616-09-1Relevant articles and documents
METHOD FOR PREPARING ALKYL HYDROXYL ACID ESTER AND USE THEREOF
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Page/Page column 4; 5, (2021/09/17)
Provided is a method for preparing an alkyl hydroxyl acid ester, the product and use thereof. The method has advantages of high yield, not producing waste water, gas, or solid, low cost, and is green and environment friendly.
Method for preparing lactate by catalyzing pyruvic aldehyde
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Paragraph 0191; 0192; 0210, (2020/07/02)
The invention relates to a method for preparing lactate by catalyzing pyruvic aldehyde. The method comprises the following steps: contacting pyruvic aldehyde and alcohol with a catalyst in a reactor,and reacting to obtain a lactate-containing product, wherein the molar ratio of pyruvic aldehyde to alcohol is 1:(50-225), the reaction temperature is 30-180 DEG C, the reaction time is 1-10 h, the reaction pressure is 0.1-3 MPa, the catalyst contains a tin-titanium-silicon molecular sieve, and the weight ratio of pyruvic aldehyde to the tin-titanium-silicon molecular sieve based on dry basis weight is 1:(1-6). According to the method, the catalyst containing the binary tin-titanium-silicon molecular sieve is adopted, framework tin atoms and framework titanium atoms of the molecular sieve synergistically catalyze pyruvic aldehyde and alcohol to generate lactate, and the reaction efficiency is improved.
Preparation method and application of hydroxy acid alkyl ester
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Paragraph 0025-0027, (2020/06/16)
The invention relates to a preparation method of a green solvent hydroxy acid alkyl ester, which comprises the following steps: (1) an alkyl alcohol and a hydroxy acid methyl ester or an ethyl ester are mixed under normal pressure or micro-positive pressure in the presence of a catalyst and reacted at the temperature of 50-200 DEG C, and the molar ratio of alkyl alcohol to the hydroxy acid methylester or ethyl ester is greater than 1; (2) at the temperature of 135-170 DEG C, a product methanol or ethanol is fractionated for the first time, and the top temperature of a fractionating column isthe boiling point temperature of methanol or ethanol; (3) atmospheric pressure or reduced pressure distillation is carried out for the second time to obtain redundant reactants alkyl alcohol and unreacted hydroxy acid methyl ester or ethyl ester, and the distillation temperature is controlled to be the boiling point temperature of the alkyl alcohol and the hydroxy acid methyl ester or ethyl ester;and (4) the remaining product hydroxy acid alkyl ester is collected. The method has the advantages of high yield, no generation of any three wastes, low production cost, greenness and environmental protection.
Robust acidic pseudo-ionic liquid catalyst with self-separation ability for esterification and acetalization
Shi, Yingxia,Liang, Xuezheng
, p. 1413 - 1421 (2019/05/04)
The novel acidic pseudo-ionic liquid catalyst with self-separation ability has been synthesized through the quaternization of triphenylphosphine and the acidification with silicotungstic acid. The pseudo-IL showed high activities for the esterification with average conversions over 90%. The pseudo-IL showed even higher activities for acetalization than traditional sulfuric acid. The homogeneous catalytic process benefited the mass transfer efficiency. The pseudo-IL separated from the reaction mixture automatically after reactions, which was superior to other IL catalysts. The high catalytic activities, easy reusability and high stability were the key properties of the novel catalyst, which hold great potential for green chemical processes.
Retention Characteristics and Sorption Enthalpies of Esters of Natural Hydroxycarboxylic Acids on DB-1 Stationary Phase
Portnova,Yamshchikova, Yu. F.,Krasnykh
, p. 577 - 583 (2019/06/03)
Abstract: Sorption characteristics and retention of esters of glycolic, lactic, malic, and tartaric acids with C1?C8 alcohols of linear structure are studied by gas-liquid chromatography in the temperature range of 90?260°C on DB-1 nonpolar phase. The values of the retention indices of the compounds studied are obtained. On the basis of experimentally determined retention times, the thermodynamic characteristics of sorption under the conditions of limiting dilution are estimated. The dependences of the change in sorption enthalpies on the length of the linear alkyl substituent and on the value of the logarithmic retention index are found. The possibility of estimating the energy of intermolecular interactions of lactic acid esters in the liquid phase is shown on the basis of the obtained values of sorption enthalpies and vaporization enthalpies.
