52708-37-9

Usage

Uses

4-(Carbazol-9-yl)aniline

Upstream product

• 86-74-8 9H-carbazole 
• 540-37-4 p-aminoiodobenzene 
• 17763-95-0 2,2'-bis-<<(trifluoromethyl)sulfonyl>oxy>biphenyl 
• 106-50-3 1,4-phenylenediamine 
• 1806-29-7 2,2'-dihydroxybiphenyl 
• 103-88-8 4-bromoacetanilide 
• 371-40-4 4-fluoroaniline 
• 13029-09-9 2,2'-dibromobiphenyl 
• 586-78-7 para-nitrophenyl bromide 
• 350-46-9 4-Fluoronitrobenzene 
• 100-00-5 4-chlorobenzonitrile 
• 98-95-3 nitrobenzene 
• 636-98-6 p-nitrobenzene iodide 
• 622-50-4 4-Acetamido-1-iodobenzene 

Downstream Products

• 859084-99-4 (4-carbazol-9-yl-phenyl)-(2-nitro-phenyl)-amine 
• 896452-73-6 N-(4-(9H-carbazol-9-yl)phenyl)-4-nitro-N-(4-nitrophenyl)aniline 
• 57103-15-8 9-(4-iodophenyl)carbazole 
• 896452-75-8 N¹-(4-(9H-carbazol-9-yl)phenyl)-N₁-(4-aminophenyl)benzene-1,4-diamine 
• 1217364-38-9 (S)-(+)-2-hydroxy-N-[4-(9-carbazolyl)phenyl]succinimide 
• 785051-54-9 9-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole 
• 1394130-73-4 9-{4-[2-(pyrrolidin-1-yl)diazen-1-yl]phenyl}-9H-carbazole 
• 1415476-91-3 2-(((4-(9H-carbazol-9-yl)phenyl)imino)methyl)phenol 
• 212385-56-3 4-(9H-carbazol-9-yl)-N,N-diphenylaniline 
• 1228784-79-9 [Au(C₆F₅)(9-(4-isocyanophenyl)carbazole)] 
• 1228784-77-7 9-(4-isocyanophenyl)carbazole 

Relevant academic research and scientific papers

Method for synthesizing carbazole derivative

The invention aims to provide a method for synthesizing a carbazole derivative. The method is characterized in that palladium chloride is used as a catalyst, 2, 2' - dibromobiphenyl is used as an electrophilic reagent, primary amine is taken as a nucleophile, and the carbazole derivative is directly cross-coupled under the conditions of toluene as a solvent and an air atmosphere. The method has the advantages of high yield, high selectivity, simplicity and convenience in operation and the like.

Phthalimide organic light-emitting material with aggregation-induced emission and linear force stimulation-light-emitting color change response and application thereof

The invention belongs to the technical field of organic light-emitting materials, and particularly discloses a class of phthalimide organic light-emitting materials with aggregation-induced emission and linear force stimulation-light-emitting color change

Fluorescent carbazole-containing dyes: Synthesis and supramolecular assembly by self-complementary donor-acceptor π-stacking and dipolar interactions

Six carbazole-based dyes were synthesized by fluorescence turn on amino-ene click reactions. Two high quality single-crystals of new dyes were prepared, and their X-ray diffraction structure analyses reveal the formation of antiparallel stacking superstructures driven by self-complementary dipole-dipole and π-stacking interactions between carbazole donors and acceptors. The optical behaviors and donor-acceptor interactions of these dyes were investigated by ultraviolet–visible absorption, fluorescence emission spectroscopy, and electrochemical cyclic voltammetry. Blue fluorescence appears and increases as dye-based supramolecular polymer grows, as revealed by dynamic light scattering, fluorescence, 1H NMR and 2D NMR spectroscopy.

