3592-25-4Relevant articles and documents
The preparation and structures of several cross-conjugated allenes ("allenic dendralenes")
Lehrich, Friedhelm,Hopf, Henning,Grunenberg, Joerg
scheme or table, p. 2705 - 2718 (2011/06/25)
The cross-conjugated allenes ("allenic dendralenes") 2-allenylbuta-1,3-diene (2), 1,1-divinylallene (3, prepared here as the methyl derivative 49), and 1,1-diallenylethene (4) are prepared either by S N2′-substitution processes from appropriate allenic or acetylenic precursors or by base-catalyzed isomerizations of propargylic substrates. Thermal elimination/isomerization routes to these highly unsaturated hydrocarbons require reaction conditions under which these allenes undergo secondary transformations. The new oligoolefins, the structures of which have been calculated by MP2 methods, are interesting substrates for addition and isomerization reactions. The phenomenon of cross-conjugation is extended to allenes; the resulting oligoolefins are predicted to become useful dienes for multiple-Diels-Alder additions allowing the rapid construction of complex carbon frameworks.
Novel double para-phenylenediamines joined by a linker arm substituted with at least one group chosen from hydroxyl, alkoxy, and/or amino groups and method of dyeing keratinous fibers
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Page/Page column 9, (2008/06/13)
Disclosed herein is a novel family of double para-phenylenediamines joined by a linker arm comprising at least one substituent chosen from hydroxyl, alkoxy, and/or amino substituents. Also disclosed herein is a dyeing composition comprising, in a medium s
Large-scale synthesis of "Cpep" RNA monomers and their application in automated RNA synthesis
Pon,Yu,Prabhavalkar,Mishra,Kulkarni,Sanghvi
, p. 777 - 781 (2007/10/03)
Small interfering RNAs (siRNA) are the latest candidates for oligonucleotide-based therapeutics. Should siRNA be successful in clinical trials, a huge demand for synthetic RNA is anticipated. We believe that 1-(4-chlorophenyl)-4-ethoxypiperidin-4-yl (Cpep