Method for directly preparing lactate from 1,2-propanediol and short-chain alkyl alcohols
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Paragraph 0050; 0053, (2019/10/15)
The invention belongs to the technical field of organic matter synthesis, and particularly relates to a method for directly preparing lactate from 1,2-propanediol and short-chain alkyl alcohols, and the method comprises the following steps: using a sodium stannate loaded rare noble metal as a catalyst, adding C1-C4 alkyl alcohols and the 1,2-propanediol into a high-pressure reaction kettle, usingnitrogen for purging air in the kettle, heating and stirring while the temperature is maintained to promote esterification of the 1,2-propanediol with the C1-C4 alkyl alcohols after oxidation of the 1,2-propanediol to produce the lactate. The method has mild reaction conditions and simple reaction steps, the 1,2-propanediol is completely converted, and the highest selectivity of the lactate can reach 78%. Meanwhile, the synthesized sodium stannate loaded rare noble metal has high catalytic activity and reusability.
Application of tungsten-based solid acid in lactic acid and lactate preparation using biomass and saccharides
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Paragraph 0038; 0040, (2018/11/03)
The invention relates to the technical field of chemical catalyzing, in particular to application of tungsten-based solid acid in lactic acid and lactate preparation using biomass and saccharides. Tungsten-containing salt is allowed to have hydro-thermal synthesis reaction with the chlorine salt, sulfate, nitrate, phosphate and oxalate of barium, calcium, lead, aluminum, chromium, erbium, tin, germanium, niobium and tantalum to prepare a multiple-component tungsten-based solid acid catalyst. The multiple-component tungsten-based solid acid catalyst is simple to prepare, cheap, good in hydrothermal stability, easy to recycle, capable of catalyzing monosaccharides such as fructose and glucose to convert into the lactic acid or lactate, capable of catalyzing polysaccharides such as sucrose, maltose, starch and cellulose even biomass such as wood and corn straw containing cellulose to have hydrolysis reaction so as to prepare the lactic acid or lactate, promising in application prospect and the like, multi-step reaction catalyzing by one single catalyst is achieved, and the range of the biomass and the saccharides which can be converted by the catalyst is wide.
Quantitative NMR Approach to Optimize the Formation of Chemical Building Blocks from Abundant Carbohydrates
Elliot, Samuel G.,Tolborg, S?ren,Sádaba, Irantzu,Taarning, Esben,Meier, Sebastian
, p. 2990 - 2996 (2017/07/25)
The future role of biomass-derived chemicals relies on the formation of diverse functional monomers in high yields from carbohydrates. Recently, it has become clear that a series of α-hydroxy acids, esters, and lactones can be formed from carbohydrates in alcohol and water solvents using tin-containing catalysts such as Sn-Beta. These compounds are potential building blocks for polyesters bearing additional olefin and alcohol functionalities. An NMR approach was used to identify, quantify, and optimize the formation of these building blocks in the Sn-Beta-catalyzed transformation of abundant carbohydrates. Record yields of the target molecules can be achieved by obstructing competing reactions through solvent selection.
Development of lactic ester as bifunctional additive of methanol-gasoline
Zhang, Jie,Yang, Changchun,Tang, Ying,Xu, Lianghong,Wang, Xiaoting
, p. 4827 - 4829 (2014/12/10)
In this paper, lactic esters were synthesized and used as phase stabilizer and saturation vapor pressure depressor of methanol-gasoline. The results show that the stabilities of the methanol-gasoline depend on the length of the lactic esters' alkoxy group. Several lactic esters were found to be effective in various gasoline-methanol blends, and the lactic esters display high capacity to depress the saturation vapor pressure of methanol-gasoline. According to the results, it can be concluded that the lactic esters have the great potential to be bifunctional gasoline-methanol additives.
MONOMER, POLYMER, RESIST COMPOSITION, AND PATTERNING PROCESS
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, (2014/03/21)
A polymer comprising recurring units derived from a (meth)acrylate monomer of tertiary ester type having branched alkyl on alicycle is used to form a resist composition. When subjected to exposure, PEB and organic solvent development, the resist composition is improved in dissolution contrast.