The Key Role of Water in Solid-Liquid Phase Transfer-catalysed Substitution Reactions

DOI: 10.1039/c39840001652

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1652 - 1654 (1984)

Update date:2022-08-11

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Authors:

Zahalka, Hayder Ali

Sasson, Yoel

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Article abstract of DOI:10.1039/c39840001652

Traces of water are shown to be essential for substitution reactions catalysed by quaternary ammonium salts; in chloride-formate exchange maximum rate is observed with 0.2percent water content of the formate salt, and addition of dehydrating agents reduces the maximum rate by 50percent.

Full text of DOI:10.1039/c39840001652

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