2477-39-6Relevant articles and documents
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Bailley,West
, p. 430,436 (1965)
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A Simple Synthesis pf Primary Amines via their N,N-Bis(trimethylsilyl) Derivatives
Bestmann, Hans Juergen,Woelfel, Gerhard
, p. 1250 - 1254 (2007/10/02)
Primary halogen compounds 1 or the corresponding tosylates react with sodium bis(trimethylsilyl)amide (2) in hexamethyldisilazane to form N,N-bis(trimethylsilyl)amines 3, which are converted into the amine hydrochlorides 5 by treatment with aqueous HCl.
Method of preparing silicon-nitrogen compounds
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, (2008/06/13)
A process for preparing a silicon-nitrogen compound of the formula (R3 Si)n NR'3-n or R2 Si(NR'2)2 or RSi(NR'2)3 or cyclic --R2 SiNR'--x wherein n is 1 or 2 or 3, R' is a hydrogen atom or an alkyl moiety of 1 to 8 carbon atoms or aryl moiety, R represents an alkyl moiety of 1 to 20 carbon atoms or aryl moiety and x is 3 or 4, by contacting a hydrogen silane of the formula R4-y SiHy where y is 1 or 2 or 3 and R has the above-described meaning with an ammonia or an amine of the formula NR'3-n Hn' where R' and n have the above meanings in the presence of a catalyst.