37960-84-2

Basic information

• Product Name: BENZOIC-3,5-D2 ACID
• Synonyms: BENZOIC-3,5-D2 ACID;Benzoic--d2 Acid
• CAS NO: 37960-84-2
• Molecular Formula: C₇H₆O₂
• Molecular Weight: 124.133663556
• Mol File: 37960-84-2.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: BENZOIC-3,5-D2 ACID(CAS DataBase Reference)
• NIST Chemistry Reference: BENZOIC-3,5-D2 ACID(37960-84-2)
• EPA Substance Registry System: BENZOIC-3,5-D2 ACID(37960-84-2)

Safety Data

• Hazardous Substances Data: 37960-84-2(Hazardous Substances Data)

Usage

Uses

Benzoic-3,5-d2 Acid (CAS# 37960-84-2) is a useful isotopically labeled research compound.

Upstream product

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Downstream Products

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Relevant articles and documents

Aqueous Oxidations Started by TiO2 Photoinduced Holes Can Be a Rate-Determining Step

In aqueous TiO2 photocatalytic hydroxylation of weakly polar aromatics, a series of inverse H/D KIEs of 0.7–0.8 were observed, which is different than the normal H/D kinetic isotope effects (KIEs) usually observed for polar aromatics. This result indicated that the oxidation started by photo-induced hvb + can be the rate-determining step.

PREPARATION OF DEUTERIATED 1-PHENYLETHANOLS BY REDUCTIVE DEHALOGENATION OF THE CORRESPONDING HALOGENOACETOPHENONES WITH RANEY ALLOYS IN AN ALKALINE DEUTERIUM OXIDE SOLUTION

Deuteriated 1-phenylethanols were prepared by reductive dehalogenation of the corresponding halogenoacetophenones with Raney Ni-Al and Cu-Al alloys in 5percent NaOD-D2O solution.It was found that the Ni-Al alloy introduced greater than expected numbers of deuterium atoms in the phenyl ring, but the expected deuteriated 1-phenylethanols were obtained in high yield and in high isotopic purity when Raney Cu-Al alloy was used.

Preparation of All the Possible Ring-deuteriated Benzoic Acids by Reductive Dehalogenation of the Corresponding Halogenobenzoic Acids with Raney Alloys in an Alkaline Deuterium Oxide Solution

All the possible undeuteriated benzoic acids were prepared mainly by treatment of the corresponding bromobenzoic acid with Raney Cu-Al alloy in 10percent NaOD-D2O solution. 5>Benzoic acid was obtained from pentafluorobenzoic acid by a similar reaction.However, only 4>benzoic acid was prepared by decarboxylation of 4>phthalic acid.