69712-22-7

Basic information

• Product Name: 1-deoxy-1-dibenzylamino-D-fructose
• Synonyms: 1-deoxy-1-dibenzylamino-D-fructose
• CAS NO: 69712-22-7
• Molecular Weight: 359.422
• Mol File: 69712-22-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-deoxy-1-dibenzylamino-D-fructose(CAS DataBase Reference)
• NIST Chemistry Reference: 1-deoxy-1-dibenzylamino-D-fructose(69712-22-7)
• EPA Substance Registry System: 1-deoxy-1-dibenzylamino-D-fructose(69712-22-7)

Safety Data

• Hazardous Substances Data: 69712-22-7(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 50-99-7 D-glucose 
• 103-49-1 dibenzylamine 
• 3458-28-4 D-Mannose 
• 105-53-3 diethyl malonate 
• 67-56-1 methanol 
• 108-59-8 malonic acid dimethyl ester 

Downstream Products

• 492-30-8 2-C-methyl-D-ribono-1,4-lactone 
• 2051-97-0 1-benzyl-1H-pyrrole 
• 28564-83-2 2,3-dihydro-3,5-dihydroxy-6-methyl-4H-pyran-4-one 
• 102-05-6 N-methyldibenzylamine 
• 100-52-7 benzaldehyde 
• 64-19-7 acetic acid 
• 103-49-1 dibenzylamine 
• 4429-04-3 1-amino-1-deoxy-D-fructose 

Relevant articles and documents

Carbon-branched carbohydrate chirons: practical access to both enantiomers of 2-C-methyl-ribono-1,4-lactone and 2-C-methyl-arabinonolactone

Readily crystallized 2-C-methyl-d-ribono-1,4-lactone is formed in a one-pot procedure from d-glucose without any protecting groups by treatment with dimethylamine to give an Amadori ketose and then with aqueous calcium hydroxide in yields of approximately 25%; 2-C-methyl-l-ribono-1,4-lactone is similarly produced from l-glucose. 3,4-O-Isopropylidene-2-C-methyl-d-arabinono-1,5-lactone and 2-C-methyl-d-arabinono-1,4-lactone were prepared in a combined 60% yield by the Kiliani reaction of sodium cyanide with a protected 1-deoxy-d-ribulose derived from d-erythronolactone; the enantiomeric arabinonolactones are similarly available from l-erythronolactone.