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(1R, 2R)-2-(phenylthio)cyclohexyl acetate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

133775-38-9

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133775-38-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 133775-38-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,3,7,7 and 5 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 133775-38:
(8*1)+(7*3)+(6*3)+(5*7)+(4*7)+(3*5)+(2*3)+(1*8)=139
139 % 10 = 9
So 133775-38-9 is a valid CAS Registry Number.

133775-38-9Relevant articles and documents

PhI(OAc)2/KI mediated 1,2-acetoxysulfenylation of alkenes: Facile synthesis of β-acetoxysulfides

Muangkaew, Charoensak,Katrun, Praewpan,Kanchanarugee, Patcharaphon,Pohmakotr, Manat,Reutrakul, Vichai,Soorukram, Darunee,Jaipetch, Thaworn,Kuhakarn, Chutima

, p. 8847 - 8856 (2013/09/23)

A convenient method for 1,2-acetoxysulfenylation of alkenes using disulfide promoted by (diacetoxyiodo)benzene (PhI(OAc)2, DIB)/KI was developed. The reaction is highly regioselective for styrene derivatives while aliphatic alkenes lead to a mixture of two regioisomers.

Highly enantioselective kinetic resolution of trans-2-(phenylthio) cyclohexanol derivatives by immobilized Candida antartica B lipase

Chimni, Swapandeep Singh,Kaur, Kirandeep,Bala, Neeraj

, p. 67 - 74 (2013/10/22)

Candida antartica B (immobilized CAL-B) mediated resolutions of trans-2-(phenylthio)cyclohexanol derivatives using vinyl acetate as acylating agent and MTBE as solvent provide excellent enantioselectivity (up to >99%) and high yield of both the enantiomer

Diastereoselective synthesis of β-hydroxy sulfoxides: Enzymatic and biomimetic approaches

Colonna, Stefano,Pironti, Vincenza,Zambianchi, Francesca,Ottolina, Gianluca,Gaggero, Nicoletta,Celentano, Giuseppe

, p. 363 - 368 (2007/10/03)

Stereoselectivities of up to 98 % have been found in the enzymatic synthesis of β-hydroxy sulfoxides catalyzed by cyclohexanone monooxygenase (CHMO). The diastereoselectivity of the "one-pot" preparation of the title compounds in the presence of bovine se

Copper-catalyzed 1,2-hydroxysulfenylation of alkene using disulfide via cleavage of the S-S bond

Taniguchi, Nobukazu

, p. 7874 - 7876 (2007/10/03)

(Chemical Equation Presented) Copper-catalyzed 1,2-hydroxysulfenylation of alkenes can be carried out by the use of disulfides and acetic acid in air. This reaction regio- and anti-selectively gave the corresponding 1,2-acetoxysulfides. Furthermore, the p

Synthesis of an enantiomerically pure aminoisoquinocarbazole with antiarrhythmic activity via lipase-catalyzed enantioselective transesterification

Fukazawa, Tetuya,Shimoji, Yasuo,Hashimoto, Toshihiko

, p. 1649 - 1658 (2007/10/03)

Enantiomerically pure (R)-2-cyclohexen-1-ol 5 was prepared via lipase- catalyzed enantioselective transesterification of 2-substituted cyclohexanol, and stereospecifically converted to (-)-(2-cyclohexenyl)acetic acid 4. Enantiomerically pure aminoisoquinocarbazole 1 (RS-2135) was synthesized stereoselectively from 4, using an intramolecular Diels-Alder reaction and Curtius rearrangement.

Synthesis of enantiomerically pure (R)-2-cycloalken-1-ols using highly enantioselective enzymatic transesterification

Fukazawa,Hashimoto

, p. 2323 - 2326 (2007/10/02)

Optically pure (R)-2-cycloalken-1-ols were synthesized via highly enantioselective lipase-catalyzed transesterification of 2-substituted cycloalkanols.

Indolobenzoquinoline derivatives, their preparation and their use as anti-arrhythmic drugs

-

, (2008/06/13)

Optically active compounds of formula (I): in which R1 is hydrogen or alkyl; Xband Ybare hydrogen or hydroxy; and Z is -NRaRb, in which Raand Rbare hydrogen, alkyl or hydroxyalkyl,or a cyclic amino group;, and pharmaceutically acceptable salts thereof have enhanced anti-arrhythmic activity and may be prepared by a stereospecific synthesis process.

ELECTROPHILIC SULFAMATOSULFENYLATION OF OLEFINS

Zefirov, N.S.,Zyk, N.V.,Kutateladze, A.G.,Lapin, Yu.A.

, p. 351 - 360 (2007/10/02)

The reaction of N,N-dialkylarenesufenamides with sulfur trioxides gave arenesulfenyl sulfamates, which have clearly defined electrophilic characteristics.These reagents are capable of adding at the C=C bond of olefins with the formation of the sulfamates of arylthio-substituted alcohols.The reaction with cyclohexene is stereospecific and leads to the trans-1,2-adducts, while the reaction with norbornene and norbornadiene is accompanied by rearrangement of the carbon framework.For the case of the cyclohexane derivatives it was shown that the vicinal arylthiosulfamates are highly sensitive to nucleophilic reagents.

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