4433-85-6Relevant academic research and scientific papers
SILVER β-KETOCARBOXYLATE, MATERIAL COMPRISING THE SAME FOR FORMING SILVER METAL, AND USE THEREOF
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Page/Page column 25-26, (2008/06/13)
A new material from which silver metal can be rapidly formed even at a temperature as low as about 210°C or below. The material for silver metal formation comprises a silver β-ketocarboxylate. Heating this forming material can rapidly form silver metal even at a temperature as low as about 210°C or below. Examples of the silver β-ketocarboxylate include silver isobutyrylacetate, silver benzoylacetate, silver acetoacetate, silver propionylacetate, silver α-methylacetoacetate, and silver α-ethylacetoacetate.
Synthesis of 1,3-dioxin-4-one Derivatives
Sato, Masayuki,Ogasawara, Hiromichi,Oi, Keiichi,Kato, Tetsuzo
, p. 1896 - 1901 (2007/10/02)
A facile and general synthesis of 2,2-dimethyl-1,3-dioxin-4-one derivatives (1) is reported.Treatment of β-keto acids with a mixture of isopropenyl acetate and conc. sulfuric acid gave 2,2-dimethyl-1,3-dioxin-4-ones (1).Similar treatment of tert-butyl esters of β-keto acids also gave 1.KEYWORDS - 2,2-dimethyl-1,3-dioxin-4-one derivative; diketene-acetone adduct; diketene; acylketene; β-keto acid; β-keto ester
