66985-46-4Relevant academic research and scientific papers
Copper(II) complexes with carboxylic- or sulfonic-functionalized arylhydrazones of acetoacetanilide and their application in cyanosilylation of aldehydes
Gurbanov, Atash V.,Mahmudov, Kamran T.,Sutradhar, Manas,Guedes da Silva, Fátima C.,Mahmudov, Talib A.,Guseinov, Firudin I.,Zubkov, Fedor I.,Maharramov, Abel M.,Pombeiro, Armando J.L.
, p. 22 - 27 (2017)
The new copper(II) complexes [Cu(HL1)(H2O)(CH3OH)] (1, H3L1?= (Z)-2-(2-(1,3-dioxo-1-(phenylamino)butan-2-ylidene)hydrazinyl)benzoic acid) and [Cu(HL2)(H2O)(CH3OH)] (2,
Cyanosilylation of aldehydes catalyzed by mixed ligand copper(II) complexes
Gurbanov, Atash V.,Mahmoudi, Ghodrat,Guedes da Silva, M. Fátima C.,Zubkov, Fedor I.,Mahmudov, Kamran T.,Pombeiro, Armando J.L.
, p. 130 - 136 (2018)
The new mixed ligand copper(II) complexes [Cu(HL)(H2O)(A)]·2H2O (1, NaH2L = sodium (Z)-2-(2-(1,3-dioxo-1-(phenylamino)butan-2-ylidene)hydrazinyl)benzenesulfonate, A = dimethylsulfoxide, [Cu(HL)(H2O)(B)] (2, B =
Trinuclear and polymeric cobalt(II or II/III) complexes with an arylhydrazone of acetoacetanilide and their application in cyanosilylation of aldehydes
Gurbanov, Atash V.,Maharramov, Abel M.,Guedes da Silva, M. Fátima C.,Pombeiro, Armando J.L.
, p. 632 - 637 (2017)
The new trinuclear [CoII(H2O)2(Me2NCHO)2{CoIII(1κNOO′:2κO″-μ-HL)}2(1κNOO′)]·2H2O (1) and polymeric [CoII(1κNOO′:2κO″-μ-HL)(MeOH)2]n (2
Reaction of sodium 2-(2-(2,4-dioxopentan-3-ylidene)hydrazinyl) benzenesulfonate with ethylenediamine on Cu(ii) and Ni(ii) centres: Efficient Cu(ii) homogeneous catalysts for cyanosilylation of aldehydes
Mahmoud, Abdallah G.,Mahmudov, Kamran T.,Guedes Da Silva, M. Fátima C.,Pombeiro, Armando J. L.
, p. 54263 - 54269 (2016)
By reacting copper(ii) or nickel(ii) salts with sodium 2-(2-(2,4-dioxopentan-3-ylidene)hydrazinyl) benzenesulfonate (NaHL) in an EtOH/H2O solvent mixture and in the presence of ethylenediamine (en), [Cu(HL)2(en)2] (1) or {
Packing polymorphism in 3-amino-2-pyrazinecarboxylate based tin(ii) complexes and their catalytic activity towards cyanosilylation of aldehydes
Karmakar, Anirban,Hazra, Susanta,Rúbio, Guilherme M. D. M.,Guedes Da Silva, M. Fátima C.,Pombeiro, Armando J. L.
, p. 17513 - 17523 (2018)
Reactions of 3-amino-2-pyrazinecarboxylic acid (HL) with SnCl2 under different hydrothermal conditions and crystallization processes produced two new mononuclear Sn(ii) compounds (1 and 2) of general formula [Sn(κN,O-L)2] (L = 3-amin
Solvent-Induced Facile Synthesis of Cubic-, Spherical-, and Honeycomb-Shape Palladium N-Heterocyclic Carbene Particles and Catalytic Applications in Cyanosilylation
Zhao, Huaixia,Li, Xinxiong,Li, Liuyi,Wang, Ruihu
, p. 3642 - 3647 (2015)
The facile synthesis of palladium N-heterocyclic carbene (NHC) particles with spherical, cubic, and honeycomb morphologies is accomplished. The structures of cubic and honeycomb particles are defined as an unprecedented trinuclear palladium-NHC complex. A
Synthesis, crystal structure and catalytic property of a cadmium(II) coordination polymer derived from a zwitterionic carboxylate ligand
Zhang, Jian-Wei,Cheng, Yan,Liu, Shu-Hua
, p. 347 - 351 (2018)
A new Cadmium(II) zwitterionic coordination polymer, {[Cd(cbdcp)(H2O)4]·H2O}n, (1) was synthesized based on the 1-(3,5-dicarboxybenzyl)-4,4′-bipyridinium bromide (H3cbdcpBr) organic linker. In 1, Cd(I
Photoluminescence, Unconventional-Range Temperature Sensing, and Efficient Catalytic Activities of Lanthanide Metal-Organic Frameworks
Gomez, Germán E.,Kaczmarek, Anna M.,Van Deun, Rik,Brusau, Elena V.,Narda, Griselda E.,Vega, Daniel,Iglesias, Marta,Gutierrez-Puebla, Enrique,Monge, M. ángeles
, p. 1577 - 1588 (2016)
A luminescent lanthanide metal-organic framework (MOF) based on Eu3+ and Tb3+ ions with 2-phenylsuccinate (EuTb-psa) was obtained solvothermally to explore its behavior as a temperature sensor in an unconventional temperature range t
Two Gd(III) coordination polymers based on a flexible tricarboxylate: Syntheses, structures, luminescence and catalytic properties
Zhu, Yu,Zhu, Min,Liu, Pan,Xia, Li,Wu, Yunlong,Xie, Jimin
, p. 26 - 32 (2017)
Two Gadolinium coordination polymers {[Gd·(TTTA)·(H2O)2]·2H2O}n (1) and [Gd·(TTTA)·DMF]n (2) have been synthesized based on Gd(NO3)3·6H2O and the flexible tripodal lig
Zirconium-based MOF catalyst with double active sites and preparation method and application thereof
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Paragraph 0071; 0073; 0075-0079, (2021/06/09)
The invention discloses a zirconium-based MOF catalyst loaded with double active sites as well as a preparation method and an application of the zirconium-based MOF catalyst. The method comprises thefollowing steps: adding zirconium salt and an organic ligand into an organic solvent, taking organic acid as a regulator, and carrying out self-assembly reaction to obtain a metal organic framework; adding salicylaldehyde for aldehyde amine condensation to obtain chelating coordination sites, adding palladium salt, and performing coordination through an impregnation method; reducing the obtained MOF in hydrogen to obtain an MOF loaded with Pd nanoparticles; reacting MOF and zinc salt in an organic solvent, and obtaining the catalyst. The Pd-Zn-coated UiO-68-NH2-CH3 catalyst synthesized by thepreparation method disclosed by the invention has efficient catalytic activity in a tandem alcohol oxidation/aldehyde cyanosilylation reaction. According to the catalyst, a metal organic framework UiO-68-NH2-CH3 is constructed, Pd nanoparticles and Zn are loaded by taking the metal organic framework UiO-68-NH2-CH3 as a carrier, the loading capacity of the Pd nanoparticles is 4-8wt%, and the loading capacity of the Zn is 3-5wt%.
