10199-14-1

Basic information

• Product Name: 4,4,6-trimethyl-1,3,2-dioxaborinane
• CAS NO: 10199-14-1
• Molecular Weight: 127.979
• Mol File: 10199-14-1.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 4,4,6-trimethyl-1,3,2-dioxaborinane(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4,6-trimethyl-1,3,2-dioxaborinane(10199-14-1)
• EPA Substance Registry System: 4,4,6-trimethyl-1,3,2-dioxaborinane(10199-14-1)

Safety Data

• Hazardous Substances Data: 10199-14-1(Hazardous Substances Data)

Upstream product

• 100-89-0 tris{2-methyl pentane diol(2.4)ato}diborane 
• 52137-80-1 2-chlor-4,4,6-trimethyl-1,3,2-dioxaborinane 
• 230299-21-5 4,4,4',4',6,6'-hexamethyl-2,2'-bi(1,3,2-dioxaborinane)bis(hexyleneglycolato)diboron 
• 1333-74-0 hydrogen 
• 107-41-5 2-methyl-2,4-pentanediol 
• 13292-87-0 dimethylsulfide borane complex 
• 19287-45-7 diborane 
• 14697-50-8 4,4,6,4',4',6'-hexamethyl-2,2'-oxy-bis-[1,3,2]dioxaborinane 

Downstream Products

• 934558-32-4 4-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)phenylamine 
• 934558-37-9 2-(2-methoxyphenyl)-4,4,6-trimethyl-1,3,2-dioxaborinane 
• 934558-31-3 2-(4-methoxyphenyl)-4,4,6-trimethyl-1,3,2-dioxaborinane 
• 100-66-3 methoxybenzene 
• 15961-35-0 4,4,6-trimethyl-2-phenyl-[1,3,2]dioxaborinane 
• 4627-10-5 4,4,6-trimethyl-2-vinyl-1,3,2-dioxaborinane 
• 91-20-3 naphthalene 
• 1260068-92-5 4,4,6-trimethyl-2-naphthalen-2-yl[1,3,2]dioxaborinane 
• 1092060-77-9 2-(4-methylphenyl)-4,4,6-trimethyl-1,3,2-dioxaborinane 
• 119-61-9 benzophenone 
• 1260068-93-6 C₁₉H₂₁BO₃ 
• 93-58-3 benzoic acid methyl ester 
• 1092060-80-4 methyl 4-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)benzoate 
• 1092060-81-5 4-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)benzonitrile 

Relevant articles and documents

A highly efficient cobalt-catalyzed deuterogenolysis of diboron: Synthesis of deuterated pinacolborane and vinylboronates

Highly efficient hydrogenolysis and deuterogenolysis of diboron compounds have been realized by the use of a cobalt catalyst, affording TON up to 48201. Furthermore, a one-pot two-step procedure comprising sequential deuterogenolysis of diboron and deuteroboration of alkynes under the same cobalt catalyst has been developed for the efficient, atom-economical synthesis of deuterated vinylboronates with high deuterium incorporation and excellent regio- and stereoselectivity.

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A process for preparing a diboron ester (by machine translation)

The invention discloses a process for preparing a diboron ester. Borane complexes and corresponding diol reaction and produce corresponding mellow borane, the iron then took place in the presence of catalyst to self-coupling forming a diboron ester. Short synthesis steps of the method, high safety, mild reaction conditions, suitable for many kinds of a diboron ester synthesis. (by machine translation)

Catalytic asymmetric hydroboration of β,γ-unsaturated Weinreb amides: Striking influence of the borane

Subtle differences in the structure of the borane strongly influence the catalytic efficiency and level of enantioselectivity in the catalytic asymmetric hydroboration of β,γ-unsaturated Weinreb amides.