13803-39-9

Basic information

• Product Name: 5-PHENYL-2-FURALDEHYDE
• Synonyms: ASISCHEM R39511;5-PHENYL-FURAN-2-CARBALDEHYDE;5-PHENYL-2-FURALDEHYDE;AKOS BAR-0555;2-ForMyl-5-phenylfuran;5-Phenyl-2-furancarboxaldehyde;5-Phenylfurfural;5-Phenyl-2-furaldehyde 96%
• CAS NO: 13803-39-9
• Molecular Formula: C₁₁H₈O₂
• Molecular Weight: 172.18
• Product Categories: API intermediates;Building Blocks;Furans;Heterocyclic Building Blocks
• Mol File: 13803-39-9.mol
• Article Data: 89

Chemical Properties

• Melting Point: 29-33 °C(lit.)
• Boiling Point: 146℃ (5 Torr)
• Flash Point: >230 °F
• Appearance: Yellow to green to brown/Solid or Lliquid
• Density: 1.154 g/cm³
• Vapor Pressure: 0.000279mmHg at 25°C
• Refractive Index: 1.583
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• CAS DataBase Reference: 5-PHENYL-2-FURALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 5-PHENYL-2-FURALDEHYDE(13803-39-9)
• EPA Substance Registry System: 5-PHENYL-2-FURALDEHYDE(13803-39-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 13803-39-9(Hazardous Substances Data)

Usage

General Description

5-Phenyl-2-furaldehyde can be prepared from phenylfuran, via formylation. It undergoes electrochemical reduction on a dropping Hg electrode to afford anion radicals in DMF.

InChI:InChI=1/C11H8O2/c12-8-10-6-7-11(13-10)9-4-2-1-3-5-9/h1-8H

Upstream product

• 591-50-4 iodobenzene 
• 27329-70-0 5-formylfurane-2-boronic acid 
• 98-01-1 furfural 
• 108-90-7 chlorobenzene 
• 108-86-1 bromobenzene 
• 1899-24-7 5-bromo-2-furancarboxaldehyde 
• 109674-45-5 4-methyl-2,6-dioxo-8-phenylhexahydro-[1,3,2]oxazaborolo[2,3-b][1,3,2]oxazaborol-4-ium-8-uide 
• 62-53-3 aniline 
• 603-33-8 triphenylbismuthane 
• 98-13-5 Phenyltrichlorosilane 
• 21508-19-0 5-chloro-2-furaldehyde 
• 368-47-8 phenyltrifluorosilane 
• 2689-65-8 5-iodofuran-2-carbaldehyde 
• 98-80-6 phenylboronic acid 

Downstream Products

• 179055-61-9 Cycloheptyl-(5-phenyl-furan-2-ylmethyl)-amine 
• 1200091-32-2 methyl 2-[{[(4-methylphenyl )sulfonyl]amino}(5-phenylfuran-2-yl)methyl]prop-2-enoate 
• 1403473-77-7 N-{3-[3-(tert-butoxycarbonylamino)benzyl]-2,4-dioxoimidazolidin-1-yl}-5-phenyl-2-furamide 
• 1403473-09-5 N-[3-(3-aminobenzyl)-2,4-dioxoimidazolidin-1-yl]-5-phenyl-2-furamide hydrochloride 
• 1403473-71-1 5-phenyl-N-(2,4-dioxoimidazolidin-1-yl)-2-furamide 
• 73486-35-8 2-(2-nitrovinyl)-5-phenylfuran 
• 71971-00-1 Ethyl 2-Phenyl-4H-furo<3,2-b>pyrrole-5-carboxylate 
• 86345-40-6 ethyl 2-phenyl-4-methylfuro<3,2-b>pyrrole-5-carboxylate 
• 86345-42-8 ethyl 2-phenyl-4-(2-cyanoethyl)furo<3,2-b>pyrrole-5-carboxylate 
• 86345-46-2 2-phenyl-4-methylfuro<3,2-b>pyrrole-5-carboxylic acid 
• 86345-44-0 2-phenyl-4H-furo<3,2-b>pyrrole-5-carboxylic acid 
• 86345-48-4 2-phenyl-4-methylfuro<3,2-b>pyrrole 
• 77485-00-8 2-phenyl-4H-furo<3,2-b>pyrrole 
• 145161-77-9 ethyl 2-triphenylphosphoimino-3-(5-phenyl-2-furyl)acrylate 

Relevant articles and documents

A Bis (BICAAC) Palladium(II) Complex: Synthesis and Implementation as Catalyst in Heck-Mizoroki and Suzuki-Miyaura Cross Coupling Reactions

Carbenes are one of the most appealing, well-explored, and exciting ligands in modern chemistry due to their tunable stereoelectronic properties and a wide area of applications. A palladium complex (BICAAC)2PdCl2 with a recently discovered cyclic (alkyl)(amino)carbene having bicyclo[2.2.2] octane skeleton (BICAAC) was synthesized and characterized. The enhanced σ-donating and π-accepting ability of this carbene lend a hand to form a robust Pd-carbene bond, which allowed us to probe its reactivity as a precatalyst in Heck-Mizoroki and Suzuki-Miyaura cross-coupling reactions with low catalyst loading in open-air conditions. The diverse range of substrates was explored for both the cross-coupling reactions. To get a better understanding of the catalytic reactions, several analytical techniques such as field-emission scanning electron microscopy, high-resolution transmission electron microscopy, and powder X-ray diffraction were employed in a conclusive manner.

A novel class of amide-derived air-stable P,O-ligands for Suzuki cross-coupling at low catalyst loading

The benzamide-derived P,O-ligands efficiently promoted the Pd-catalyzed Suzuki cross-coupling reactions of aryl bromides with phenylboronic acid at 0.01mol% of Pd loading at 60-80°C to form biaryls in excellent yields. A sterically hindered arylboronic acid gave a quantitative yield of the coupling product at 110°C with 1mol% Pd.

Synthesis of [PdBr2(benzimidazole-2-ylidene)(pyridine)] complexes and their catalytic activity in the direct C[sbnd]H bond activation of 2-substituted heterocycles

A series of unsymmetrical 1,3-disubstituted benzimidazolium chlorides, 2a-f, having two nitrogen atoms substituted by various alkyl groups were synthesized as N-heterocyclic carbene (NHC) precursors in high yields. The benzimidazolium salts are readily co

New benzimidazolium N-heterocyclic carbene precursors and their related Pd-NHC complex PEPPSI-type: Synthesis, structures, DFT calculations, biological activity, docking study, and catalytic application in the direct arylation

New benzhydryl-5,6-dimethyl-(3-methylbenzyl)benzimidazolium salt as N-heterocyclic carbene precursors and their related new Pd-NHC complex PEPPSI-type with the general formula [PdBr2(NHC)(pyridine)] were prepared and theoretically studied. Quan

Synthesis, structures, DFT calculations, and catalytic application in the direct arylation of five-membered heteroarenes with aryl bromides of novel palladium-N-heterocyclic carbene PEPPSI-type complexes

A new series of Pd-catalysts based on an N-heterocyclic carbene PEPPSI-type ligand (PEPPSI = pyridine enhanced precatalyst preparation stabilization and initiation) with the general formula [Pd(ii)Br2(NHC)(pyridine)] was synthesized and fully characterize