18523-34-7Relevant articles and documents
Reduction and carbonylation of gem-dihalogeno cyclopropanes with iron pentacarbonyl
Reyne, F.,Brun, P.,Waegell, B.
, p. 4597 - 4600 (1990)
Reductive carbonylation of a gem-dibromo cyclopropane to carbomethoxycyclopropane can be achieved with excess Fe(CO)5 in DMF and an added nucleophile such as MeOH or MeONa.
Reductive Carbonylation of gem-Dihalogenocyclopropanes by Pentacarbonyliron(0) in the Presence of Sodium Methoxide
Reyne, Francoise,Waegell, Bernard,Brun, Pierre
, p. 1162 - 1167 (2007/10/02)
The reaction of gem-dihalogenocyclopropanes derivatives with (tetracarbonyl)(methoxycarbonylato)ferrate(I-) has been investigated; gem-dibromocyclopropanes and gem-chlorobromocyclopropane derivatives are reduced and carbonylated.It could be shown that a bromo ester such as methyl 1-bromo-2-phenylcyclopropanecarboxylate is an intermediate in the transformation of 1,1-dibromo-2-phenylcyclopropane into methyl cis- and trans-2-phenylcyclopropanecarboxylates and dimethyl 2-phenyl-1,1-cyclopropanedicarboxylate.
PRODUCTION OF 2-PHENYL-1-CYCLOPROPANONE ACETALS FROM 2,2-DIBROMO-1-PHENYLCYCLOPROPANE
Varakin, G. S.,Kostikov, R. R.,Ogloblin, K. A.
, p. 1569 - 1570 (2007/10/02)
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