746-28-7 1-bromo-4-(2-bromoethyl)benzene 
• 111-66-0 oct-1-ene 
• 2016-57-1 1-aminodecane 
• 5467-74-3 4-Bromophenylboronic acid 
• 108-86-1 bromobenzene 

Downstream Products

• 135329-95-2 C₃₄H₅₂ 
• 106418-66-0 2--1,3-dichloro-2-propanol 
• 38300-04-8 4-decylbenzoic acid 
• 170981-25-6 (4-decylphenyl)boronic acid 
• 126708-45-0 1-decyl-4-ethynylbenzene 
• 54256-43-8 4-decylbenzoyl chloride 
• 106418-63-7 2--2-(chloromethyl)oxirane 
• 106418-48-8 sym-hydroxy-16-crown-5 
• 1246263-85-3 4,8-bis(4-decylphenylethynyl)benzo[1,2-b:4,5-b']dithiophene 
• 1246263-87-5 2,6-dibromo-4,8-bis(4-decylphenylethynyl)benzo-[1,2-b:4,5-b']dithiophene 
• 744246-56-8 (2-(4-decylphenyl)ethynyl)trimethylsilane 
• 1065644-38-3 2,6-bis[2-(4-decylphenyl)ethynyl]anthracene 
• 1398398-07-6 2-(4-decylphenyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 

Relevant academic research and scientific papers

Synthesis of new iridium complexes and their electrophosphorescent properties in polymer light-emitting diodes

Several new iridium complexes with p-substituted 2-phenylpyridine (R-PPy) ligands have been synthesized and characterized. The complexes were incorporated into phosphorescent polymer light-emitting devices using soluble poly[1,4-bis(6′-cyano-6′-methylhept

Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C-N Bond Activation

We developed a strategy to harness alkyl amines as alkylating agents via C-N bond activation. This Suzuki-Miyaura cross coupling of alkylpyridinium salts, readily formed from primary amines, is the first example of a metal-catalyzed cross coupling via C-N bond activation of an amine with an unactivated alkyl group. This reaction enjoys broad scope and functional group tolerance. Primary and secondary alkyl groups can be installed. Preliminary studies suggest a NiI/NiIII catalytic cycle.

Discovery of a novel activator of 5-lipoxygenase from an anacardic acid derived compound collection

Lipoxygenases (LOXs) and cyclooxygenases (COXs) metabolize poly-unsaturated fatty acids into inflammatory signaling molecules. Modulation of the activity of these enzymes may provide new approaches for therapy of inflammatory diseases. In this study, we screened novel anacardic acid derivatives as modulators of human 5-LOX and COX-2 activity. Interestingly, a novel salicylate derivative 23a was identified as a surprisingly potent activator of human 5-LOX. This compound showed both non-competitive activation towards the human 5-LOX activator adenosine triphosphate (ATP) and non-essential mixed type activation against the substrate linoleic acid, while having no effect on the conversion of the substrate arachidonic acid. The kinetic analysis demonstrated a non-essential activation of the linoleic acid conversion with a KA of 8.65 μM, αKA of 0.38 μM and a β value of 1.76. It is also of interest that a comparable derivative 23d showed a mixed type inhibition for linoleic acid conversion. These observations indicate the presence of an allosteric binding site in human 5-LOX distinct from the ATP binding site. The activatory and inhibitory behavior of 23a and 23d on the conversion of linoleic compared to arachidonic acid are rationalized by docking studies, which suggest that the activator 23a stabilizes linoleic acid binding, whereas the larger inhibitor 23d blocks the enzyme active site.

Suzuki-miyaura cross-coupling reactions of unactivated alkyl halides catalyzed by a nickel pincer complex

A nickel(II) pincer complex, [(MeN2N)Ni-Cl], was used to catalyze alkyl-alkyl and alkyl-aryl Suzuki-Miyaura coupling reactions of unactivated alkyl halides. The coupling of 9-alkyl-9-borabicyclo[3.3.1]nonane and 9-phenyl-9-borabicyclo[3.3.1]nonane reagents with alkyl halides was achieved in modest to good yields. The reactions tolerated a variety of useful functional groups including ester, ether, furan, thioether, acetal, and Boc groups. Georg Thieme Verlag Stuttgart, New York.

