17355-24-7

Usage

Chemical Properties

White powder

Upstream product

• 108-24-7 acetic anhydride 
• 7479-01-8 O-methyl-L-tyrosine methyl ester hydrochloride 
• 537-55-3 N-acetyl-L-tyrosine 
• 74-88-4 methyl iodide 
• 28047-05-4 (S)-N-acetyl-p-methoxyphenylalanine 
• 556-02-5 tyrosine 
• 19764-32-0 Ac-D-Tyrosine 
• 71198-72-6 4-[(4-methoxyphenyl)methylene]-2-methyl-5(4H)-oxazolone 
• 71198-72-6 (4Z)-4-(4-methoxybenzylidene)-2-methyl-oxazolin-5-one 
• 123-11-5 4-methoxy-benzaldehyde 
• 824-94-2 p-methoxybenzyl chloride 
• 81961-88-8 ethyl 2-acetylamino-2-cyano-3-(4-methoxyphenyl)propanoate 
• 109-21-7 butyl butyrate 
• 70529-50-9 methyl 2-acetylamino-3-(4-methoxyphenyl)propanoate 

Downstream Products

• 855594-70-6 N-[(1S)-2-hydroxy-1-(4-methoxybenzyl)ethyl]acetamide 
• 37466-31-2 C₁₄H₁₇NO₅ 
• 103550-92-1 N-acetyl-3-(3-formyl-4-methoxyphenyl)-D-alanine methyl ester 
• 1262850-97-4 C₁₉H₂₇NO₆ 
• 1380403-22-4 C₁₄H₁₇NO₃ 
• 1380403-23-5 C₁₉H₂₉NO₇ 
• 1380403-25-7 C₂₀H₃₁NO₉S 
• 1380403-08-6 C₁₂H₁₇NO₃ 
• 1380403-11-1 (R)-N-(1-(4-methoxyphenyl)-3-oxopropan-2-yl)acetamide 

Relevant academic research and scientific papers

A comparison of phosphaferrocene and phospharuthenocene ligands in Rh +-catalysed enamide hydrogenation reactions: Superior performance of the phospharuthenocene

Enantiopure Cp*-substituted 3.4-dimethyl-5-phenylphosphametallocene- 2-methanols (M=Fe, Ru) have been prepared from the corresponding 2-carboxy-(-)-menthylphospholide anion and elaborated into 2-CH 2PPh2 phosphametallocenes (13: M =

High enantioselectivity is induced by a single monodentate phosphoramidite ligand in iridium-catalyzed asymmetric hydrogenation

(Chemical Equation Presented) The Full Monty? Stripping a catalyst down to its bare essentials gives a neutral iridium complex containing only one monodentate phosphoramidite ligand that is an efficient catalyst for the enantioselective hydrogenation of α-dehydroamino acids (see picture).

Novel chiral phosphine-phosphoramidite ligands derived from 1-naphthylamine for highly efficient Rh-catalyzed asymmetric hydrogenation

A new chiral phosphine-phosphoramidite ligand (S)-HY-Phos 1 has been prepared from 1-naphthylamine via a two-step transformation, and successfully applied in the Rh-catalyzed asymmetric hydrogenation of various functionalized olefins, including α-(acetamido)cinnamates, enamides and α-enol ester phosphonates, in which up to 98% ee, 99% ee and 99% ee were achieved, respectively.

Studies on the rhodium- and ruthenium-catalyzed asymmetric hydrogenation of α-dehydroamino acids using a family of chiral dipyridylphosphine ligand (P-Phos)

The applications of the chiral dipyridylphosphine ligand P-Phos and its derivatives Tol-P-Phos and Xyl-P-Phos in Ru- and Rh-catalyzed hydrogenations of the methyl esters of a variety of (Z)-2-acetamido-3-arylacrylic acids have been studied systematically.

Modified BINAPO ligands for Rh-catalysed enantioselective hydrogenation of acetamidoacrylic acids and esters

(S)- and (R)-2,2′-Bis[bis(3,5-dimethylphenyl)phosphinoyl]-5,5′,6, 6′,7,7′,8,8′-octahydro-1,1′-binaphthyl (Xyl-H8-BINAPO) were synthesised by reacting chlorobis(3,5-dimethylphenyl)phosphine with (S)- and (R)-2,2′-dihydroxyl-5,5′,6,6′,7,7′,8,8′-

Novel phosphine-phosphites and their use in asymmetric hydrogenation

Excellent enantioselectivities and activities have been obtained in the rhodium catalyzed asymmetric hydrogenation of dimethyl itaconate and several dehydroamino acid esters using a new class of BINOL based phosphine-phosphite ligand. The hydrogenation pr

Carbohydrate-derived monophosphite ligands for Rh-catalyzed enantioselective hydrogenation of α- and β-dehydroamino acid esters

A series of monophosphite ligands derived from D-fructose and D-glucose have been synthesized and employed in Rh-catalyzed asymmetric hydrogenation of α- and β-dehydroamino acid esters. A variety of chiral α- and β-amino acid esters have been obtained in

Unsymmetrical ferrocenylethylamine-derived monophosphoramidites: Highly efficient chiral ligands for Rh-catalyzed enantioselective hydrogenation of enamides and α-dehydroamino acid derivatives

A new family of unsymmetrical ferrocenylethylamine-derived monophosphoramidites were synthesized and successfully applied in the Rh-catalyzed enantioselective hydrogenation of a range of enamides and α-dehydroamino acid esters, and ee values of up to 99.5% were obtained for both types of substrate. These results suggest that unsymmetrical amine-derived monophosphoramidites can also exhibit excellent enantioselectivity for a broad range of substrates, comparable to or higher than those of the most efficient symmetrical amine-derived monophosphoramidites reported thus far.

Highly enantioselective hydrogenation of α-dehydroamino acids by rhodium complex with H8-MonoPhos

H8-MonoPhos, a new stable and easily prepared monodentate phosphoramidite ligand, has been synthesized from H8-BINOL. The ligand showed extremely highly enantioselectivity of higher than 99.9% e.e. in the asymmetric Rh-catalyzed hydr

Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation

A novel three hindered quadrant bisphosphine ligand has been synthesized. The ligand shows excellent enantioselectivities and reactivities for rhodium-catalyzed hydrogenations of various functionalized olefins.