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17888-62-9

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17888-62-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 17888-62-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,7,8,8 and 8 respectively; the second part has 2 digits, 6 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 17888-62:
(7*1)+(6*7)+(5*8)+(4*8)+(3*8)+(2*6)+(1*2)=159
159 % 10 = 9
So 17888-62-9 is a valid CAS Registry Number.

17888-62-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name hexoxy(trimethyl)silane

1.2 Other means of identification

Product number -
Other names hexyl trimethylsilyl ether

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:17888-62-9 SDS

17888-62-9Relevant articles and documents

Nickel-mediated hydrogenolysis of C-O bonds of aryl ethers: What is the source of the hydrogen?

Kelley, Paul,Lin, Sibo,Edouard, Guy,Day, Michael W.,Agapie, Theodor

, p. 5480 - 5483 (2012)

Mechanistic studies of the hydrogenolysis of aryl ethers by nickel were undertaken with (diphosphine)aryl methyl ethers. A Ni(0) complex containing Ni-arene interactions adjacent to the aryl-O bond was isolated. Heating led to aryl-O bond activation and generation of a nickel aryl methoxide complex. Formal β-H elimination from this species produced a nickel aryl hydride which can undergo reductive elimination in the presence of formaldehyde to generate a carbon monoxide adduct of Ni(0). The reported complexes map out a plausible mechanism of aryl ether hydrogenolysis catalyzed by nickel. Investigations of a previously reported catalytic system using isotopically labeled substrates are consistent with the mechanism proposed in the stoichiometric system, involving β-H elimination from a nickel alkoxide rather than cleavage of the Ni-O bond by H2.

Use of Silylated Formiates as Hydrosilane Equivalents

-

Paragraph 0514, (2021/09/26)

The present invention relates to a method for preparing organic compounds of formula (I) by reaction between a silylated formiate of formula (II) and an organic compound in the presence of a catalyst and optionally of an additive. The invention also relates to use of the method for preparing organic compounds of formula (I) for the preparation of reagents for fine chemistry and for heavy chemistry, as well as in the production of vitamins, pharmaceutical products, adhesives, acrylic fibres, synthetic leathers, and pesticides.

P2O5/SiO2 as an efficient and mild catalyst for trimethylsilylation of alcohols using hexamethyldisilazane

Eshghi, Hossein,Rahimizadeh, Mohammad,Ghadamyari, Zohreh,Shiri, Ali

, p. 1435 - 1439 (2013/02/22)

The protection of alcohols with hexamethyldisilazane (HMDS) in the presence of P2O5/SiO2 at very mild and ambient condition with short reaction times is accomplished in excellent yields. P 2O5/SiOsub

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