2360-04-5Relevant articles and documents
HYDROGEN BOND IN SOME PHOSPHORUS-SUBSTITUTED ALIPHATIC ALCOHOLS
Bondarenko, N. A.,Matrosov, E. I.,Tsvetkov, E. N.,Kabachnik, M. I.
, p. 92 - 98 (1980)
-
Self-immolative systems for the disclosure of reactive electrophilic alkylating agents
Acton, Aaron L.,Leroux, Flavien,Feula, Antonio,Melia, Kelly,Sambrook, Mark R.,Hayes, Wayne,Russell, Andrew T.
supporting information, p. 5219 - 5222 (2019/05/07)
In this paper we report the design, synthesis and assessment of the first examples of self-immolative systems triggered by non-acidic electrophilic agents such as methyl, allyl or benzylic halides. These systems provide a visual colorimetric disclosure response upon exposure to these electrophilic reagents under mild, basic conditions without the need for the use of analytical instrumentation.
Synthese und Charakterisierung von Hydridotrispyrazolylborat-Heterobimetall-Komplexen mit Titan und Molybdaen
Ipaktschi, Junes,Sulzbach, Werner
, p. 287 - 302 (2007/10/02)
The reaction of TiCl4 with (C6H5)2P(CH2CH2O)nH (2) and K*)3BH> affords the complexes Tp*TiCl2(OCH2CH2)nP(C6H5)2 (n = 1-3) (3), Tp*TiCl2 (n = 1-3) (4) and Tp*Ti3 (n = 1-3) (5) which are then converted into the heterobinuclear complexes 8 and 9.Similarly, we succeeded in the synthesis of the heterobimetallacycles Tp*TiCl2Mo(CO)4 (13) and Tp*TiCl2Mo(CO)4 (14) by the use of (CO)4Mo2 (10) and (CO)4Mo2 (n = 1-2) (11).The shortest distance between Ti and Mo according to the crystal structure analysis is 5.393 Angstroem.