32093-01-9

Basic information

• Product Name: Benzene, [[(2-phenylethenyl)sulfonyl]methyl]-, (E)-
• CAS NO: 32093-01-9
• Molecular Formula: C15H14O2S
• Molecular Weight: 258.341
• Mol File: 32093-01-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, [[(2-phenylethenyl)sulfonyl]methyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[(2-phenylethenyl)sulfonyl]methyl]-, (E)-(32093-01-9)
• EPA Substance Registry System: Benzene, [[(2-phenylethenyl)sulfonyl]methyl]-, (E)-(32093-01-9)

Safety Data

• Hazardous Substances Data: 32093-01-9(Hazardous Substances Data)

Upstream product

• 51793-64-7 sodium α-toluenesulfinate 
• 122-78-1 phenylacetaldehyde 
• 100-39-0 benzyl bromide 
• 100-53-8 phenylmethanethiol 
• 536-74-3 phenylacetylene 
• 52147-97-4 trans 2-phenylethenesulfonyl chloride 
• 100-42-5 styrene 
• 1939-99-7 benzenesulfonyl chloride 
• 96-09-3 styrene oxide 
• 838-67-5 2-benzylsulfanyl-1-phenylethan-1-ol 
• 100-52-7 benzaldehyde 
• 203664-74-8 diethyl benzylsulfonylmethylphosphonate 
• 86317-56-8 (E)-styryl benzyl sulfide 
• 100-44-7 benzyl chloride 

Downstream Products

• 1097725-25-1 methyl 4-phenylmethanesulfonyl-3-phenylbutyrate 
• 190841-33-9 (1E)-3-((E)-1,3-diphenylallyloxy)-1,3-diphenylprop-1-ene 
• 131252-66-9 2.4-Diphenylbut-2-en-4-ol 
• 1083-30-3 dihydrochalcone 
• 4663-33-6 1,3-diphenyl-3-hydroxypropene 
• 90059-27-1 C₁₆H₁₆O₂S 

Relevant articles and documents

Gram-scale synthesis of β-sulfonyl styrenes

A simple and gram-scale synthesis of β-sulfonyl styrenes has been developed starting from one-pot PPA (polyphosphoric acid)-catalyzed 1,1-diacetoxylation of arylacetaldehydes (ArCH2CHO) with acetic anhydride (Ac2O) followed by deacetoxylative sulfonylation of the resulting 1,1-diacetate intermediate with sodium sulfinates (RSO2Na) in good yields under solvent-free conditions.

The epoxy-Ramberg-Baecklund reaction (ERBR): A sulfone-based method for the synthesis of allylic alcohols

The epoxy-Ramberg-Baecklund reaction (ERBR) is outlined, in which α,β-epoxy sulfones are converted into a range of mono-, di- and tri-substituted allylic alcohols, on treatment with base. Modification of this method enabled the preparation of enantio-enriched allylic alcohols following the diastereoselective epoxidation of enantio-enriched vinyl sulfones that were accessed efficiently from the chiral pool. The scope, optimisation and limitations of the ERBR as a method for the preparation of allylic alcohols are discussed. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.

A NEW ROUTE FOR THE SYNTHESIS OF STYRYLBENZYLSULFONES, PRECURSORS OF 1-BENZYLSULFONYL-2-ARYLCYCLOPROPANES

A novel method for the synthesis of E-styrylbenzylsulfones from E-sodium styrylsulfinates and benzyl chlorides has been described.The cyclopropanation of these compounds with dimethylsulfonium methylide gave E-1-benzylsulfonyl-2-arylcyclopropanes in good