tris(4-methoxyphenyl)bismuth

Base Information

• Chemical Name: tris(4-methoxyphenyl)bismuth
• CAS No.: 33397-21-6
• Molecular Formula: C₂₁H₂₁BiO₃
• Molecular Weight: 530.376
• Mol file: 33397-21-6.mol

Synonyms:tris(4-methoxyphenyl)bismuth

Chemical Property of tris(4-methoxyphenyl)bismuth

Chemical Property:

Purity/Quality:

98%,99%, ^*data from raw suppliers

TRIS(4-METHOXYPHENYL)BISMUTHINE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tris(4-methoxyphenyl)bismuth

There total 15 articles about tris(4-methoxyphenyl)bismuth which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

(4-methoxybenzoylseleno)bis(4-methylphenyl)bismuth → bismuth (7440-69-9) + tris(4-methoxyphenyl)bismuth (33397-21-6)

Guidance literature:

In neat (no solvent); byproducts: Se-(4-CH3C6H4)-4-methoxybenzenecarboselenoate; Bi-compound under N2 in an ampoule was heated at 150°C for 2 h; ppt. was filtered (Bi), washed with diethyl ether and CH2Cl2, evapd., column chromy. on silica gel (hexane-diethyl ether);

DOI:10.1002/hlca.200690070

Reference yield: 18.0%

bismuth (7440-69-9) + bismuth(III) chloride (7787-60-2) + 4,4'-dimethoxy-diphenyliodonium chloride (50619-99-3) → tris(4-methoxyphenyl)bismuth (33397-21-6)

Guidance literature:

In acetone; 2 h;

Reference yield: 10.0%

bismuth(III) chloride (7787-60-2) + 4-methoxyphenyl magnesium bromide (13139-86-1) → tris(4-methoxyphenyl)bismuth (33397-21-6)

Guidance literature:

In diethyl ether; cooling; treatment with H2O, extraction with CHCl3;

upstream raw materials:

1-bromo-4-methoxy-benzene

4-methoxyphenyl magnesium bromide

ethanol

bismuth(III) chloride

Downstream raw materials:

4,4'-Dimethoxybiphenyl

3,4-dimethylphenyl-4'-methoxyphenylamine

phenyl(p-methoxyphenyl)telluride

bis(4-methoxyphenyl)ditelluride