13683-11-9

Basic information

• Product Name: chloro(dimethyl)[(trimethylsilyl)methyl]silane
• Synonyms: [(Chlorodimethylsilyl)methyl]trimethyl silane; Chloro(dimethyl)[(trimethylsilyl)methyl]silane; silane, chlorodimethyl[(trimethylsilyl)methyl]-
• CAS NO: 13683-11-9
• Molecular Formula: C₆H₁₇ClSi₂
• Molecular Weight: 180.8232
• Mol File: 13683-11-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 153.2°C at 760 mmHg
• Flash Point: 34.9°C
• Density: 0.859g/cm³
• Vapor Pressure: 4.32mmHg at 25°C
• Refractive Index: 1.409
• CAS DataBase Reference: chloro(dimethyl)[(trimethylsilyl)methyl]silane(CAS DataBase Reference)
• NIST Chemistry Reference: chloro(dimethyl)[(trimethylsilyl)methyl]silane(13683-11-9)
• EPA Substance Registry System: chloro(dimethyl)[(trimethylsilyl)methyl]silane(13683-11-9)

Safety Data

• Hazardous Substances Data: 13683-11-9(Hazardous Substances Data)

Upstream product

• 1719-57-9 Chloro(chloromethyl)dimethylsilane 
• 2117-28-4 bis(trimethylsilyl)methane 
• 1440146-65-5 dimethyl(2,4,6-trimethoxyphenyl)[(trimethylsilyl)methyl]silane 

Downstream Products

• 69053-37-8 [3-(Dimethyl-trimethylsilanylmethyl-silanyl)-prop-2-ynyl]-benzene 
• 992-94-9 methylsilane 
• 1111-74-6 dimethylsilane 
• 993-07-7 trimethylsilan 
• 993-00-0 chloro-methyl-silane 
• 814-98-2 1,1,2,2-tetramethyldisilane 
• 870-26-8 1,2-dimethyldisilane 
• 18163-84-3 2,4-dimethyl-2,4-disilapentane 
• 1189-75-9 (trimethylsilylmethyl)dimethylsilane 
• 18148-13-5 1,3,3-Trimethyl-1,3-disilapropan 
• 5654-05-7 bis(methylsilyl)methane 
• 75-54-7 Dichloromethylsilane 
• 1066-35-9 dimethylmonochlorosilane 
• 73355-30-3 {2-[4-(Dimethyl-trimethylsilanylmethyl-silanyl)-phenoxy]-ethyl}-diethyl-amine 

Relevant articles and documents

Synthesis of silicon-functionalized (silylmethyl)silanes and-dichlorocarbosilanes using the TMOP (2,4,6-trimethoxyphenyl) protecting group: (TMOP)Me2SiCH2Cl and (TMOP) 2MeSiCH2Cl as reagents to introduce the ClMe 2SiCH2, MeOMe2SiCH2, or Cl2MeSiCH2 group by nucleophilic substitution at silicon

In this study, the synthetic potential of the 2,4,6-trimethoxyphenyl (TMOP)-substituted (chloromethyl)silanes (TMOP)Me2SiCH2Cl (1) and (TMOP)2MeSiCH2Cl (2) for the preparation of Si-functionalized (silylmethyl)silanes and α,ω-dichlorocarbosilanes (with skeletons consisting of alternate carbon and silicon atoms) was investigated. Compounds 1 and 2 were used as reagents to introduce the ClMe 2SiCH2, MeOMe2SiCH2, or Cl 2MeSiCH2 group by nucleophilic substitution at silicon. The three-step synthetic method involves the (i) transformation of 1 and 2 into (TMOP)Me2SiCH2MgCl, (TMOP)Me2SiCH 2Li, (TMOP)2MeSiCH2MgCl, and (TMOP) 2MeSiCH2Li, respectively, (ii) reaction of these nucleophiles with chloro- or methoxysilanes, and (iii) subsequent selective cleavage of the TMOP protecting group with HCl/Et2O or MeOH/[CF 3COOH]. Using this method, the following compounds were prepared: ClMe2SiCH2SiMe3 (3), ClMe2SiCH 2SiMe2Cl (4), ClMe2SiCH2SiMeCl 2 (5), ClMe2SiCH2SiCl3 (6), ClMe2SiCH2Si(OMe)3 (7), MeOMe 2SiCH2Si(OMe)3 (8), Cl2MeSiCH 2SiMe3 (9), Me2Si(CH2SiMe 2Cl)2 (10), and Me2Si(CH2SiMe 2CH2SiMe2Cl)2 (11).

GENERATION OF 1,1-DIMETHYL-1-SILAETHYLENE Me2Si=CH2 IN THE DECHLORINATION OF CHLOROMETHYLDIMETHYLCHLOROSILANE BY ALKALI METAL VAPOR

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