623-81-4Relevant articles and documents
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Warlitz
, p. 74 (1867)
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Meuwsen,Gebhardt
, (1936)
PROCESS FOR PRODUCING CYCLOPROPANE MONOACETAL DERIVATIVE AND INTERMEDIATE THEREFOR
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Page/Page column 10, (2008/06/13)
A method of industrially advantageously producing a cyclopropane monoacetal derivative represented by the formula (III) conveniently and also in a fewer steps by reacting a halogenated unsaturated carbonyl compound represented by the formula (II) with an alcoholate. wherein each symbol is as defined in the specification.
Reactions of 4-chloromethyl-1,3,2-dioxathiolane 2-oxides with sodium phenoxide. A reinvestigation
Bredikhina, Z. A.,Pashagin, A. V.,Bredikhin, A. A.
, p. 1753 - 1756 (2007/10/03)
The reactions of 4-chloromethyl-1,3,2-dioxathiolane 2-oxides with PhONa in EtOH are accompanied by ring opening under the action of the ethoxide ion rather than leading to a rearrangement of the starting molecule as has been assumed previously. Under conditions precluding competition with other nucleophiles, the phenoxide anion smoothly replaces the chlorine atom in chloromethyl-substituted cyclic sulfites.