61836-76-8Relevant articles and documents
The Key Role of Water in Solid-Liquid Phase Transfer-catalysed Substitution Reactions
Zahalka, Hayder Ali,Sasson, Yoel
, p. 1652 - 1654 (1984)
Traces of water are shown to be essential for substitution reactions catalysed by quaternary ammonium salts; in chloride-formate exchange maximum rate is observed with 0.2percent water content of the formate salt, and addition of dehydrating agents reduces the maximum rate by 50percent.
Compounds, Compositions and methods for insect control
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Page/Page column 12, (2008/06/13)
Rapidly acting compositions having vapor phase insecticidal activity comprise natural products or natural product-based materials. Further, these materials are non-petroleum based, are typically 100% biodegradable, and typically do not persist in the environment, unlike traditional pesticides. The compositions kill susceptible insects on contact in seconds, even the notoriously hardy peripleneta species. The compositions also kill insects behind cracks and crevices and when sprayed onto absorbent surfaces such as wood and plasterboard, where traditional contact insecticides work poorly or not at all. New methods of testing insecticides can be used to quantify these effects.
One-Pot Conversion of Primary Alkyl Chlorides and Dichlorides into Alcohols, Diols, and Ethers via Formic Ester Intermediates under Phase-Transfer Conditions
Zahalka, Hayder A.,Sasson, Yoel
, p. 763 - 765 (2007/10/02)
A procedure for the synthesis of alkyl formates, 1,ω-alkanediyl diformates, and unsaturated analogs from alkyl (or 2-alkenyl) halides and sodium formate under solid/liquid phase-transfer conditions is reported.For conversion into alcohols or diols, respectively, the formic esters can be directly hydrolyzed in the reaction mixture of their preparation.Using a related procedure, cyclic ethers are prepared from 1,ω-dichloroalkanes, sodium formate, and potassium hydroxide under solid/liquid phase-transfer conditions.