Carbazole-perylenebisimide electron donor/acceptor dyads showing efficient spin orbit charge transfer intersystem crossing (SOCT-ISC) and photo-driven intermolecular electron transfer

Perylenebisimide-carbazole (PBI-Cz) dyads were prepared to study charge-recombination (CR) induced intersystem crossing (ISC) in electron donor/acceptor dyads. The distance and the mutual orientation of the perylenebisimide (PBI) and carbazole (Cz) moieties were varied to study their effect on photophysical properties. Steady state and time-resolved optical spectroscopies show that electronic coupling between the electron donor and acceptor is negligible at the ground state. The fluorescence of the PBI moiety is strongly quenched in the dyads, and a larger separation between the donor and the acceptor results in less fluorescence quenching. The Gibbs free energy changes of the electron transfer and the energy level of the charge transfer state were studied using the electrochemical and optical spectra data. The singlet oxygen quantum yields (ΦΔ) are up to 72% for dyads with the shortest separation between the donor and the acceptor. Nanosecond transient absorption spectra confirmed the formation of the PBI-localized long lived triplet state (the lifetime is up to 190 μs). Notably non-orthogonal dyads show efficient spin orbit charge transfer (SOCT-ISC), which is different from the previously proposed orthogonal molecular structure for SOCT-ISC. Time-resolved electron paramagnetic resonance (TREPR) spectroscopy shows that all three dyads give the same electron spin polarization of eae/aea, and thus the radical pair ISC (RP ISC) mechanism is excluded, which is different from the previously reported PBI-phenothiazine analogues. Efficient and reversible transformation of dyads to their radical anion was observed in the presence of sacrificial electron donor triethanolamine in an inert atmosphere with photo-irradiation.

Hole transport material based on anilino carbazole and application thereof

The invention discloses a hole transport material based on anilino carbazole. The hole transport material is a compound with a structure shown as a structural general formula (I). The compound can beused as the hole transport material, applied to a perovs

Preparation of various morphological films at nanoscale by phase separation method

A film consisting of nanopore and nanopillar structures was produced from a binary immiscible polymer solution of poly(amic acid) (PAA) and polyimide (PI), which can be used as a potential light extraction layer or flexible substrate in organic light-emit

Novel triphenylamine polyamides bearing carbazole and aniline substituents for multi-colored electrochromic applications

A novel carbazolyl-derived diamine containing triphenylamine, 4,4′-bis[(4-aminophenyl)amino]-4″-carbazolyltriphenylamine (VI), was prepared via the reduction of 4,4′-bis[(4-nitrophenyl)amino]-4″-carbazolyltriphenylamine. A series of novel polyamides (PAs,

Protonation-induced dual fluorescence of a blue fluorescent material with twisted A-π-D-π-A configuration

In this work, we introduced a blue fluorescent material with twisted A-π-D-π-A configuration, namely CzPA-F-PD. This compound exhibits remarkable dual fluorescence properties triggered by trifluoroacetic acid (TFA), resulting in blue and red emission peak

Triphenylamine/carbazole-modified ruthenium(ii) Schiff base compounds: Synthesis, biological activity and organelle targeting

Four triphenylamine/carbazole-modified half-sandwich ruthenium(ii) compounds [(η6-p-cymene)Ru(N/O^N)Cl]0/+ with Schiff base chelating ligands (N/O^N) are synthesized and characterized. The introduction of Schiff base units effectively increases the antitumor activity of these compounds (IC50: 1.70 ± 0.56-17.75 ± 3.10 μM), which, meanwhile, can inhibit the metastasis of tumor cells effectively. These compounds follow an energy-dependent cellular uptake mechanism, mainly accumulate in lysosomes to destroy their integrity, and then eventually promote apoptosis. In addition, these compounds can induce an increase of intracellular reactive oxygen species (ROS) levels and provide an antitumor mechanism of oxidation, which is confirmed by the decrease of mitochondrial membrane potential (MMP) and the catalytic oxidation of the coenzyme nicotinamide-adenine dinucleotide (NADH). All these indicate that these ruthenium(ii) compounds are expected to be dual-functional antitumor agents: anti-metastasis and lysosomal damage.

Base-promoted SNAR reactions of fluoro- And chloroarenes as a route to N-aryl indoles and carbazoles

KOH/DMSO-promoted C-N bond formation via nucleophilic aromatic substitution (SNAr) between chloroarenes or fluoroarenes with indoles and carbazole under transition metal-free conditions affording the corresponding N-arylated indoles and carbazoles has been developed.