3459-80-1

Basic information

• Product Name: Benzyln-butylether
• Synonyms: (tert-Butoxymethyl)benzene;Benzyl tert-butyl ether;tert-Butyl benzyl ether
• CAS NO: 3459-80-1
• Molecular Formula: C₁₁H₁₆O
• Molecular Weight: 164.24
• Mol File: 3459-80-1.mol
• Article Data: 48

Chemical Properties

• Boiling Point: 204.1°C at 760 mmHg
• Flash Point: 75.1°C
• Appearance: /
• Density: 0.921g/cm³
• Vapor Pressure: 0.383mmHg at 25°C
• Refractive Index: 1.488
• CAS DataBase Reference: Benzyln-butylether(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyln-butylether(3459-80-1)
• EPA Substance Registry System: Benzyln-butylether(3459-80-1)

Safety Data

• Hazardous Substances Data: 3459-80-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Chemistry Letters, 17, p. 229, 1988The Journal of Organic Chemistry, 43, p. 447, 1978 DOI: 10.1021/jo00397a015Tetrahedron Letters, 29, p. 2483, 1988 DOI: 10.1016/S0040-4039(00)87913-7

InChI:InChI=1/C11H16O/c1-11(2,3)12-9-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3

Upstream product

• 115-11-7 isobutene 
• 100-51-6 benzyl alcohol 
• 67-56-1 methanol 
• 908094-04-2 phenyldiazomethane 
• 75-65-0 tert-butyl alcohol 
• 13058-24-7 tert-butoxytrimethylsilane 
• 100-52-7 benzaldehyde 
• 620-05-3 iodomethylbenzene 
• 507-19-7 t-butyl bromide 
• 100-44-7 benzyl chloride 
• 1000-63-1 n-butyl tert-butyl ether 
• 24424-99-5 di-tert-butyl dicarbonate 
• 865-47-4 potassium tert-butylate 
• 1634-04-4 tert-butyl methyl ether 

Downstream Products

• 507-20-0 tertiary butyl chloride 
• 100-44-7 benzyl chloride 
• 75-65-0 tert-butyl alcohol 
• 1022-45-3 2-phenyl-4(3H)-quinazolinone 
• 1629-75-0 2-benzoylbenzothiazole 
• 28458-93-7 benzo[d]oxazol-2-yl(phenyl)methanone 
• 33074-70-3 3-phenylquinoxaline-2-carbonitrile 1,4-dioxide 
• 59393-45-2 3-phenyl-2-quinoxalinecarbonitrile 
• 58585-84-5 1,3-dioxoisoindolin-2-yl benzoate 
• 20773-06-2 C₁₁H₁₅LiO 
• 774-65-2 benzoic acid tert-butyl ester 
• 1384603-93-3 tert-butyl (tert-butylperoxy)(phenyl)methyl ether 
• 100-52-7 benzaldehyde 
• 101-81-5 Diphenylmethane 

Relevant articles and documents

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Electrophilic Substitution in Pyrroles. Part 4. Hydrogen Exchange in Acid Solution

Hydrogen exchange at the unsubstituted positions in 1,2,5-trimethyl- and 1,3,4-trimethyl-pyrrole in aqueous buffer has been examined.The two positions were found to be of similar reactivities.General acid catalysis was detected.No hydrogen exchange on the methyl groups of 2,3,4,5-tetramethylpyrrole, even in strong acid, was detected.The 13C n.m.r. spectrum of the tetramethylpyrrole was examined.

Hydrosilylation of carbonyl and carboxyl groups catalysed by Mn(i) complexes bearing triazole ligands

Manganese(i) complexes bearing triazole ligands are reported as catalysts for the hydrosilylation of carbonyl and carboxyl compounds. The desired reaction proceeds readily at 80 °C within 3 hours at catalyst loadings as low as 0.25 to 1 mol%. Hence, good to excellent yields of alcohols could be obtained for a wide range of substrates including ketones, esters, and carboxylic acids illustrating the versatility of the metal/ligand combination.

Synthesis of Benzyl Alkyl Ethers by Intermolecular Dehydration of Benzyl Alcohol with Aliphatic Alcohols under the Effect of Copper Containing Catalysts

Synthesis of benzyl alkyl ethers was performed in high yields by intermolecular dehydration of benzyl and primary, secondary, tertiary alcohols under the effect of copper containing catalysts. The formation of benzyl alkyl ethers occurs with participation of benzyl cation.