Solution processable symmetric 4-alkylethynylbenzene end-capped anthracene derivatives

New candidates composed of anthracene and 4-alkylethynylbenzene end-capped oligomers for OTFTs were synthesized under Sonogashira coupling reaction conditions. All oligomers were characterized by FT-IR, mass, UV-visible, and PL emission spectrum analyses, cyclic voltammetry (CV), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), 1H-NMR, and 13C-NMR. Investigation of their physical properties showed that the oligomers had high oxidation potential and thermal stability. Thin films of DHPEAnt and DDPEAnt were characterized by spin coating them onto Si/SiO 2 to fabricate top-contact OTFTs. The devices prepared using DHPEAnt and DDPEAnt showed hole field-effect mobilities of 4.0 × 10-3 cm2/Vs and 2.0 × 10-3 cm2/Vs, respectively, for solution-processed OTFTs.

Synthesis and electronic properties of semiconducting polymers containing benzodithiophene with alkyl phenylethynyl substituents

Semiconducting polymers containing benzodithiophene with decyl phenylethynyl and hexadecyl phenylethynyl substituents have been synthesized by Stille coupling polymerization. The optoelectronic properties of the synthesized polymers have been investigated

NOVEL ORGANIC SEMICONDUCTOR COMPOUND, AND ORGANIC THIN FILM TRANSISTOR USING THE SAME

The present invention relates to novel mono- molecular organic semiconductor compounds and organic thin film transistors comprising the same. The organic semiconductor compounds according to the present invention are characterized by a structure of an acene derivative substituted with acetylene groups at both ends, a structure of anthracene derivative substituted with acetylene groups, or a structure of a multi-nuclear aromatic derivative functionalized by naphthalene having an electron-donor substituent at both ends.

Synthesis of novel chiral dopants based on optically active p-substituted mandelic acids

Novel esters of optically active p-substituted mandelic acids (+)-1 and (+)-2 were prepared by a convergent synthetic strategy in high enantiomeric excess (99% ee). The esters (+)-1 and (+)-2 induce helical macrostructures in the mesophases of achiral liq

Room-temperature discotic nematic liquid crystals

The use of discotic nematic liquid crystals instead of calamitic nematic liquid crystals to improve the viewing angle of a liquid crystal display device has recently been reported. Compared to the large number of calamitic molecules showing nematic phase at room temperature, the number of disk-shaped molecules showing subambient discotic nematic phase ND are rare. In this paper we present the design, synthesis, mesomorphic behaviour and structureproperty relationship of discotic nematic liquid crystals based on benzene multiyne core.

Discotic liquid crystals of transition metal complexes, 31: Establishment of mesomorphism and thermochromism of bis[1,2-bis(4-n-alkoxyphenyl)ethane-1,2-dithiolene]nickel complexes

Two series of bis[1,2-bis(4-n-alkylphenyl)ethane-1,2-dithiolene]nickel, Cn-Ni (n= 1-12), and bis[1,2-bis(4-n-alkoxyphenyl)ethane-1,2-dithiolene]nickel, CnO-Ni(n = 1-12, 14, 16, 18), have been synthesized. Their mesomorphism, thermochromism, supramolecular structures and π-acceptor property have been investigated by using different scanning calorimetry, polarizing microscopy, temperature-dependent X-ray diffraction technique, electronic spectroscopy and cyclic voltammetry. From the X-ray diffraction and electronic spectral results, it was established that the CnO-Ni complexes for n ≤ 10 exhibit two differently colored discotic lamellar (DL) mesophases whereas none of the Cn-Ni complexes has a mesophase, and that the thermochromism (brown→green) is attributable to a slow transformation from the Ni-Ni bonded dimers to the Ni-S bonded dimers.