3582-84-1Relevant articles and documents
Hydrophosphinylation of Styrenes Catalysed by Well-Defined s-Block Bimetallics
Borys, Andryj M.,Hevia, Eva,Platten, Andrew W. J.
, (2022/02/01)
Advancing the applications of s-block heterobimetallic complexes in catalysis, we report the use of potassium magnesiate (PMDETA)2K2Mg(CH2SiMe3)4 [PMDETA=N,N,N’,N’,N’’-pentamethyldiethylenetriamine] f
Potassium tert -Butoxide Mediated Reductive C-P Cross-Coupling of Arylvinyl Sulfides through C-S Bond Cleavage
Feng, Jie,Zhang, Qiaoling,Li, Fuhai,Yang, Lu,Kuchukulla, Ratnakar Reddy,Zeng, Qingle
, p. 224 - 228 (2020/10/30)
A transition-metal-free t -BuOK-mediated reductive C-P cross-coupling reaction of arylvinyl sulfides with diarylphosphine oxides through C-S bond cleavage has been developed. This protocol not only permits the synthesis of diaryl(2-arylethyl)phosphine oxides, but also achieves an unprecedented construction of a C-P bond through C-S bond cleavage and reduction of a C-C double bond in one pot.
Lanthanum-Catalyzed Regioselective Anti-Markovnikov Hydrophosphinylation of Styrenes
Rina, Yesmin Akter,Schmidt, Joseph A. R.
, p. 4261 - 4270 (2019/10/28)
A useful and convenient method for sp3 C-P(O) bond formation via direct regioselective hydrophosphinylation of simple and readily available alkenes using a lanthanum-based N,N-dimethylbenzylamine complex (La(DMBA)3) as a precatalyst is demonstrated. The reaction proceeds with perfect atom economy for a wide range of styrenes with secondary phosphine oxides, giving moderate to excellent yields.