32768-54-0Relevant articles and documents
H β molecular sieve catalytic O-chlorotoluene preparation 2, 6 - dichloro toluene method (by machine translation)
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Paragraph 0026; 0028-0031, (2017/08/26)
The invention relates to 2, 6 - dichloro toluene preparation technology field, in particular to a molecular sieve catalyst H β of O-toluene selective chlorination of preparation 2, 6 - dichloro toluene. The invention relates to a low cost of O-toluene as the raw materials, chlorine is the chlorinating agent, H β molecular sieve as the catalyst, adopt the one-step chlorination process, catalytic O-toluene selective chlorination of preparation 2, 6 - dichloro toluene, the process is easy to operate, simple steps, low production cost, easy industrialization. (by machine translation)
Synthesis of Triptycene-Based Molecular Rotors for Langmuir-Blodgett Monolayers
Kaleta, Ji?í,Kaletová, Eva,Císa?ová, Ivana,Teat, Simon J.,Michl, Josef
, p. 10134 - 10150 (2015/11/03)
We describe syntheses of six triptycene-containing molecular rotors with several single-crystal X-ray diffraction analyses. These rod-shaped molecules carrying an axial rotator are designed to interleave on an aqueous surface into Langmuir-Blodgett (LB) monolayers containing a two-dimensional trigonal array of dipoles rotatable about an axis normal to the surface. Monolayer formation was verified with the simplest of the rotor structures. On an aqueous subphase containing divalent cations (Mg2+, Ca2+, Zn2+, Sr2+, or Cd2+), the LB isotherm yielded an area of 53 ± 3 ?2/molecule (monolayer of type A), compatible with the anticipated triangular packing of axes normal to the surface. On pure water, the area is 30 ± 3 ?2/molecule, and it is proposed that in this monolayer (type B), the molecular axes are tilted by 40-45° to a structure similar to those observed in single crystals of related triptycenes. After transfer to a gold surface, ellipsometry and PM IRRAS yield tilt angles of 29 ± 4° (monolayers of type A) and 38 ± 4° (type B). A full-scale examination of monolayers from all the rotors on a subphase and after transfer is underway and will be reported separately.