2477-39-6

Upstream product

• 917-64-6 methyl magnesium iodide 
• 88211-44-3 N-(methoxymethyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine 
• 75-16-1 methylmagnesium bromide 
• 88211-45-4 2-Hexyloxymethyl-1,1,1,3,3,3-hexamethyl-disilazane 
• 1070-89-9 sodium hexamethyldisilazane 
• 75-03-6 ethyl iodide 
• 80-40-0 ethyl ester of p-toluenesulfonic acid 
• 993-07-7 trimethylsilan 
• 75-04-7 ethylamine 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 51907-88-1 1,3-Diethyl-2,2,4,4-tetrafluoro-2,4-diphenyl-2λ⁵,4λ⁵-[1,3,2,4]diazadiphosphetidine 
• 107-46-0 Hexamethyldisiloxane 
• 557-66-4 ethanamine hydrochloride 
• 420-56-4 trimethylsilyl fluoride 
• 35380-27-9 FB{N(Si(CH₃)3)2}{NC₂H₅Si(CH₃)3} 
• 16029-98-4 trimethylsilyl iodide 
• 23138-72-9 N-trimethylsilyle du N-ethylacetamide 
• 23728-69-0 N-ethyl-N-trimethylsilylbenzamide 

Relevant academic research and scientific papers

Silylated Amines II. A New, Highly Variable Amine Synthesis by the N,N-Bis(trimethylsilyl)aminomethylation of Grignard Compounds

Sodium bis(trimethylsilyl)amide reacts with chloromethyl methylether (1) to form methoxy-N,N-bis(trimethylsilyl)aminomethane (3), which effects the aminomethylation of Grignard compounds 4 to form N,N-bis(trimethylsilyl)amines 5.

A Simple Synthesis pf Primary Amines via their N,N-Bis(trimethylsilyl) Derivatives

Primary halogen compounds 1 or the corresponding tosylates react with sodium bis(trimethylsilyl)amide (2) in hexamethyldisilazane to form N,N-bis(trimethylsilyl)amines 3, which are converted into the amine hydrochlorides 5 by treatment with aqueous HCl.

Method of preparing silicon-nitrogen compounds

A process for preparing a silicon-nitrogen compound of the formula (R3 Si)n NR'3-n or R2 Si(NR'2)2 or RSi(NR'2)3 or cyclic --R2 SiNR'--x wherein n is 1 or 2 or 3, R' is a hydrogen atom or an alkyl moiety of 1 to 8 carbon atoms or aryl moiety, R represents an alkyl moiety of 1 to 20 carbon atoms or aryl moiety and x is 3 or 4, by contacting a hydrogen silane of the formula R4-y SiHy where y is 1 or 2 or 3 and R has the above-described meaning with an ammonia or an amine of the formula NR'3-n Hn' where R' and n have the above meanings in the presence of a catalyst.