7119-93-9

Upstream product

• 186581-53-3 diazomethane 
• 645-55-6 N-nitroaniline 
• 77-78-1 dimethyl sulfate 
• 67-56-1 methanol 
• 124-41-4 sodium methylate 
• 74-88-4 methyl iodide 
• 60-29-7 diethyl ether 
• 121-69-7 N,N-dimethyl-aniline 
• 58682-35-2 potassium benzene-anti-diazotate 
• 100-61-8 N-methylaniline 
• 6786-32-9 benzoyl nitrate 

Downstream Products

• 618-40-6 1-Methyl-1-phenylhydrazine 
• 612-28-2 2-nitro-N-methylaniline 
• 100-15-2 N-methyl(p-nitroaniline) 
• 100-61-8 N-methylaniline 
• 64-18-6 formic acid 
• 7782-77-6 cis-nitrous acid 
• 62-53-3 aniline 
• 614-00-6 N-methyl-N-nitrosoaniline 
• 7664-41-7 ammonia 
• 479-45-8 tetryl 
• 655-56-1 N-methyl-N-(4-fluorophenyl)nitramine 
• 16698-03-6 N-nitro-N-methyl-4-nitroaniline 
• 943-41-9 N-methyl-N-nitroso-4-nitroaniline 
• 58538-01-5 N-methyl-N-nitroso-2,4-dinitroaniline 

Relevant academic research and scientific papers

Synthesis method of nitramide

The invention relates to a synthesis method of nitramide. The method comprises the step of enabling an aniline reaction substrate and a nitrating reagent to be subjected to a reaction in a solvent at20-60 DEG C for 2-8 hours to obtain the nitramide, where

Synthesis and properties of secondary N-nitroamines

Secondary arylamines and related compounds can readily be converted into the corresponding N-nitroamines by treatment of their organomagnesium derivatives with butyl nitrate. The yield of the products ranges from 45 to 77%. Secondary aromatic N-nitroamine

Direct Nitration of Anilines Using Nitrocyclohexadienones

Nitrocyclohexadienones (in particular, 2,3,5,6-tetrabromo-4-methyl-4-nitro-2,5-cyclohexadienone) are used as reagents for the direct nitration of anilines.Depending on the conditions, good yields of C-nitroanilines are obtained.Under the same conditions, N,N-dimethylaniline is converted into N-methyl-N-nitroaniline.

SUBSTITUENT EFFECT TREATMENT OF INTERACTIONS BETWEEN CONTIGUOUS FUNCTIONALITIES. IV. RESTRAINT TO PHENYL-NITROGEN CONJUGATIVE INTERACTION IN N-FUNCTIONALIZED N-METHYLANILINES

13C shifts at the para position in PhN(Me)X for 17 different substituents X serve as monitors for investigating, in correlative analysis, the nature and the extent of interactions occurring between the substituent X and the N-Me cavity.For the majority of substituent, X, partitioning of the nitrogen electron pair between the phenyl and the substituent is partially hampered because of the non-zero twist angle between the planes containing the phenyl ring and the Me-N-X fragment.As a consequence, relative to PhNHX, the interactions between the cavity and the substituents are increased in intensity, especially their mesomeric component, and, at the same time, para-13C shifts are displaced toward lower field.Evidence is also provided that possible H-bonding by the NH cavity of PhNHX with dimethyl sulphoxide does not appreciably influence the substituent electron demand determined previously.