33421-39-5Relevant articles and documents
Organic electrophosphorescent material, preparation method, and OLED device containing the same (by machine translation)
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Paragraph 0064-0069, (2020/04/02)
Is an organic electro-phosphorescent material, a preparation method OLED thereof, and an organic electrophosphorescent material comprising the compound. of Formula I, or Formula II, wherein the compound of Formula III is a red light-emitting material. and the compound of Formula I is a red light-emitting material, of the present invention. II. The organic electrophosphorescent material of the present invention is easily sublimated and dissolved III for mass production . The present invention provides an organic electrophosphorescent material having a structure represented by the following formula: OLED. The organic electrophosphorescent material of the present invention is advantageous; in terms of efficiency. OLED. (by machine translation)
A sustainable heterogenized palladium catalyst for Suzuki-Miyaura cross coupling reaction of azaheteroaryl halides in aqueous media
Ganesamoorthy,Muthu Tamizh,Shanmugasundaram,Karvembu
, p. 76 - 85 (2018/03/23)
A unique recyclable Pd catalyst (‘SiO2’-NH2-Pd) for Suzuki-Miyaura coupling reaction of azaheteroaryl halides is developed. The catalytic system is working under mild aqueous condition with low Pd loading and without the use of phosphine ligand. The plausible mechanism is proposed based on the formation of undesired symmetrical biaryl from the coupling reaction of azaheteroaryl chlorides due to the oxidative homocoupling of nucleophilic arylboronic acid. This catalytic system represents an attractive and promising approach for the synthesis of azaheterobiaryls with high product yields. The catalyst has demonstrated an excellent recyclability.
Aza-spirobifluorene derivative and preparation method thereof
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Paragraph 0087-0089, (2017/08/18)
The invention discloses an aza-spirobifluorene derivative. The aza-spirobifluorene derivative is characterized by having a structural formula as shown in the specification, wherein only one of X1, X2, X3 and X4 is a nitrogen atom, and the other three are carbon atoms; and R is an aromatic or heterocyclic aromatic ring containing 6-60 carbon atoms. The aza-spirobifluorene derivative disclosed by the invention can be used as an illuminant material; the aza-spirobifluorene derivative can be independently used as an illuminating layer or doped dye for illuminating or can be formed into an exciplex with the other materials for illuminating; the aza-spirobifluorene derivative also has a carrier transporting capacity; and a group has a hole transmitting capacity and an electron transmitting capacity. The aza-spirobifluorene derivative provided by the invention can be prepared into an excellent amorphous film according to vacuum evaporation or solution methods (spin coating, printing, and the like). The aza-spirobifluorene derivative also has higher thermal stability and photo-stability.