55790-16-4

Basic information

• Product Name: METHYL 2-METHOXYCARBONYL-4-NITRO-3-PHENYLBUTANOATE
• Synonyms: METHYL 2-METHOXYCARBONYL-4-NITRO-3-PHENYLBUTANOATE
• CAS NO: 55790-16-4
• Molecular Formula: C₁₃H₁₅NO₆
• Molecular Weight: 281.26
• Mol File: 55790-16-4.mol
• Article Data: 35

Chemical Properties

• Boiling Point: 408.2°C at 760 mmHg
• Flash Point: 171.5°C
• Appearance: /
• Density: 1.246g/cm³
• Vapor Pressure: 7.1E-07mmHg at 25°C
• Refractive Index: 1.519
• CAS DataBase Reference: METHYL 2-METHOXYCARBONYL-4-NITRO-3-PHENYLBUTANOATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 2-METHOXYCARBONYL-4-NITRO-3-PHENYLBUTANOATE(55790-16-4)
• EPA Substance Registry System: METHYL 2-METHOXYCARBONYL-4-NITRO-3-PHENYLBUTANOATE(55790-16-4)

Safety Data

• Hazardous Substances Data: 55790-16-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H15NO6/c1-19-12(15)11(13(16)20-2)10(8-14(17)18)9-6-4-3-5-7-9/h3-7,10-11H,8H2,1-2H3

Upstream product

• 5153-67-3 nitrostyrene 
• 28868-76-0 2-chlorodimethylmalonate 
• 102-96-5 (2-nitroethenyl)benzene 
• 105-53-3 diethyl malonate 
• 100-52-7 benzaldehyde 
• 108-59-8 malonic acid dimethyl ester 
• 75-52-5 nitromethane 
• 67-56-1 methanol 
• 6626-84-2 dimethyl 2-benzylidenepropanedioate 
• 18424-76-5 dimethyl malonate sodium salt 

Downstream Products

• 4674-93-5 bromo-(2-nitro-1-phenyl-ethyl)-malonic acid dimethyl ester 
• 37178-51-1 1-Phenyl-2-nitro-3.3-dicarbomethoxy-cyclopropan 
• 947381-33-1 methyl 3-phenylindolizine-1-carboxylate 
• 55790-17-5 3-methoxycarbonyl-4-phenyl-2-pyrrolidone 
• 77519-55-2 2-oxo-4-phenylpyrrolidine-3-carboxylic acid 
• 71657-88-0 (4R)-4-phenyl-2-pyrrolidone 
• 62624-45-7 (S)-4-phenyl-1-tosylpyrrolidin-2-one 
• 635-51-8 2-phenylsuccinic acid 

Relevant articles and documents

Stereoselective, nitro-Mannich/lactamisation cascades for the direct synthesis of heavily decorated 5-nitropiperidin-2-ones and related heterocycles

A versatile nitro-Mannich/lactamisation cascade for the direct stereoselective synthesis of heavily decorated 5-nitropiperidin-2-ones and related heterocycles has been developed. A highly enantioenriched substituted 5-nitropiperidin-2-one was synthesised in a four component one-pot reaction combining an enantioselective organocatalytic Michael addition with the diastereoselective nitro- Mannich/lactamisation cascade. Protodenitration and chemoselective reductive manipulation of the heterocycles was used to install contiguous and fully substituted stereocentres in the synthesis of substituted piperidines.

Asymmetric synthesis of 3-prenyl-substituted pyrrolidin-2-ones

Pharmacology-relevant compounds bearing structural fragments of racetam nootropics, wound-healing acyclic isoprenoids and neurotropic GABA analogues, were enantioselectively (up to 94% ee) synthesized from available and inexpensive precursors.

Application of pentacoordinated spirophosphorane as a new organocatalyst for the Michael addition reaction

Pentacoordinated spirophosphorane as a simple, effective and novel organocatalyst for the Michael addition reaction has been investigated. The bisaminoacyl spirophosphorane that possessed a thiourea-like moiety and an amine group was applied to the Michae

Na+ Ions Induce the Pirouetting Motion and Catalytic Activity of [2]Rotaxanes

We have prepared [2]rotaxanes, the behavior of which as switchable catalysts depends on their pirouetting motion, which can be controlled through the addition and removal of Na+ ions. At least three sequential on/off cycles of a Michael reactio

A thiourea-functionalized metal-organic macrocycle for the catalysis of Michael additions and prominent size-selective effect

A discrete tetranuclear thiourea-based metal-organic macrocycle (MOM) with a large size was constructed by a well-designed organic ligand and nickel(ii) ions via self-assembly. Incorporating thiourea groups as hydrogen-bond donors into a metal-organic com