3239-71-2Relevant academic research and scientific papers
Anodic cyanation of β-dicarbonyl compounds
Okimoto, Mitsuhiro,Numata, Kaori,Takahashi, Yukio,Hoshi, Masayuki,Tomozawa, Kenta,Shigemoto, Takamasa
, p. 2507 - 2509 (2005)
Several β-dicarbonyl compounds were electrochemically oxidized in a methanolic solution in the presence of sodium cyanide and sodium methoxide to yield the corresponding α-cyano-β-dicarbonyl compounds in moderate to good yields. Presumably, a two-electron
One-pot synthesis of benzoylacetonitriles through sequential Pd-catalyzed carbonylation and decarboxylation
Lee, Sunwoo,Kim, Han-Sung,Min, Hongkeun,Pyo, Ayoung
, p. 239 - 242 (2015/12/31)
Benzoylacetonitrile were prepared through sequential carbonylation and decarboxylation. The palladium-catalyzed carbonylation of aryl iodides and methyl cyanoacetate using Mo(CO)6 as a carbon monoxide source afforded beta-keto cyanoesters, and then the subsequent reaction with Li/H2O produced the desired benzoylacetonitriles.
Synthesis of 2-Alkoxy-6-aryl-5-cyano-4(3H)-pyrimidinones
Perez, Miguel A.,Soto, Jose L.
, p. 177 - 179 (2007/10/02)
The reaction of methyl 3-aryl-2-cyano-3-methoxypropenoates 1 with cyanamide and sodium methoxide in methanol afforded after acid hydrolysis the methyl 3--3-aryl-2-cyanopropenoates 4.By performing the reaction in higher boiling alcoho
