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13067-19-1

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13067-19-1 Usage

General Description

3',4'-METHYLENEDIOXYACETANILIDE, also known as MDAA, is a chemical compound with the molecular formula C10H11NO3. It is a derivative of acetanilide, and its structure includes a methylenedioxy group attached to the 3' and 4' positions of the acetanilide molecule. MDAA is a psychoactive drug and a designer drug that has been identified in a number of illicit drug preparations. It exhibits stimulating and hallucinogenic effects similar to MDMA, and its use is associated with potential health risks and adverse effects. The compound has been classified as a Schedule I controlled substance in the United States, and its production, sale, and possession are illegal.

Check Digit Verification of cas no

The CAS Registry Mumber 13067-19-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,0,6 and 7 respectively; the second part has 2 digits, 1 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 13067-19:
(7*1)+(6*3)+(5*0)+(4*6)+(3*7)+(2*1)+(1*9)=81
81 % 10 = 1
So 13067-19-1 is a valid CAS Registry Number.

13067-19-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name N-(1,3-benzodioxol-5-yl)acetamide

1.2 Other means of identification

Product number -
Other names 5-acetamido-1,3-benzodioxole

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13067-19-1 SDS

13067-19-1Relevant articles and documents

Synthesis and biological evaluation of 10,11-methylenedioxy-14- azacamptothecin

Elban, Mark A.,Sun, Wenyue,Eisenhauer, Brian M.,Gao, Rong,Hecht, Sidney M.

, p. 3513 - 3516 (2006)

10,11-Methylenedioxy-14-azacamptothecin, a potent analogue of the antitumor agent camptothecin (CPT), has been prepared via a key condensation between AB and DE ring precursors. The biological testing of this compound validated a strategy for modulation of the off-rate of camptothecin analogues from the topoisomerase-DNA-CPT ternary complex via structural modification.

A novel construction of acetamides from rhodium-catalyzed aminocarbonylation of DMC with nitro compounds

Bao, Zhi-Peng,Miao, Ren-Guan,Qi, Xinxin,Wu, Xiao-Feng

supporting information, p. 1955 - 1958 (2021/03/02)

Dimethyl carbonate (DMC), an environment-friendly compound prepared from CO2, shows diverse reactivities. In this communication, an efficient procedure using DMC as both a C1 building block and solvent in the aminocarbonylation reaction with nitro compounds has been developed. W(CO)6acts both a CO source and a reductant here.

Preparation method of acetamide compound

-

Paragraph 0035-0047; 0056-0059, (2021/05/19)

The invention discloses a preparation method of an acetamide compound, the preparation method comprises the following steps: reacting tetracarbonyl dichloride rhodium, 1, 3-bis (diphenylphosphine) propane, tungsten carbonyl, sodium phosphate, sodium iodide, water, a nitro compound and dimethyl carbonate at 120 DEG C for 24 hours, and after the reaction is completed, performing post-treatment to obtain the acetamide compound. According to the preparation method, dimethyl carbonate serves as a C1 source and also serves as a green solvent, operation is easy, reaction starting raw materials are low in price and easy to obtain, the tolerance range of substrate functional groups is wide, and reaction efficiency is high. Various acetamide compounds can be synthesized according to actual needs, so that the practicability of the method is widened while the operation is convenient.

Sulfuryl Fluoride Mediated Synthesis of Amides and Amidines from Ketoximes via Beckmann Rearrangement

Gurjar, Jitendra,Fokin, Valery V.

supporting information, p. 10402 - 10405 (2020/07/25)

A metal-free and redox-neutral method for Beckmann rearrangement employing inexpensive and readily available SO2F2 gas is described. The reported transformation proceeds at ambient temperature and is compatible with a wide range of sterically and electronically diverse aromatic, heteroaromatic, aliphatic and lignin-like oximes providing amides in good to excellent yields. The reaction proceeds through the formation of an imidoyl fluoride intermediate that can also be used for the synthesis of amidines.

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