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15961-35-0

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15961-35-0 Usage

Description

4,4,6-Trimethyl-2-phenyl-1,3,2-dioxaborinane, a boron-containing heterocyclic compound with the molecular formula C11H15BO2, is widely recognized for its versatility in organic synthesis. This chemical compound is characterized by its ability to introduce boron functional groups, making it a valuable reagent in the preparation of pharmaceuticals, agrochemicals, and materials. Additionally, its capacity to form stable complexes with transition metals has established it as a prominent ligand in organometallic catalysis reactions. The significance of 4,4,6-Trimethyl-2-phenyl-1,3,2-dioxaborinane in the realm of organic chemistry is underscored by its diverse applications in the synthesis of crucial compounds.

Uses

Used in Pharmaceutical Synthesis:
4,4,6-Trimethyl-2-phenyl-1,3,2-dioxaborinane is used as a reagent for the introduction of boron functional groups in the synthesis of various pharmaceuticals. Its ability to form stable complexes with transition metals aids in the development of new drugs with improved efficacy and selectivity.
Used in Agrochemical Production:
In the agrochemical industry, 4,4,6-Trimethyl-2-phenyl-1,3,2-dioxaborinane serves as a building block for the creation of novel agrochemicals. Its role in the synthesis of boron-containing compounds contributes to the development of more effective and targeted pest control agents.
Used in Material Science:
4,4,6-Trimethyl-2-phenyl-1,3,2-dioxaborinane is utilized as a key component in the synthesis of advanced materials, such as polymers and composites. Its incorporation into these materials enhances their properties, leading to improved performance in various applications.
Used in Organometallic Catalysis:
As a ligand in organometallic catalysis reactions, 4,4,6-Trimethyl-2-phenyl-1,3,2-dioxaborinane is employed to form stable complexes with transition metals. This enhances the efficiency and selectivity of catalytic processes, facilitating the synthesis of complex organic compounds with high yields and purity.

Check Digit Verification of cas no

The CAS Registry Mumber 15961-35-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,5,9,6 and 1 respectively; the second part has 2 digits, 3 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 15961-35:
(7*1)+(6*5)+(5*9)+(4*6)+(3*1)+(2*3)+(1*5)=120
120 % 10 = 0
So 15961-35-0 is a valid CAS Registry Number.

15961-35-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 4,4,6-TRIMETHYL-2-PHENYL-1,3,2-DIOXABORINANE

1.2 Other means of identification

Product number -
Other names Benzeneboronic acid hexylene glycol cyclic ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:15961-35-0 SDS

15961-35-0Relevant articles and documents

Unreactive C-N Bond Activation of Anilines via Photoinduced Aerobic Borylation

Ji, Shuohan,Luo, Lu,Qin, Shengxiang,Yin, Chunyu,Zhang, Hua

supporting information, (2021/12/27)

Unreactive C-N bond activation of anilines was achieved by photoinduced aerobic borylation. A diverse range of tertiary and secondary anilines were converted to aryl boronate esters in moderate to good yields with wide functional group tolerance under simple and ambient photochemical conditions. This transformation achieved the direct and facile C-N bond activation of unreactive anilines, providing a convenient and practical route transforming widely available anilines into useful aryl boronate esters.

Nickel-catalysed decarbonylative borylation of aroyl fluorides

Wang, Zhenhua,Wang, Xiu,Nishihara, Yasushi

supporting information, p. 13969 - 13972 (2019/01/03)

The first Ni(cod)2/PPh3 catalyst system has been established for decarbonylative borylation of aroyl fluorides with bis(pinacolato)diboron. A wide range of functional groups in the substrates were well tolerated. The ease of access of the starting aroyl fluorides indicates that these results might become an alternative to the existing decarbonylation events.

Tris(trimethylsilyl)silylboronate Esters: Novel Bulky, Air- and Moisture-Stable Silylboronate Ester Reagents for Boryl Substitution and Silaboration Reactions

Yamamoto, Eiji,Shishido, Ryosuke,Seki, Tomohiro,Ito, Hajime

supporting information, p. 3019 - 3022 (2017/09/05)

New, bulky tris(trimethylsilyl)silylboronate pinacol and hexylene glycol esters ((TMS)3Si-B(pin) and (TMS)3Si-B(hg)) were prepared in 46 and 61% yields, respectively, by the reaction of tris(trimethylsilyl)silylpotassium with the corresponding boron electrophiles. Notably, these silylboronate esters exhibited high stability to air and silica gel and were applied to the transition-metal-free boryl substitution of aryl halides, providing the desired borylated products in high yields with excellent B:Si ratios (up to 96% yield, B/Si = 99/1). These new silylboronate esters were also applied to a sequential borylation/cross-coupling process with various aryl halides, as well as the base-mediated silaboration of styrene.

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