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2974-92-7

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2974-92-7 Usage

Uses

3,4-Dichlorobiphenyl is a polychlorinated biphenyl (PCB) congeners.

Check Digit Verification of cas no

The CAS Registry Mumber 2974-92-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,9,7 and 4 respectively; the second part has 2 digits, 9 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 2974-92:
(6*2)+(5*9)+(4*7)+(3*4)+(2*9)+(1*2)=117
117 % 10 = 7
So 2974-92-7 is a valid CAS Registry Number.
InChI:InChI=1/C12H8Cl2/c13-11-7-6-10(8-12(11)14)9-4-2-1-3-5-9/h1-8H

2974-92-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,2-dichloro-4-phenylbenzene

1.2 Other means of identification

Product number -
Other names 4-phenyl-1,2-dichlorobenzene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2974-92-7 SDS

2974-92-7Relevant articles and documents

Phototransformations of polychlorobiphenyls in brij 58 micellar solutions

Chu, Wei,Jafvert, Chad T.,Diehl, Claude A.,Marley, Karen,Larson, Richard A.

, p. 1989 - 1993 (1998)

Our purpose in conducting these studies was to examine photolysis as a destructive process for polychlorobiphenyls (PCBs) extracted from soils with surfactant solutions. Surfactants have shown promise as agents for removing free phase and sorbed contaminants from soils, yet information on ultimate disposal options and recycle/recovery strategies for the surfactants is generally lacking. For arylhalides, photodechlorination may result in decontamination, eliminating the need to physically separate these contaminants from the washing solution. Photochemical reactions of the PCB congener mixture, Aroclor 1254, and the specific congener, 2,3,4,5- tetrachlorobiphenyl (2,3,4,5-TeCB), were investigated in aqueous solutions containing surfactant micelles with UV light at 253.7 nm. Photoreduction through photodechlorination was shown to be the main decay pathway in which lesser chlorinated congeners were formed as intermediates. In experiments with 2,3,4,5-TeCB, final noncarbon-containing products included Cl- and H+, both produced nearly stoichiometrically from the starting materials. The quantum yield for decay of 0.1 μM 2,3,4,5-TeCB in 0.5 mM Brij 58 micellar solutions was over six times greater than in water alone. Sequential extraction from a soil and photoreduction of 2,3,4,5-tetrachlorobiphenyl by Brij 58 solutions proved to be limited by surfactant loss to the soil. Our purpose in conducting these studies was to examine photolysis as a destructive process for polychlorobiphenyls (PCBs) extracted from soils with surfactant solutions. Surfactants have shown promise as agents for removing free phase and sorbed contaminants from soils, yet information on ultimate disposal options and recycle/recovery strategies for the surfactants is generally lacking. For arylhalides, photodechlorination may result in decontamination, eliminating the need to physically separate these contaminants from the washing solution. Photochemical reactions of the PCB congener mixture, Aroclor 1254, and the specific congener, 2,3,4,5-tetrachlorobiphenyl (2,3,4,5-TeCB), were investigated in aqueous solutions containing surfactant micelles with UV light at 253.7 nm. Photoreduction through photodechlorination was shown to be the main decay pathway in which lesser chlorinated congeners were formed as intermediates. In experiments with 2,3,4,5-TeCB, final noncarbon-containing products included Cl- and H+, both produced nearly stoichiometrically from the starting materials. The quantum yield for decay of 0.1 μM 2,3,4,5-TeCB in 0.5 mM Brij 58 micellar solutions was over six times greater than in water alone. Sequential extraction from a soil and photoreduction of 2,3,4,5-tetrachlorobiphenyl by Brij 58 solutions proved to be limited by surfactant loss to the soil.

Iron(III)-Catalyzed Ortho-Preferred Radical Nucleophilic Alkylation of Electron-Deficient Arenes

Yu, Fei,Wang, Ting,Zhou, Huan,Li, Yajun,Zhang, Xinhao,Bao, Hongli

supporting information, p. 6538 - 6541 (2017/12/26)

The untraditional iron-catalyzed, ortho-preferred, radical alkylation of electron-deficient (hetero)arenes is reported. A variety of electron-deficient arenes were shown to react with various primary alkyl sources, producing the alkylated (hetero)arenes in good yields. This reaction might be an alkyl radical, nucleophilic aromatic substitution reaction, rather than the traditional electrophilic Friedel-Crafts reaction. HOMO-LUMO analysis and DFT studies on the key transition states underlying the regioselectivity are consistent with the observed reactions and the conclusions.

Hydrogenolysis of polychlorinated biphenyls by sodium borohydride with homogeneous and heterogeneous nickel catalysts

Roth,Dakoji,Hughes,Carmody

, p. 80 - 87 (2007/10/03)

The hydrogenolysis (hydrodechlorination) of a series of pure PCB congeners with sodium borohydride was studied. In the absence of nickel compounds, very little reaction occurred, but in the presence of solid Raney-type nickel or in the presence of a soluble Ni(0)triphenylphosphine complex, extensive hydrogenolysis occurred at ambient temperatures in DMF. The selectivity of one congener versus another was studied and found to be low. The selectivity for 2-, 3-, and 4-chloro displacement from di- and trichlorobiphenyls in the presence of Ni(0) complexes, however, was found to be high. The selectivities are interpreted with respect to the known mechanism of oxidative addition of aryl halides with Ni(0) complexes.

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