18370-11-1

Basic information

• Product Name: N-METHYL-P-TOLUAMIDE
• Synonyms: TIMTEC-BB SBB008263;N-METHYL-P-TOLUAMIDE;N,P-DIMETHYLBENZAMIDE;N,4-Dimethylbenzamide;Benzamide, N,4-dimethyl- (9CI);p-Dimethylbenzamide;N-Methyl-4-MethylbenzaMide, 97%;BenzaMide, N,4-diMethyl-
• CAS NO: 18370-11-1
• Molecular Formula: C₉H₁₁NO
• Molecular Weight: 149.19
• Product Categories: AMIDE
• Mol File: 18370-11-1.mol
• Article Data: 55

Chemical Properties

• Boiling Point: 293.2 °C at 760 mmHg
• Flash Point: 168.3 °C
• Appearance: /
• Density: 1.021 g/cm³
• Vapor Pressure: 0.00175mmHg at 25°C
• Refractive Index: 1.524
• CAS DataBase Reference: N-METHYL-P-TOLUAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N-METHYL-P-TOLUAMIDE(18370-11-1)
• EPA Substance Registry System: N-METHYL-P-TOLUAMIDE(18370-11-1)

Safety Data

• Hazardous Substances Data: 18370-11-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Canadian Journal of Chemistry, 64, p. 2010, 1986 DOI: 10.1139/v86-332

InChI:InChI=1/C9H11NO/c1-7-3-5-8(6-4-7)9(11)10-2/h3-6H,1-2H3,(H,10,11)

Upstream product

• 874-60-2 4-methyl-benzoyl chloride 
• 74-89-5 methylamine 
• 16155-60-5 5-phenyl-2-p-tolyloxazole 
• 17177-63-8 4-tolyl mesylate 
• 6638-79-5 N,O-dimethylhydroxylamine*hydrochloride 
• 13939-06-5 molybdenum hexacarbonyl 
• 123-39-7 N-Methylformamide 
• 106-38-7 para-bromotoluene 
• 593-51-1 methylamine hydrochloride 
• 99-94-5 p-Toluic acid 
• 62926-02-7 4-methyl-thiobenzoic acid methylamide 
• 36930-95-7 2,2,2-trichloro-1-(4-methylphenyl)ethanone 
• 68-12-2 N,N-dimethyl-formamide 
• 3235-02-7 p-methylbenzaldehyde oxime 

Downstream Products

• 85046-76-0 C₁₁H₁₀N₂O₃ 
• 329940-36-5 N-methyl-3-nitro-4-methylbenzamide 
• 97661-71-7 N-methyl-4-methyl-N-nitrobenzamide 
• 23754-45-2 4-(Methylaminocarbonyl)benzoic acid 
• 94-08-6 4-methylbenzoic acid ethyl ester 
• 530145-18-7 tert-butyl methyl(4-methylbenzoyl)carbamate 
• 1513867-21-4 N-methyl-N-methacryloyl-4-methylbenzamide 

Relevant articles and documents

Visible light-mediated synthesis of amides from carboxylic acids and amine-boranes

Here, a photocatalytic deoxygenative amidation protocol using readily available amine-boranes and carboxylic acids is described. This approach features mild conditions, moderate-to-good yields, easy scale-up, and up to 62 examples of functionalized amides with diverse substituents. The synthetic robustness of this method was also demonstrated by its application in the late-stage functionalization of several pharmaceutical molecules.

Assemblies of 1,4-Bis(diarylamino)naphthalenes and Aromatic Amphiphiles: Highly Reducing Photoredox Catalysis in Water

Host-guest assemblies of a designed 1,4-bis(diarylamino)naphthalene and V-shaped aromatic amphiphiles consisting of two pentamethylbenzene moieties bridged by an m -phenylene unit bearing two hydrophilic side chains emerged as highly reducing photoredox catalysis systems in water. An efficient demethoxylative hydrogen transfer of Weinreb amides has been developed. The present supramolecular strategy permits facile tuning of visible-light photoredox catalysis in water.