16483-98-0

Basic information

• Product Name: 2,3-Diphenyl-2H-azirine
• Synonyms: 2,3-Diphenyl-2H-azirine
• CAS NO: 16483-98-0
• Molecular Formula: C₁₄H₁₁N
• Molecular Weight: 193.2438
• Mol File: 16483-98-0.mol
• Article Data: 34

Chemical Properties

• Boiling Point: 323.1°Cat760mmHg
• Flash Point: 141.3°C
• Appearance: /
• Density: 1.09g/cm³
• Vapor Pressure: 0.000506mmHg at 25°C
• Refractive Index: 1.623
• PKA: 3.16±0.40(Predicted)
• CAS DataBase Reference: 2,3-Diphenyl-2H-azirine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-Diphenyl-2H-azirine(16483-98-0)
• EPA Substance Registry System: 2,3-Diphenyl-2H-azirine(16483-98-0)

Safety Data

• Hazardous Substances Data: 16483-98-0(Hazardous Substances Data)

Usage

General Description

2,3-Diphenyl-2H-azirine is a chemical compound with a molecular formula C14H12N. It is a nitrogen-containing heterocyclic compound that is classified as an azirine. Azirines are highly reactive and have been studied for their potential use in organic synthesis and as intermediates in the preparation of various compounds. 2,3-Diphenyl-2H-azirine has been investigated for its reactivity in various chemical reactions and its potential applications in the field of organic chemistry. It is important to handle this compound with care due to its reactivity and potential hazards.

InChI:InChI=1/C14H11N/c1-3-7-11(8-4-1)13-14(15-13)12-9-5-2-6-10-12/h1-10,13H

Upstream product

• 4098-15-1 (1-azido-2-iodoethane-1,2-diyl)dibenzene 
• 140-29-4 phenylacetonitrile 
• 98-80-6 phenylboronic acid 
• 19690-01-8 1,2-diphenylethanone O-acetyl oxime 
• 588-59-0 stilbene 
• 61795-22-0 (1-azidoethene-1,2-diyl)dibenzene 
• 952-06-7 deoxybenzoin oxime 
• 33777-82-1 N'-[1,2-Diphenyl-eth-(E)-ylidene]-N,N,N-trimethyl-hydrazinium; iodide 
• 33785-81-8 1,2-diphenylethan-1-one N,N-dimethylhydrazone 
• 451-40-1 phenyl benzyl ketone 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 4098-15-1 C₁₄H₁₂IN₃ 
• 61588-70-3 N-(4,5-diphenyl-1H-[1,2,3]triazol-1-yl)-4-methyl-benzamide 
• 61588-68-9 N-(4,5-diphenyl-[1,2,3]triazol-1-yl)-benzamide 

Downstream Products

• 54049-12-6 5-(tert-butyl)-2,4-diphenyloxazole 
• 2818-82-8 2-methyl-4,5-diphenyl-1H-imidazole 
• 642-04-6 2,3,5,6-tetraphenylpyrazine 
• 750593-89-6 dimethyl 3,4-diphenyl-2,3-dihydroazete-2,2-dicarboxylate 
• 1369425-94-4 C₂₈H₂₂N₂ 
• 1369425-93-3 C₂₈H₂₂N₂ 
• 100-47-0 benzonitrile 
• 185623-84-1 (1E,3Z)-1,3,4-triphenyl-2-aza-1,3-butadiene 
• 1454283-84-1 ethyl 4,5,6-triphenylpicolinate 

Relevant articles and documents

Visible-Light-Promoted [3 + 2] Cycloaddition of 2H-Azirines with Quinones: Access to Substituted Benzo[f]isoindole-4,9-diones

A visible-light-promoteded [3 + 2] cycloaddition reaction of 2H-azirines with quinones has been developed under mild reaction conditions. The reaction provides a general and efficient strategy for the synthesis of the benzo[f]isoindole-4,9-diones scaffold

Harnessing in Situ Radical Oxygenation: Copper-Catalyzed Interrupted Azirine-Alkyne Ring-Expansion Reaction for the Synthesis of Pyrrolones

Here we report a novel interrupted azirine-alkyne ring-expansion reaction with molecular oxygen for the direct synthesis of highly functionalized pyrrolones enabled by copper catalysis. Mechanistic investigations indicate that the present three-component reaction proceeds via two copper-catalyzed sequential reactions, an azirine-ring-opening alkynylation and an amine-directed radical oxygenation, leading to the formation of interesting pyrrolone structures under mild conditions.

Photocatalytic Approach for Construction of 5,6-Dihydroimidazo[2,1- A[isoquinolines and Their Luminescent Properties

A visible-light-driven photoredox reaction of tetrahydroisoquinoline with 2H-azirines is described. 4,7-Bis(4-methoxyphenyl)benzo[c][1,2,5]thiadiazole, a benzothiadiazole (BTD) derived fluorophore, is used as an organic photoredox catalyst, and the reacti